• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.32-37
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• 1998

• Journal of Korean Society on Water Environment
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• v.21 no.6
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• pp.630-636
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• 2005

Groundwater contamination by nitrate exceeding water quality criteria (10 mg $NO_3{^-}-N/L$) occurs frequently. Fumarate, acetate, formate, lactate, propionate, ethanol, methane and hydrogen gas were evaluated for their nitrate removal efficiencies and removal rates for in situ bioremediation of nitrate contaminated groundwater. Denitrification rate for each substrate was in the order of: fumarate > hydrogen > formate/lactate > ethanol > propionate > methanol > acetate. Microcosm studies were performed with fumarate and acetate. When fumarate was used as a substrate, nitrate was removed 100 percent with rate of 0.66 mmol/day while conversion rate from nitrate to nitrogen gas or another by-product was 87 percent. 42 mg of fumarate was needed to remove 30 mg $NO_3{^-}-N/L$. When using acetate as carbon source, 31 percent of nitrate was removed during initial adjustment period. Among removed fraction, however, 83 percent of nitrate removed by cell growth. Overall nitrate removal rate was 0.37 mmol/day. Acetate showed longer lag time in consumption compared to that of nitrate, which implying that acetate would be better carbon source compared to fumarate as more amount was utilized for nitrate removal than cell growth.

• ALGAE
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• v.34 no.3
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• pp.237-251
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• 2019

The dinoflagellate genus Alexandrium is known to often form harmful algal blooms causing human illness and large-scale mortality of marine organisms. Therefore, the population dynamics of Alexandrium species are of primary concern to scientists and aquaculture farmers. The growth rate of the Alexandrium species is the most important parameter in prediction models and nutrient conditions are critical parameters affecting the growth of phototrophic species. In Korean coastal waters, Alexandrium affine and Alexandrium fraterculus, of similar sizes, often form red-tide patches together. Thus, to understand bloom dynamics of A. affine and A. fraterculus, growth rates and nitrate uptake of each species as a function of nitrate ($NO_3$) concentration at $100{\mu}mol\;photons\;m^{-2}s^{-1}$ under 14-h light : 10-h dark and continuous light conditions were determined using a nutrient repletion method. With increasing $NO_3$ concentration, growth rates and $NO_3$ uptake of A. affine or A. fraterculus increased, but became saturated. Under light : dark conditions, the maximum growth rates of A. affine and A. fraterculus were 0.45 and $0.42d^{-1}$, respectively. However, under continuous light conditions, the maximum growth rate of A. affine slightly increased to $0.46d^{-1}$, but that of A. fraterculus largely decreased. Furthermore, the maximum nitrate uptake of A. affine and A. fraterculus under light : dark conditions were 12.9 and $30.1pM\;cell^{-1}d^{-1}$, respectively. The maximum nitrate uptake of A. affine under continuous light conditions was $16.4pM\;cell^{-1}d^{-1}$. Thus, A. affine and A. fraterculus have similar maximum growth rates at the given $NO_3$ concentration ranges, but they have different maximum nitrate uptake rates. A. affine may have a higher conversion rate of $NO_3$ to body nitrogen than A. fraterculus. Moreover, a longer exposure time to the light may confer an advantage to A. affine over A. fraterculus.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.2
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• pp.159-173
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• 2017

The Weather Research and Forecast (WRF) - Community Multiscale Air Quality (CMAQ) system was applied to investigate the influence of major point sources located in Chungcheongnam-do (CN) on surface $PM_{2.5}$ (Particulate Matter of which diameter is $2.5{\mu}m$ or less) concentrations in its surrounding areas. Uncertainties associated with contribution estimations were examined through cross-comparison of modeling results using various combinations of model inputs and setups; two meteorological datasets developed with WRF for 2010 and 2014, and two domestic emission inventories for 2010 and 2013 were used to estimate contributions of major point sources in CN. The results show that contributions of major point sources in CN to annual $PM_{2.5}$ concentrations over Seoul, Incheon, Gyeonggi, and CN ranged $0.51{\sim}1.63{\mu}g/m^3$, $0.71{\sim}1.62{\mu}g/m^3$, $0.63{\sim}1.66{\mu}g/m^3$, and $1.04{\sim}1.86{\mu}g/m^3$, respectively, depending on meteorology and emission inventory choice. It indicates that the contributions over the surrounding areas can be affected by model inputs significantly. Nitrate was the most dominant $PM_{2.5}$ component that was increased by major point sources in CN followed by sulfate, ammonium, and others. Based on the model simulations, it was estimated that primary $PM_{2.5}$ $(PPM)-to-PM_{2.5}$ conversion rates were 41.3~50.7 ($10^{-6}{\mu}g/m^3/TPY$) for CN, and 12.4~18.3 ($10^{-6}{\mu}g/m^3/TPY$) for Seoul, Incheon, and Gyeonggi, respectively. In addition, spatial gradients of PPM contributions show very steep trends. $NO_X$-to-nitrate conversion rates were 7.61~12.3 ($10^{-6}{\mu}g/m^3/TPY$) for CN, and 3.94~11.3 ($10^{-6}{\mu}g/m^3/TPY$) for the sub-regions in the SMA. $SO_2$-to-sulfate conversion rates were 4.04~5.28 ($10^{-6}{\mu}g/m^3/TPY$) for CN, and 3.73~4.43 ($10^{-6}{\mu}g/m^3/TPY$) for the SMA, respectively.