• Title/Summary/Keyword: The Quaternary

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Characterization of Solidification and Microstructure of an Al-Zn-Mg-Si Alloy

  • He Tian;Dongdong Qu;Zherui Tong;Nega Setargew;Daniel J. Parker;David StJohn;Kazuhiro Nogita
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.104-112
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    • 2024
  • Al-Zn-Mg-Si alloy coatings have been developed to inhibit corrosion of cold rolled steel sheets, and an understanding of the alloy system helps prevent coating defects. We used a Bridgman furnace to characterise the nature and formation mechanisms of the phases present in the quaternary system with 0.4 wt% Fe. In the directional solidification experiments we imposed steep temperature gradients and varied the pull rate. After the samples were quenched in the furnace, detailed characterization of the samples was carried out by electron microscopy (SEM/EDS). From the dT/dt vs T plots of the cooling curves of the alloys, the solidification path was determined to be $Liquid{\longrightarrow[80]^{544-558}}{\alpha}-Al{\longrightarrow[80]^{453-459}}Al/Mg_2Si{\longrightarrow[80]^{371-374}}Al/Zn{\longrightarrow[80]^{331-333}}Zn/mgZn_2$. The formation mechanisms of the Mg and Zn containing phases and their morphology was discussed together with the effects of the cooling rate. Key findings include the lengthening of the mushy zone in directionally solidified samples remelted against a positive temperature gradient, as well as an enrichening of the α-Al phase by Zn through remelting. Mg2Si and other Si based phases were observed to adopt a much finer faceted microstructure in favour of a script-like microstructure when exposed to the higher cooling rate of coolant quenching.

Major Element Changes in the Upper Quaternary Sediment of the East Sea (Sea of Japan): Their Implications for the Onset of Holocene

  • Hyun, Sang-Min;Han, Sang-Joon;Bahk, Jang-Jun
    • Journal of the korean society of oceanography
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    • v.33 no.4
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    • pp.185-195
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    • 1998
  • Two piston cores (94PC-2 and 95PC-4) taken from the East Sea (Sea of Japan) are studied to evaluate the paleoceanographic changes and its interaction with climatic variation. The bulk geochemistry of the non-biogenic fractions of 54 sediment samples is determined using X-ray fluorescence. Four geochemical stratigraphic units at both core sediments are recognized based on the variations in major element concentration. These chemical stratigraphic units correspond well with the sedimentological and paleontological facies. Source materials are considered as basic and/or intermediate rocks judging from silica content. A distinctive boundary around 11 kyr may correspond to Younger Dryas event. The switch of most major elements at this level and the distinctive changes in concentration of typical terrigenous elements (TiO$_2$ and Al$_2$O$_3$) are the strong evidence for the difference in sources of terrigenous materials. The weathering indices exhibit high degree in Core 94PC-2 and low degree in Core 95PC-4. The changes in weathering degree can be distinguished by the lowest value occurred at 11 kyr in Core 94PC-2 and by a gradual decrease from top to bottom in Core 95PC-4. The profiles of potassium and sodium exhibit specific excursions between the Holocene and the late Pleistocene. This implies that sediments of the two cores originating from different sources with different weathering degrees. The distinct two-group distributions in K$_2$O/CaO vs. Na$_2$O/K$_2$O also support the difference in provenance of aluminosilicate materials at the boundary of 11 kyr. Thus, supply patterns of terrigenous materials are stable in Holocene and more complicated in the last glacial period.

