• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.129-134
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• 1999

This study is related to the investigation of the direct incorporation of $CO_2$ to polymer using quaternary ammonium salt catalysts. Quaternary ammonium salts showed good catalytic activity of $CO_2$ fixation in the synthesis of poly[(1,3-dioxolane-2-oxo-4-yl)methyl methacrylate] [poly(DOMA)] by the direct incorporation of $CO_2$ to poly(glycidyl methacrylate)[poly(GMA)]. Among the salts tested, the ones with higher alkyl chain length and with more nucleophilic counter anion showed higher catalytic activity. The yield of carbon dioxide addition increased with the reaction temperature. Kinetic study was carried out by measuring the variation of $CO_2$, pressure in a high pressure batch reactor. The reaction rate was first order to the concentration of poly(GMA) and $CO_2$, respectively. The rate constant was $0.69L/mol{\cdot}h$ and Henry's constant of $CO_2$ in DMSO at $80^{\circ}C$ was $6.8{\times}10^{-4}mol/L{\cdot}KPa$.

• Journal of Food Hygiene and Safety
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• v.22 no.4
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• pp.235-242
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• 2007

This study was conducted to investigate the effect of aerosolized chemical sanitizers on inhibiting foodborne pathogens such as Escherichia coli O157:H7, Salmonella typhimurium, and Listeria monocytogenes. Five domestic commercial sanitizers subjected to five groups of sanitizer (chlorine-based, hydrogen peroxide-based, Iodophor-based, quaternary ammonium-based, and alcohol-based sanitizers) were aerosolized by an aerosol generator into a model cabinet and treated in laboratory media containing three pathogens for 1 h at room temperature. Aerosolized hydrogen peroxide-based and quaternary ammonium-based sanitizers were effective at inhibiting levels of E. coli O157:H7 (ca. 4-9 log reductions) whereas other aerosolized sanitizers such as chlorine-based, Iodophor-based, and alcohol-based sanitizers did not significantly reduced the levels of E. coli O157:H7. For S. typhimurium, the only aerosolized hydrogen peroxide-based sanitizer was effective and resulted in ca. 5-9 log reduction. Aerosolized hydrogen peroxide-based, Iodophor-based, and quaternary ammonium-based sanitizers significantly reduced levels of L. monocytogenes and especially, aerosolized quaternary ammonium-based sanitizer was strongly effective to kill L. monocytogenes, resulted in higher than 8.8 log reduction. And there was no special trend in inhibitory efficacy of sanitizers aerosolized by 1.6 or 2.4 MHz aerosol generators. From these results, aerosolization has great potential for use in commercial applications however it's efficacy could be very different depending on type of sanitizers.

• Journal of the Speleological Society of Korea
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• v.24 no.25
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• pp.1-14
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• 1991

Jeongsun limestone formations with good geochemical solution of limestone and physical environments have been developing many Karst landforms. Especially, there are many dolines and most of them elliptical shapes of planes. At present, they have been transformed into uvala toward their long diameter directions. The period of landscape processing is a Quaternary Epoch and Karst cycle corresponds to a stage from late maturity to old stage.

• Journal of the Korean earth science society
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• v.25 no.5
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• pp.377-377
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• 2004

• YAKHAK HOEJI
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• v.43 no.6
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• pp.696-702
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• 1999

The first and versatile total synthesis of isopimarol diterpene has been achieved via stereoselective construction of C-13 quaternary carbon unit as a key step. Isopimarol diterpene was synthesized from the known decalone in 17% overall yield of 16 steps.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2006.04a
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• pp.153-153
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• 2006

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3847-3850
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• 2013

• Journal of the Korean Regional Science Association
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• v.6 no.2
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• pp.107-121
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• 1990

The structural change of occupational composition with the coming of post-industrial society is most evidently observed in the developed country. Specially representative of social changes is the emergence of new occupational sectors, such as the so-called quaternary and quinary sectors, which are based on the use of information technology and managerial skills. The paper raises the question of how and in what this chage of occupational components in a mtro area affects the existing residential structure over the period. In order to extend the discussion of the question, the related hypothetical statements on urban spatial impact due to transformation of the society have xtnsively considered and identified a possible multicenter structure concentration and deconcentration of new jobs and population over the metro area. For further examination, the renowned high tech city of Minneaplis -St. Paul has been selected and the occupational labour forces data for 1960 and 1980 analyzed. As a whole, this area has experienced a dispersal and reconcentration of population in new patterns which have resulted from changes in the occupational structure. In particular, the residential area of white-coller workers(the quaternary / quinary or information workers) has expanded into the city from a suburban core area. In this process, a large proportion of the manual-worker's residential areas in the central city either disappeared or diminished. Consequently, other isolated centers created by the manualworker residents are emerging in both the central city and suburbs. Thus, the development of mulitple centers or cores based on the distribution of occupational characteristics can be considered as a typical ongoing pattern of metro areas in the Unite States.

• Journal of the Korean earth science society
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• v.43 no.4
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• pp.520-531
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• 2022

The Yellow Sea experienced glacio-eustasy sea-level fluctuations during the Quaternary period. In the middle part of the Yellow Sea, the Quaternary successions were accumulated by alternating terrestrial, paralic, and shallow marine deposits that reflected the fluctuating sea levels. A long core of 69.2 m was acquired at the YMGR-102 site (33°50.1782'N and 123°48.3019'E) at a depth of 72.5 m in the middle of the Yellow Sea. A four-layered geoacoustic model was reconstructed for the sedimentary succession. It was based on seismic characteristics from 3.5 kHz SBP and air-gun seismic profiles and 96 grain-size properties in the core sample from YMGR-102. For the underwater simulation and experiments, the in-situ P-wave speeds were calculated using the sound speed ratio of the Hamilton method. The geoacoustic model of YMGR-102 can contribute to the reconstruction of geoacoustic models, reflecting the vertical and lateral variability of the acoustic properties in the continental shelf of the middle Yellow Sea.

• The Korean Journal of Quaternary Research
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• v.22 no.2
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• pp.1-5
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• 2008

Some reverse fault lines pass through the alluvial fans and west hill slope of Bulguksa mountains including Mt. Toham in the directions of N-S and NW-SE. The study area is known as relatively unstable, because of active faults. Assuming the record of earthquake in the Samguksagi, the architects in the construction of the Bulguksa temple should have recognized the possibility of breakdown from the earthquakes and the need for an unique structure against at that time. Against earthquakes, Greavee technique, a stonework construction technique following woothe one and use of Chushouok (Dongtleouok or Chumchaouok) were applied for the construction of Bulguksa temple. By designing the foundation stone with hole, a structure is prevented from motiff Ction that pillarsakdcede from a foundation stone in spite of horizontal load of earthquake while woot construction isaktrong frame at earthquake. The Bulguksa-temple isausually evaluated to be a beautiful architecture from the appeaultces like the weight balltced structure with unique decoration. ampressive architectures are beautiful in balance and harmony coming from the important and specific rolls in its own way by each part of whole structure. This beauty comes from the science.