• Title/Summary/Keyword: The adhesion strength

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Emulsification of Asphalt Modified with Styrene Butadiene Rubber (SBR) and Styrene Butadiene Styrene (SBS); 1) Phase Stability Behavior and 2) Physical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • v.54 no.4
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    • pp.335-344
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    • 2019
  • In this work, styrene butadiene rubber (SBR) and styrene butadiene styrene (SBS) were used to modify asphalt, resulting in SBR- and SBS-modified asphalt, respectively. The two modified asphalts were emulsified with a nonionic emulsifier (Span 60) and cationic emulsifiers (ID, DDA) and their phase stabilization was investigated via particle size, Zeta potential, and flow behavior analysis. With increasing amount of the mixed emulsifier, the particle size decreased, leading to an increase in viscosity. The shear thinning behaviors and Zeta potential values ranging from 35-65 mV were determined and remained considerably stable. In addition, the adhesion strength and compression strength of the SBR-and SBS-modified asphalt emulsion were evaluated via surface free energy examination. The remarkable adhesion and compression strengths were estimated when 5 phr ID and 6 phr DDA were added to the emulsified asphalt modified with SBR and SBS. Therefore ID and DDA, the two cationic surfactants, played significant roles in improving the dispersion and interfacial adhesion strength, resulting in the improved adhesion and compression strength of the emulsified asphalts modified with SBR and SBS.

A study on affecting factors by using dolly in coating adhesion test (돌리를 이용한 도막 부착력 시험의 영향 인자에 관한 연구)

  • Baek, Yun-Ho;Son, Seong-Mo;Park, Chung-Seo
    • Corrosion Science and Technology
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    • v.13 no.5
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    • pp.186-194
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    • 2014
  • Establishment of adhesion strength measurement procedure for marine epoxy coatings was conducted in order to ensure reliability of the test results. It was found that (1) the increase in thickness of the substrates would induce increase of pull-off strength. Especially, the increase in adhesion strength with the substrate thickness increment was attributed to the transition of stress mode to the pure tensile mode excluding bending effect. (2) The longer curing time, the higher pull-off strength. It may be due to higher cross-linking density of the coating (3) The pull-off strength increases as coating thickness increases due to the diminishment of bending effect (4) The longer drying time after water immersion, the higher pull-off strength. It may be due to the evaporation of water molecule at the coating-substrate interface.

Synthesis of Adhesion Promoters with Improved Compatibility and Properties of UV-Curable Adhesives Containing Adhesion Promoters (상용성이 개선된 접착 증진제의 합성 및 이를 함유한 자외선 경화형 접착제의 특성분석)

  • Park, Jung-Hyun;Won, Jonh-Woo;Kim, Ju-Yeol;Yoon, Yoo-Jung;Kwon, Oh-Hyeong;Hwang, Jin-Sang
    • Journal of Adhesion and Interface
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    • v.19 no.4
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    • pp.145-153
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    • 2018
  • In this study, adhesion promoters with acrylate and carboxylic acid moiety were synthesized from malenized polybutadiene and 2-hydroxyethyl acrylate for producing adhesive film with low water absorption and high adhesion. The surface properties, adhesion strength, mechanical properties and water absorption of adhesive films were characterized according to the amount of acrylate and carboxylic acid in the synthesized adhesion promoters. As the carboxylic acid in the adhesion promoters increased, the adhesion strength showed a tendency to increase and the mechanical properties also improved compared to the commercial adhesion promoter. The compatibility of adhesion promoters improved remarkably due to the presence of polybutadiene (hydrophobic nature), maleic anhydride (hydrophilic nature) and carboxylic acid (hydrophilic nature).