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Extraction of Lineament and Its Relationship with Fault Activation in the Gaeum Fault System (가음단층계의 선형구조 추출과 선형구조와 단층활동의 관련성)

  • Oh, Jeong-Sik
    • Journal of The Geomorphological Association of Korea
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    • v.26 no.2
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    • pp.69-84
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    • 2019
  • The purpose of this study is to extract lineaments in the southeastern part of the Gaeum Fault System, and to understand their characteristics and a relationship between them and fault activation. The lineaments were extracted using a multi-layered analysis based on a digital elevation model (5 m resolution), aerial photos, and satellite images. First-grade lineaments inferred as an high-activity along them were classified based on the displacement of the Quaternary deposits and the distribution of fault-related landforms. The results of classifying the first-grade lineaments were verified by fieldwork and electrical resistivity survey. In the study area of 510 km2, a total of 222 lineaments was identified, and their total length was 333.4 km. Six grade lineaments were identified, and their total length was 11.2 km. The lineaments showed high-density distribution in the region along the Geumcheon, Gaeum, Ubo fault, and a boundary of the Hwasan cauldron consisting the Gaeum Fault System. They generally have WNW-ESE trend, which is the same direction with the strike of Gaeum Fault System. Electrical resistivity survey was conducted on eight survey lines crossing the first-grade lineament. A low-resistivity zone, which is assumed to be a fault damage zone, has been identified across almost all survey lines (except for only one survey line). The visual (naked eyes) detecting of the lineament was evaluated to be less objectivity than the automatic extraction using the algorithm. However, the results of electrical resistivity survey showed that first-grade lineament extracted by visual detecting was 83% reliable for inferred fault detection. These results showed that objective visual detection results can be derived from multi-layered analysis based on tectonic geomorphology.

Syntheses and Mechanical Properties of Quaternary Cr-Si-O-N Coatings by Hybrid Coating System (하이브리드 코팅시스템에 의한 Cr-Si-O-N 코팅막 합성 및 기계적 성질)

  • Lee, Jeong-Doo;Wang, Qi Min;Kim, Kwang-Ho
    • Journal of Surface Science and Engineering
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    • v.43 no.5
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    • pp.238-242
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    • 2010
  • In the present work, the influence of oxide on the Cr-Si-N coatings was investigated for the Cr-Si-O-N coatings on AISI 304 and Si wafer deposited by hybrid system, which combines the DC magnetron sputtering technique and arc ion plating (AIP) using Cr and Si target in an $Ar/N_2/O_2$ gaseous mixture. As the O content in the Cr-Si-N coatings increased, the diffraction patterns of the Cr-Si-O-N coatings showed CrN and $Cr_2O_3$ phases. However, as the O content increased to 28.8 at.%, diffraction peak of $Cr_2O_3$ was disappeared in the Cr-Si-O-N coating. The $d_{200}$ value was decreased with increasing of O content. The average grain size increased from about 40 nm to 65 nm as the O content increased. The maximum micro-hardness of the Cr-Si-O-N coating was obtained 4507 Hk at the O content of 24.8 at.%. The average friction coefficient of the Cr-Si-O-N coatings was gradually decreased by increasing the O content and the average friction coefficient decreased from 0.37 to 0.25 by increasing the O content. These results indicated that amorphous phase was increased in the Cr-Si-O-N coatings by increasing of O content.

The Gradient Analysis of the Korean Peninsula by using DEM (DEM을 이용한 한반도 지형의 경사도 분석)

  • Lee, Kum-Sam;Jo, Wha-Ryong
    • Journal of the Korean Association of Geographic Information Studies
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    • v.3 no.1
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    • pp.35-43
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    • 2000
  • The slope gradient of the Korean Peninsula was analyzed by using DEM(DTED level 1). The Peninsula has high percentages of gentle slopes. But low plains and very steep slope regions are scarcely distributed in the Peninsula. Altitude lower than 150m areas are composed of plains and undulated plains. The steepest and most rugged topographies are observed in the range of altitude from 500m to 1,000m areas. The areas of altitude greater than 1,000m show plateau landscapes. By overlapping digital geology maps and the gradient grade maps, We revealed the characteristics of slope regions by geological districts. High latitude with steep slope are well developed in the geological districts of granitic gneiss(ARgr) and gneiss($PR_1$) of the Pre-Cambrian, sandstone of the Paleozoic era(P-T), and sedimentary rocks of the Mesozoic era($J_2$). Low altitude with gentle slope areas are representative in the districts of granite of the Mesozoic era($Jgr_1$), the Cretaceous sedimentary rocks of the Mesozoic era($K_1$, $K_2$) and the Cenozoic strata(N). Basalt extruded the Quaternary($Q_1$) are observed in the areas of very gentle slope but greater than 1,000m altitude.

