• Title/Summary/Keyword: The Quaternary

Search Result 1,248, Processing Time 0.025 seconds

Ion Exchange Modeling in ETA and NH$_3$ Aqueous Solutions (ETA 및 암모니아 수용액에서 이온교환 모델링)

  • 안현경;김상대;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.4 no.3
    • /
    • pp.307-311
    • /
    • 2003
  • The test did for the determine the optimized ratio of cation to anion in mixed ion exchange demineralizers. Binary, ternary, quaternary, and quinary cation and anion adsorption was performed to develop a comprehensive experimental data set from small-volume batch tests to obtain the selectivity coefficients of many cations and anions. The quantitative run time might be estimated by such ion exchange models as semi-empirical mass action and surface complexation models. The demineralizer can be used longer by increasing the ratios of cation to anion exchange resins in the bed.

  • PDF

Method of Recurrence Interval Estimation for Fault Activity from Age Dating Data (연대측정자료를 이용한 단층활동주기 산정 방법)

  • 최원학
    • Proceedings of the Earthquake Engineering Society of Korea Conference
    • /
    • 2001.04a
    • /
    • pp.74-80
    • /
    • 2001
  • The estimation of recurrence interval for fault activity and earthquake is an important input parameter for seismic hazard assessment. In this study, the methods of recurrences interval estimation were reviewed and tentative calculation was performed for age dating data which have uncertainty. Age dating data come from previous studies of Ulsan fault system which is a well developed lineament in the southeastern part of korean Peninsula. Age dating for fault gouges, parent rocks, Quaternary sediments and veins were carried out by several researchers through various methods. Recurrence interval for fault activity was estimated on the basis of the age dating data of minor fault gouge and sediments during past 3Ma. The estimated recurrence interval was about 430-500 ka. Exact estimation of recurrence interval for fault activity need to compile more geological data and fault characteristics such as fault length, amount of displacement, slip rate and accurate fault movement age. In the future, the methods and results of fault recurrence interval estimation should be considered for establishing the criteria for domestic active fault definition.

  • PDF

Microwave-assisted Solvent-free Synthesis of Some Dimethine Cyanine Dyes, Spectral Properties and TD-DFT/PCM Calculations

  • Zhang, Xiang-Han;Wang, Lan-Ying;Zhai, Gao-Hong;Wen, Zhen-Yi;Zhang, Zu-Xun
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.12
    • /
    • pp.2382-2388
    • /
    • 2007
  • A series of dimethine cyanine dyes were synthesized in a fast, efficient and high yield by the condensation of quaternary salts with 1H-indole-3-carbaldehyde in the presence of piperidine under solvent-free microwave irradiation. The products were identified by 1H NMR, IR, UV-Vis spectra and elemental analysis. The absorption and fluorescence properties of these dyes were investigated both experimentally and theoretically. Calculations performed at a combination of time-dependent density functional theory (TD-DFT) and the polarizable continuum model (PCM) reproduced the π-π* type absorption bands of the dyes. Regression analysis was used for studying theoretical results of the absorption maxima in different solvents. Compared with experimental counterparts, estimated overall uncertainties in the absorption maxima were about ±2%.

Experimental fabrication and analysis of thermoelectric devices (복합재료에 의한 열전변환 냉각소자의 개발에 관한 연구)

  • 성만영;송대식;배원일
    • Electrical & Electronic Materials
    • /
    • v.9 no.1
    • /
    • pp.67-75
    • /
    • 1996
  • This paper has presented the characteristics of thermoelectric devices and the plots of thermoelectric cooling and heating as a function of currents for different temperatures. The maximum cooling and heating(.DELTA.T) for (BiSb)$\_$2/Te$\_$3/ and Bi$\_$2/(TeSe)$\_$3/ as a function of currents is about 75.deg. C, A solderable ceramic insulated thermoelectric module. Each module contains 31 thermoelectric devices. Thermoelectric material is a quaternary alloy of bismuth, tellurium, selenium, and antimony with small amounts of suitable dopants, carefully processed to produce an oriented polycrystalline ingot with superior anisotropic thermoelectric properties. Metallized ceramic plates afford maximum electrical insulation and thermal conduction. Operating temperature range is from -156.deg. C to +104.deg. C. The amount of Peltier cooling is directly proportional to the current through the sample, and the temperature gradient at the thermoelectric materials junctions will depend on the system geometry.

  • PDF

Oxidation of TiZrAlN nanocomposite thin films in air at temperatures between 500 and $700^{\circ}C$ (TiZrAlN의 500-$700^{\circ}C$ 사이에서 공기 중 산화)

  • Kim, Min-Jeong;Bong, Seong-Jun;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2011.05a
    • /
    • pp.167-170
    • /
    • 2011
  • Quaternary TiZrAlN nanocomposite thin films with a composition of 20.7Ti-22.2Zr-2.7Al-54.4N (at.%) were deposited by the closed-field unbalanced magnetron sputtering (CFUBMS) method and oxidized in air at temperatures between 500 and $700^{\circ}C$. The oxides formed were $TiO_2$, $ZrO_2$, and $Al_2O_3$. The films had inferior oxidation resistance because the amounts of $ZrO_2$ and $TiO_2$ were large while the amount of $Al_2O_3$ was small. The oxidation progressed primarily by the inward diffusion of oxygen and the outward diffusion of nitrogen.

