• The Research Journal of the Costume Culture
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• v.20 no.2
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• pp.238-250
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• 2012

This study examined the degradation behavior of SB(standard berberine) dye and SB dyed silk using HPLC-MS instrument after degradation in the hydrogen peroxide/ultraviolet ray radiation/oxygen system up to 9 days and 40 hours respectively. In the degraded samples, berberine was detected at 5.2 min in the SB dye and 5.3 min in the SB dyed silk with its molecular ion=336 and the UV spectra of quaternary alkaloid. Degradation product 3(m/z=102) newly appeared after 5 day degradation treatment with continued increase till the end of degradation treatment. The amount of berberine in the degraded dye decreased with degradation progression. In the silk dyeings, berberine was detected only up to 21 hour degradation sample. The amount of berberine decreased dramatically during the first 6 hours of degradation treatment. The CIELAB color measurement of the silk dyeings showed dramatic change in the b* value, near zero in the 40 hour degraded silk. CIELAB and Munsell color measurements were in agreement with the HPLC-MS results of the dyed silk in the change of berberine content that the degraded silk became white and lost yellow color.

• Journal of the korean society of oceanography
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• v.34 no.1
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• pp.43-48
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• 1999

The latest-Quaternary paleoceanographic history of the Ulleung Basin, the East Sea (the Sea of Japan) is reconstructed on the base of planktonic foraminifera, oxygen and carbon isotopes, and accelerator mass spectrometer radiocarbon (AMS-$^{14}$C) data from two cores. Sinistral populations of Neogloboquadrina pachyderma are dominant during the last glacial period while dextral forms of Neogloboquadrina pachydeyma are abundant in the Holocene. An abrupt increase in ${\delta}^{18}$O values in both cores that began about 11 ka B.P may indicate the Younger Dryas cooling episode. A low-salinity event, marked by light ${\delta}^{18}$O values (0-1 %), is observed before the Younger Dryas event. As previous works suggested, the low-salinity event is probably due to the freshening of surface water caused by fresh water input from Huang Ho river and/or the excess of precipitation over evaporation. The lowest salinity water in the Ulleung Basin was probably continued from approximately 18 ka B.P. to 15 ka B.P. The ${\delta}^{18}$O values have gradually decreased since the Younger Dryas as a result of the continuous inflow of the warm Tsushima Current into the East Sea.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1819-1824
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• 2006

The general objective of the present study was to investigate the potential application of the UV spectroscopic method for determination of the polymeric additives present in papermaking fibrous stock solutions. The study also intended to establish the surface-chemical retention model associated with the adsorption kinetics of additives on fiber surfaces. Polyamide epichlorohydrin (PAE) wet strength resin and imidazolinium quaternary (IZQ) softening agents were selected to evaluate the analytical method. Concentrations of PAE and IZQ in solution were proportional to the UV absorption at 314 and 400 nm, respectively. The time-dependent behavior of polymeric additives obeyed a mono-molecular layer adsorption as characterized in Langmuir-type expression. The kinetic modeling for polymeric adsorption on fiber surfaces was based on a concept that polymeric adsorption on fiber surfaces has two distinguishable stages including initial dynamic adsorption phase and the final near-equilibrium state. The simulation model predicted not only the real-time additive adsorption behavior for polymeric additives at high accuracy once the kinetic parameters were determined, but showed a good agreement with the experimental data. The spectroscopic method examined on the PAE and IZQ adsorption study could potentially be considered as an effective tool for the wet-end retention control as applied to the paper industry.