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Epidemiological Multi-center Study of Blast Injury in Military Centers (군내 폭발손상환자 현황에 대한 다기관연구)

  • Kim, Won Young;Choi, Wook Jin;Lee, Jong Ho;Park, Ha Young;Kim, Dong Ook
    • Journal of Trauma and Injury
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    • v.21 no.2
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    • pp.78-84
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    • 2008
  • Purpose: Recently, the incidence of blast injury has been on the increase worldwide. The purpose of this study was to evaluate and analyze blast injuries in South Korea. Methods: This was a retrospective multi-center study of blast injuries in three tertiary military centers. The medical records of patients with blast injuries from January 2003 to December 2007 were reviewed. The injury severity was evaluated according to the Injury Severity Score (ISS), the Revised Trauma Score (RTS), and the Trauma Score and the Injury Severity Score (TRISS). Results: This study revealed epidemiological data of blast injury in the three tertiary military hospital. A total of 94 cases of blast injury had occurred. Various body regions were involved. The most frequently injured site was the upper extremity (52.1%). The mechanisms for the blast injuries were primary (41.5%), secondary (74.5%), tertiary (7.4%), and quaternary (29.8%). The mean injury-to-hospital arrival time was $3.2{\pm}1.7hour$. The rate of admission was 88.3%, and the rate of ICU admission was 32.5%. Thirty-six (36) cases required an emergency operation. Most were performed by an Orthopedist (55.6%), an Ophthalmologist (19.4%), or a general surgeon (13.9%). The mortality rate from blast injury was 4.3%. Conclusion: This was the first paper to present data on the type of injury, the site of injury, the cause of death, and the mortality from blast injury in South Korea. Chest injury, brain injury, tertiary injury mechanisms, $ISS{\geq_-}16$, and a Maximal Abbreviated Injury Scale Score $(ABI){\geq_-}4$ were significantly associated with death.

Evaluation of Changesin the Physical Characteristics of Raindrops Under a Canopy in Central Korea (나무 아래 빗방울(雨滴)의 물리적 특성변화 분석)

  • Kim, Jin Kwan;Kim, Min Seok;Yang, Dong Yoon;Lim, Young Shin
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.3
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    • pp.105-122
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    • 2016
  • To evaluate the changes in the physical characteristics of open rainfall related to canopy effects and rainfall intensity in Korea, the terminal velocity of raindrops and drop size distributions(DSD) were continuously measured by an optical-laser disdrometer in an open site(Op) and in two forest stands(Th1: Larix leptolepis, Th2: Pinus koraiensis) during five rainfall events in 2008. The terminal velocity, DSD and two forms of kinetic energy(KE, $Jm^{-2}$ $mm^{-1}$; KER, $Jm^{-2}$ $h^{-1}$) of open rainfall drops were determined and were compared with those of throughfall drops under two different canopy heights. The effects of the canopy and rainfall intensity, together with wind speed, on the changes in drop size and kinetic energy of throughfall were evaluated. Throughfall drops were larger than open rainfall drops. The distribution of terminal velocities for the drop sizes measured at Th2 was lower than that at Op; however, at Th1 the distribution was similar to that at Op. The total kinetic energy of throughfall at Th1 and Th2 was higher than the total kinetic energy of open rainfall, and the kinetic energy distribution for the drop sizes wassimilar to the drop size distribution. The observed throughfall-KER at Th1 was lower than an estimate previously produced using a model. The overestimation from the modeled value at Th1 was likely to be due to overestimated values of a square root transformation of fall height and its coefficient in the model because the distributions of terminal velocity for the drop size measured at Th1 were similar to those of open rainfall.