AN EXPERIMENTAL STUDY ON ADHESION PATTERN, ADHESION STRENGTH AND FRACTURE PATTERN OF THE ADHESIVE CAST GOLD INLAY (접착형 구조 금 인레이의 접착 형태, 강도 및 파절 양태에 관한 실험적 연구)

  • Han, Seoung-Ryul;Hong, Chan-Ui
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.64-72
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    • 1994
  • Zinc Phosphate Cement hand been used for about more than 100 years in luting of cast gold inlay. But many scientists had been trying to develop the new form of luting agent because the ZPC hand shown the lack of adhesiveness on the tooth structure and the toxicity to the pulp tissue. Recently many researches about the surface treatment of the cast body are being done to increase the adhesion of cement to it. The conventional Class I gold inlays were fabricated in the 20 permanent molars. After the internal surface of the cast body was sandblasted with $Al_2O_3$ particles and was tin-plated, the inlays were cemented with adhesive cement [G I cement and resin cement(Super-Bond & $Panavia_{EX}$)] and the evaluation on the adhesion pattern, adhesive strength and the fracture pattern of the adhesive cast gold inlay was compared to that of the cast gold inlay cemented conventionally with ZPC. The results were as follows : 1. The surface roughness of the cast body was increased significantly after sandblasting with the $Al_2O_3$ particles and the tin oxide layer, which was consisted of round particles, came into being. 2. The bond strength was in the order of Super-Bond, ZPC, Fuji I, $Panavia_{EX}$ group. The group cemented with Super-Bond showed statistically greater strength than the other groups(p<0.05). 3. The group cemented with ZPC was fallen apart by principal adhesion failure and that with Fuji I was by complete adhesion failure. But the group with Super-Bond showed pricncipal cohesive failure pattern and in the group with $Panavia_{EX}$, complete cohesive fracture pattern was shown and small protion of tooth structure was fractured out with cast body and the fractured surface showed the figure just as the enamel prism. 4. Various gaps were shown at the pulpal side regardless of little gap at the side walls of the cavity in all groups. Only the Super-Bond was attached to the tooth structure and the other cements were detached from both the tooth and the cast body.

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Influence of Oxidation Inhibitor on Carbon-Carbon Composites : 7. Studies on Work of Adhesion and Fracture Toughness of Carbon-Carbon Composites (산화억제제를 첨가한 탄소/탄소 복합재료의 물성에 관한 연구 : 7. 탄소/탄소 복합재료외 부착력과 파괴인성)

  • 박수진;서민강;이재락
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.435-440
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    • 2001
  • The objective of this study was to examine the effect of oxidation inhibitor contents on the work of adhesion, fracture toughness, and impact strength of the unidirectional carbon-carbon composites (C/C composites). The molybdenum disilicide ($MoSi_2$) used as an oxidation inhibitor was impregnated with phenolic resins to improve the anti-oxidation properties of the composites in different concentrations of 4, 12 and 20 wt%. Based on Wilhelmy equation, the work of adhesion of C/C composites was calculated by contact angle methods. Fracture toughness and impact strength were pressured by three-point bending test for the critical intensity factor ($K_IC$) and Izod test method, respectively. As a result, the composites made with $MoSi_2$ resulted in an increasing of both fracture toughness and impact strength. Especially, the composites made with 12 wt% $MoSi_2$ content showed the highest value of London dispersive component, $W_A\;^L$, in work of adhesion, resulting from improving the interfacial adhesion force among fibers, filler, and matrix in this system.

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Surface Preparation and Activation Only by Abrasion and Its Effect on Adhesion Strength

  • Ali Gursel;Salih Yildiz
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.101-107
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    • 2022
  • Adhesive joints have many advantages such as weight savings, corrosion and fatigue resistance and now developed even withstand of high impact and dynamic loads. However, an adhesion has cumbersome and complicated surface preparation processes. The surface preparation step is critical in adhesive joint manufacturing in order to obtain the prescribed strength for adhesive joints. In this study, it was attempted to simplify and reduce the number of surface preparation steps, and abrasion and rapid adhesive application (ARAA) process is developed for an alternative solution. The abrasion processes are performed only for creating surface roughness in standard procedures (SP), although the abrasion processes cause surface activation itself. The results showed that there is no need the long procedures in laboratory or chemical agents for adhesion. After the abrasion process, the attracted and highly reactive fresh surface layer obtained, and its effect on bonding success is observed and analyzed in this research, in light of the essential physic and adhesion theories. Al 6061 aluminum adherends and epoxy-based adhesives were chosen for bonding processes, which is mostly used in light vehicle parts. The adherends were cleaned, treated and activated only with abrasion, and after the adhesive application the specimens were tested under quasi-static loading. The satisfied ARAA results were compared with that of the specimens fabricated by the standard procedure (SP) of adhesion processes of high impact loads.