  • PDF

Electrical and Dielectric Properties, and Accelerated Aging Characteristics of Lanthania Doped Zinc Oxide Varistors

  • Nahm, Choon-Woo
    • Transactions on Electrical and Electronic Materials
    • /
    • v.7 no.4
    • /
    • pp.189-195
    • /
    • 2006
  • The microstructure, electrical and dielectric properties, and stability against DC accelerated aging stress of the varistors, which are composed of quaternary system $ZnO-Pr_6O_{11}CoO-Cr_2O_3-based$ ceramics, were investigated for different $La_2O_3$ contents. The increase of $La_2O_3$ content led to more densified ceramics, whereas abruptly decreased the nonlinear properties by incorporating beyond 1.0mol%. The highest nonlinearity was obtained from 0.5mol% $La_2O_3$, with the nonlinear coefficient of 81.6 and the leakage current of $0.1{\mu}A$. The varistors doped with 0.5mol% $La_2O_3$ exhibited high stability, in which the variation rates of breakdown voltage, nonlinear coefficient, leakage current, dielectric constant, and dissipation factor were -1.1%, -3.7%, +100%, +1.4%, and +8.2%, respectively, for stressing state of $0.95V_{1mA}/150^{\circ}C/24h$.

Fault segmentation along the Ulsan Fault System based on criteria of segment type (단층분절을 정의하는 기준에 따른 울산단층의 분절화)

  • Choi, Weon-Hack;Chang, Chun-Joong;Inoue D.
    • Proceedings of the Earthquake Engineering Society of Korea Conference
    • /
    • 2006.03a
    • /
    • pp.78-85
    • /
    • 2006
  • The Ulsan Fault System continues from north of Gyeongju to Ulsan city, trending NNW-SSE and is about 50 km. Many Quaternary faults have been reported and investigated with outcrop observation. Lineaments have been extracted with aerial photograph interpretation and classified by their ranks. Trench excavations on the lineaments along Ulsan Fault System have been carried out to clarify the neotectonic movements and fault parameters such as the latest movement age, fault displacement, slip rate and recurrence interval. We have compiled data from previous studies on criteria of segment type such as lineament rank, seismicity, slip rate, and the latest fault movement. Based on these data, we tried to devide the Ulsan Fault System into several segments. The results of segmentation with each types of segment along the Ulsan Fault System did not show singular division point but overlapped or different length and location.

  • PDF

암반공학적 측면에서본 신생대 암반비탈면의 공학적 문제 및 대책

  • Shin, Hee-Soon
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2005.10a
    • /
    • pp.285-289
    • /
    • 2005
  • The Cenozoic Era consists of two period , the Tertiary and the Quaternary Period. Weak rock types may include areas containing: 1) poorly cemented or uncemented sediments, 2) highly weathered rock, or 3) fault lines. Especially this paper deal with poorly cemented or uncemented sedimentary rocks in slope. Mechanical weathering is caused by physical processes such as absorption and release of water, and changes in temperature and stress at or near the exposed rock surface. It results in the opening of discontinuities, the formation of new discontinuities by rock fracture, the opening of grain boundaries, and the fracture or cleavage of individual mineral grains. Decomposition causes some silicate minerals such as feldspars to change to clay minerals. There was a strong negative correlation between water absorption and important engineering properties such as strength and durability.

  • PDF

Influence of Selenization Pressure on Properties of CIGS Absorber Layer Prepared by RF Sputtering

  • Jung, Sung Hee;Choi, Ji Hyun;Chung, Chee Won
    • Current Photovoltaic Research
    • /
    • v.4 no.3
    • /
    • pp.87-92
    • /
    • 2016
  • The effects of selenization pressure on the structural, optical and electrical properties of the CIGS thin films prepared by RF magnetron sputtering using a single quaternary target were investigated. At selenization pressures lower than atmospheric pressure, CIGS thin films formed non-stoichiometric compounds due to deficiencies of Se vapor. In contrast, when selenization process was conducted at above atmospheric pressure, the residence time of Se vapor inside the tube increased so that the Se element could be incorporated within vacant sites of the CIGS structure, resulting in the formation of stoichiometric CIGS thin films. High quality CIGS thin films could be obtained when the selenization process was performed at pressures greater than atmospheric and $550^{\circ}C$.

Measurement of Peak-to-Average Power Ratio for HRIT

  • Park Durk-Jong;Yang Hyung-Mo;Ahn Sang-Il
    • Proceedings of the KSRS Conference
    • /
    • 2004.10a
    • /
    • pp.498-500
    • /
    • 2004
  • QPSK (Quaternary Phase Shift Keying) will be adopted as the modulation of HRIT (High Rate Information Transmission) which is transmitted to COMS (Communication, Ocean and Meteorological Satellite) through HPA (High Power Amplifier) in ground segment. Due to the nonlinearity of HPA, IMD (Inter-Modulation Distortion) of multi-carrier signals and PAPR (Peak-to-Average Power Ratio) of modulated HRIT must be considered to estimate the output power of HPA. In this paper, we measured the PAPR to various the roll-off factor of RRC (Root Raised Cosine filter) which is filtering the modulated HRIT signal for reducing ISI (Inter-Symbol Interference) and bandwidth. It was found that the minimum PAPR is 2.78dB at 0.5 of roll-off factor for scrambled data. It's 2.78dB of P APR will be in output power selecting in COMS earth station.

  • PDF