• Textile Coloration and Finishing
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• v.14 no.4
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• pp.229-239
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• 2002

Colorants were extracted from the heartwood of sappan lin. with MeOH under reflux, and the concentrate or the powder of dye was prepared by low pressure concentration method using suitable organic solvent. Various components were isolated from sappan wood, and the chemical structure and mechanism of compound having the excellent antibacterial and deodorization properties were analyzed. The results obtained are as follows ; The seventeen components of sappan wood were seperated by HPLC chromatography, and the five components among them were existed more than 6% and the other components were existed lower than 0.6%. The resolving powers of the non-polar solvent and polar solvent systems were evaluated by their ability to resolve the samples. It showed that chloroform-methanol-water(800:150:10) system has the best resolving power. Although the seperation rate is very slow, polyamide C-100 column chromatography gives a clear seperation of sappan wood. On the basis of the spectrometric data such as IR, UV, $GC-Mass,\;^1H-NMR,\;^{13}C-NMR\;and\;^1H-^{ 13}C-NMR$, the chemical structure of compound haying the excellent antibacterial and deodorization properties was established as brazilin containing the functional groups such as two quaternary carbon, one benzyl carbon, methylene contiguous to oxygen and methylene caused by oxygen atom.

• Journal of Microbiology and Biotechnology
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• v.18 no.7
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• pp.1298-1307
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• 2008

In this study, we investigated the inhibition effects of single and mixed heavy metal ions ($Zn^{2+},\;Ni^{2+},\;Cu^{2+},\;and\;Cd^{2+}$) on iron oxidation by Acidithiobacillus ferrooxidans. Effects of metals on the iron oxidation activity of A. ferrooxidans are categorized into four types of patterns according to its oxidation behavior. The results indicated that the inhibition effects of the metals on the iron oxidation activity were noncompetitive inhibitions. We proposed a reduced inhibition model, along with the reduced inhibition constant ($\alpha_i$), which was derived from the inhibition constant ($K_I$) of individual metals and represented the tolerance of a given inhibitor relative to that of a reference inhibitor. This model was used to evaluate the toxicity effect (inhibition effect) of metals on the iron oxidation activity of A. ferrooxidans. The model revealed that the iron oxidation behavior of the metals, regardless of metal systems (single, binary, ternary, or quaternary), is closely matched to that of any reference inhibitor at the same reduced inhibition concentration, $[I]_{reduced}$, which defines the ratio of the inhibitor concentration to the reduced inhibition constant. The model demonstrated that single metal systems and mixed metal systems with the same reduced inhibitor concentrations have similar toxic effects on microbial activity.

• 한국해양학회지
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• v.19 no.1
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• pp.94-102
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• 1984

The origin of the East sea is discussed in the light of modern geophysical theories such as plate tectonics and sea-floor spreading. The origin of the East Sea was due to the tensional force of the back-arc spreading which was initiated as early as late Cretaceous time of Paleocene. The spreading was asymmetric with a fast movement of eastward or southeastward and a slow westward motions. The spreading, however, was confined to the East Sea due to the change of the Pacific Plate north-northwest to west-northwest during Eocene time. Further intensifying research based on more accurate seismic data as well as on geophysical and geological informations should be carried out continuously to understand if the spreading of the Japan Sea died out due to triple junction formed by mention of the Pacific, the Eurasian, and the Philippine plates since the Quaternary.

• Macromolecular Research
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• v.13 no.6
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• pp.491-498
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• 2005

Fluorene-containing, spiro-type, conjugated polymers were synthesized via the cyclopolymerization of dipropargylfluorenes (2-substituted, X=H, Br, Ac, $ NO_{2}$) with various transition metal catalysts. The polymerization of dipropargylfluorenes proceeded well using Mo-based catalysts to give a high polymer yield. The catalytic activities of the Mo-based catalysts were found to be more effective than those of W-based catalysts. The palladium (II) chloride also increased the polymer yield of the polymerization. The polymer structure of poly(dipropargylfluorene)s was characterized by such instrumental methods as NMR ($^{1}H_{-}$, $^{13}C_{-}$), IR, UV-visible spectroscopies, and elemental analysis as having the conjugated polymer backbone bearing fluorene moieties. The $^{13}C_{-}$NMR spectral data on the quaternary carbon atoms in polymers indicated that the conjugated cyclopolymers have the six-membered rings majorly. The poly(dipropargylfluorene) derivatives were completely soluble in halogenated and aromatic hydrocarbons such as methylene chloride, chloroform, benzene, toluene, and chlorobenzene. The poly(dipropargylfluorene) derivatives were thermally more stable than poly(dipropargylfluorene) itself, and X-ray diffraction analyses revealed that the polymers are mostly amorphous. The photoluminescence peaks of the polymers were observed at about 457-491 nm, depending on the substituents of fluorene moieties.