Improvement of adhesion of Polyester Fabric and Knit by Corona Treatment (코로나 처리를 이용한 폴리에스테르 편·직물의 접착력 향상)

  • Lee, Eon Pil;Yoon, Rae Won;Lee, Jae Ho
    • Journal of Adhesion and Interface
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    • v.8 no.3
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    • pp.16-23
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    • 2007
  • Polyester fabrics and knits were corona treated with different current intensity (5, 10, 15, 20 A) and feeding speed (5, 10, 15 m/min). We confirmed the surface change of polyester fabrics and knits using scanning electron microscopy (SEM) and X-ray photoelectron spectrometer (XPS). And the change of physical properties through measuring the tensile strength, dry and wet bonding strength. Thermosetting reactive polyurethane hot melt adhesive was used in the adhesion of polyester fabrics and knits. Functional groups were introduced on PET fabrics and knits surface by treating the PET fabrics and knits in air atmosphere with corona discharge, and take placed unevenness, the result adhesion was improved. When consider both dry and wet bonding strength, we think that appropriate conditions in the PET fabrics corona treatment are feeding speed 10 m/min, current intensity 15 A and appropriate conditions in the mesh type PET knits corona treatment are feeding speed 10 m/min, current intensity above 10 A.

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The Adhesion Property of Fish Glue (어교(魚膠)의 접착특성)

  • Lee, Young-Kyu;Hwang, Hyeon-Deuk;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.5
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    • pp.59-65
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    • 2004
  • The present study aims to optimise the process parameters of fish glue and adhesion property through room temperature in terms of curing time and opened assembly time for attaining best adhesion strength to wood (Yellow birch, B. alleghaniensis). The uncured and cured fish glue have been characterised by TGA, DSC, FT-JR. It is observed that with increasing curing time up to 48 H, tensile lap shear strength of adhesive joint of fish glue to wood increases and decreases after 48 H. At 15 min. opened assembly time, lap shear strength increases up to 4833 kgf/cm2 and decreases after 15 min.

A Study on the Quality Characteristics of Leather Shoe Adhesives(I) -Ladies' Leather-shoe- (구두용 접착제의 품질 특성에 관한 연구(I) -여성 가죽구두-)

  • 서교택;이상신
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.23 no.54
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    • pp.137-144
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    • 2000
  • The chloroprene adhesive for ladies' shoe-making applied by the cementing method in KS G 3116 has been evaluated.. For the quality test of adhesive for pump whole cut vamp using chloroprene adhesive, general property and adhesion strength were measured and duration for environmental exposure was tested. Also, a list of experiments for field application was prepared. In case of adhesion-strength measurement,, the KS G 3116 method of peel strength at end of toe was found to be reasonable by measurement through a whole length, toe to heel seat on feather edge.

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Curing Behavior and Adhesion Performance of Urea-Melamine-Formaldehyde (UMF) Resin by Staged Addition of Melamine (멜라민 첨가 순서에 따른 UMF 접착제의 경화거동과 접착력의 영향)

  • Xu, Guang-Zhu;Eom, Young-Geun;Lee, Young-Kyu;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.84-89
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    • 2009
  • The objective of this research was to investigate the curing behavior and adhesion performance of urea-melamine-formaldehyde (UMF) resin for the four types of UMF-1, UMF-2, UMF-3, and UMF-4 which synthesized by the staged addition of melamine. Also, various network structures of these resin types were discussed based on their different curing behavior and adhesion performance. The curing behavior was evaluated by DMTA and thermal stability was checked by TGA. Adhesion performance was evaluated by dry and wet shear strengths and the pH value of each cured resin was checked to see its effect on the adhesion performance. The results indicated that the UMF-1 resin type by the addition of melamine initially with the urea and formaldehyde at the same F/(U+M) rate showed the lowest thermal stability, rigidity (${\Delta}E^{\prime}$), temperature of tan ${\delta}$ maximum ($T_{tan}\;_{\delta}$), and wet shear strength, and pH value of cured resin. In wet shear strength, however, the UMF-4 resin type appears to be slightly higher than UMF-1 resin type.

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