Research on the development law of karst fissures and groundwater characteristic in Xintian County

  • Xin, Zhou;Tengfei, Yao;Can, Wang;Jian, Ou;Pengfei, Zheng;Kaihong, Chen;Xiting, Long
    • Membrane and Water Treatment
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    • v.13 no.6
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    • pp.303-312
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    • 2022
  • The natural hydrology and geological conditions of Xintian County was investigated, the development law of regional karst fissures was studied, the groundwater was collected and tested through a large-scale collection of groundwater to obtain the change law of chemical characteristics and water quality characteristics of groundwater, and the water quality evaluation was carried out for the regional karst groundwater in this paper. The results show that, the whole area is dominated by carbonate rock distribution areas, and the distribution of water systems is relatively developed. The strata are distributed from the Lower Paleozoic Cambrian to the Cenozoic Quaternary, and contain multiple first-order folds. The regional karst dynamic action is strong, and many tunnels or caves of different scales were shown, which are conducive to the enrichment of groundwater. Karst groundwater is neutral and alkaline water, the water is clear and transparent with good taste, and meets the national drinking water hygiene standards. The content of toxic trace elements and fluoride in the water source is generally lower than the limit value specified by the national standard and the accumulated toxic heavy metals is never found. The overall water quality is of good quality and suitable for the development and utilization of various purposes.

One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction

  • Byambasuren, Ulziidelger;Jeon, Yukwon;Altansukh, Dorjgotov;Ji, Yunseong;Shul, Yong-Gun
    • Carbon letters
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    • v.17 no.1
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    • pp.53-64
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    • 2016
  • Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were promoted by the dual transition metals of iron and cobalt (Fe, Co), which were incorporated into the N-doped carbons lattice by subsequently heat treatments. All the prepared carbons were characterized by via transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). To evaluate the activities of synthesized doped carbons, linear sweep was recorded in an acidic solution to compare the ORR catalytic activities values for the use in the PEMFC system. The dual transition metal promotion improved the ORR activity compared with the single transition metal promotion, due to the increase in the quaternary nitrogen species from the structural change by the dual metals. The effect of different ratio of the dual metals into the N doped carbon were examined to evaluate the activities of the oxygen reduction reaction.

The Elevation of Paleo-shoreline and Formation Age of the 1st Marine Terrace in Dadaepo, Busan, South Korea (부산 다대포 지역 해안 단구 제1면의 구정선 고도와 형성 시기)

  • Shin, Jae-Ryul;Hong, Yeong-Min;Hong, Seong-Chan
    • Journal of The Geomorphological Association of Korea
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    • v.26 no.4
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    • pp.67-79
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    • 2019
  • This study documents the level of paleo-shoreline and the timing of formation of the lowest marine terrace (1st terrace) distributed in Dadaepo, Busan, South Korea. In the study area, the elevation of paleo-shoreline of the 1st terrace is clearly identified as 5 meters above mean high tide based on the elevation of wave-cut platforms and the elevation of boundary between marine and terrestial sediments. This is well consistent with the fact that are found along the Southern coast of the Korean Peninsula including Daepo-dong, Sacheon-si. The timing of formation of the 1st terrace in Dadaepo is confirmed to have been deposited around 70,000~80,000 years BP (MIS 5a) according to OSL and IRSL dating ages. However, because the formation age of the 1st terrace in Sacheon-si Daepo-dong (Southerm coast) and Pohang-si Umok-ri (Eastern coast) previously identified as about 90,000~100,000 years BP (MIS 5c), further discussion of what is needed. Possibly, it can be interpreted that the sub-interglacial (MIS 5a and 5c) sea-level records during the last interglacial period are likely to be selective on land depending on regions.