• Journal of the Korean earth science society
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• v.40 no.4
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• pp.428-435
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• 2019

In the shallow coastal area, located off the northwestern Taean Peninsula of the eastern Yellow Sea, geoacoustic models with two layers were reconstructed for underwater acoustic experimentation and modeling. The Yellow Sea experienced glacio-eustasy sea-level fluctuations during Quaternary period. Coastal sedimentation in the Yellow Sea was characterized by alternating terrestrial and shallow marine deposits that reflected the fluctuating sea levels. The coastal geoacoustic models were based on data from piston, grab cores and the high-resolution 3.5 kHz, chirp seismic profiles (about 70 line-kilometers, respectively). Geoacoustic data of the cores were extrapolated down to 3 m in depth for geoacoustic models. The geoacoustic property of seafloor sediments is considered a key parameter for modeling underwater acoustic environments. For simulating actual underwater environments, the P-wave speed of the models was adjusted to in-situ depth below the sea floor using the Hamilton method. The proposed geoacoustic models could be used for submarine acoustic inversion and modeling in shallow-water environments of the study area.

• Journal of the Earthquake Engineering Society of Korea
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• v.27 no.3
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• pp.157-162
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• 2023

As a result of active geological investigation of faults in Korea, many Quaternary faults have been identified and some of them were judged to have potential to generate earthquakes. Those faults need to be considered as additional seismic sources in the seismic hazard analysis. When a fault is introduced as a new source, the earthquakes generated by the fault should be removed from the area sources that include any part of the fault, to avoid double counting. In practice, however, double counting cannot completely be avoided as the complete separation of the fault-generated earthquakes from the area sources is impossible due to uncertainties related to the earthquake location, subsurface structures of faults, etc. When a new fault source is introduced, the only constraint is the invariance of earthquake frequency. The maximum earthquake and the Richter-b value should also be subject to change, but there are no competent approaches to estimate the change due to incomplete separation of earthquakes. To gain insight into the effect of a new fault source, an example calculation of the seismic hazard were carried out. The example calculation shows that addition of a new fault source centers seismic hazard around the fault source.

• Textile Coloration and Finishing
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• v.9 no.3
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• pp.42-49
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• 1997

In order to study the dyeability of reactive dyes fixable at neutral pH, three reactive dyes(DYE-NC, DYE-PC, and DYE-LC) were prepared by the reaction of Cibacron Brilliant Red 3B-A with nicotinic acid, pyridine, and lutidine, respectively. FT-IR and UV/Vis spectrophometry were used to identify the dyes prepared. While the maximum absorption wavelength (&{\lambda}_{max}&) of Cibacron Brilliant Red 3B-A was 515nm, the &{\lambda}_{max}& of DYE-NC, DYE-PC, and DYE-LC were 522nm, 525nm, and 536nm, respectively. The &{\lambda}_{max}& was shifted to the longer wavelength by introducing the electron donating groups to the pyridine ring of Cibacron Brilliant Red 3B-A. All of the reactive dyes synthesized showed good exhaustion and fixation property to cotton fabric at higher temperature and neutral pH condition. It was regarded that the quaternary pyridinium ion functionated as the leaving group instead of the chloride ion. Among them, DYE-NC showed the best dyeability at the above condition. It was considered that the electron withdrawing carboxylic acid group in nicotinic acid enhanced the cationic property of nitrogn in pyridine ring, resulting the good reactivity with OH group in cellulose.