• Title/Summary/Keyword: The Quaternary

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Rapidly and Accurately Processing of Low Melting Block for Shielding of Radiotherapy (방사선(放射線) 치료(治療)의 신속정확(迅速正確)을 위한 저온용융(低溫熔融) 차폐물(遮蔽物)의 제작(製作)과 응용(應用))

  • Chu, S.S.;Lee, D.H.;Park, C.Y.
    • Journal of Radiation Protection and Research
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    • v.4 no.1
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    • pp.14-20
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    • 1979
  • For accurate and easily shielding irregular shaped organ, its minimized penumbra region and a low melting point alloy 'Lead Y' and synchronizing instrument have been developed. The 'Lead Y' is the quaternary eutectic alloy and it is composed of Lead 30.0% Tin 11.5% Bismuth 48 5% Cadmium 10.0% The density of its at $22^{\circ}C$ is $9.8g/cm^3$ and the melting temperature has $40^{\circ}C\;to\;68^{\circ}C$. The thickness of 'Lead Y' for perfect shielding of Co-60 gamma ray and LINAC 10MeV x-ray is 6cm and 7cm respectively. The 'Lead Y' shielding block is casted directly on the styrofoam from which is cut with hot wire of synchronizer device. The special features and advantages of the Lead Y shielding block could be summarized as follows; 1. The shielding block for radiotherapy is rapidly processed only with boiling water and styrofoam. 2. It is not injure one's health and not danger of a fire, because of not generating of any metals vapor and evil smelling. 3. It is very effective to minimize secondary penumbra for the protection of healthy tissue from unnecessary ionizing radiation regardless of the magnification source to skin distance. 4. The HVL of the Lead Y is 1.2cm for Co-60 gamma ray and it's shielding effect is almost same as the pure lead block. 5. The hardness of Lead Y is 1.5 times higher than lead block. 6. It's reavailability is higher than lead block and then one block of Lead Y is reavailable about 30 to 40 times. 7. It is usefull for shielding of x-ray, gamma ray, beta-ray, electron and neutron radiation. 8. The materials for Lead Y are easy to acquire with reasonable price and tractable.

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Solderability and BGA Joint Reliability of Sn-Ag-Cu-In-(Mn, Pd) Pb-free Solders (Sn-Ag-Cu-In-(Mn, Pd) 무연솔더의 솔더링성과 BGA 접합부 신뢰성)

  • Jang, Jae-Won;Yu, A-Mi;Lee, Jong-Hyun;Lee, Chang-Woo;Kim, Jun-Ki
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.3
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    • pp.53-57
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    • 2013
  • Although the lowering of Ag content in Sn-3.0Ag-0.5Cu is known to improve the mechanical shock reliability of the solder joint, it is also known to be detrimental to the solderbility. In this study, the quaternary alloying effect of In and the minor alloying effects of Mn and Pd on the solderability, thermal cycling and mechanical shock reliabilities of the low Ag content Sn-1.2Ag-0.7Cu solder were investigated using board-level BGA packages. The solderability of Sn-1.2Ag-0.7Cu-0.4In was proved to be comparable to that of Sn-3.0Ag-0.5Cu but its thermal cycling reliability was inferior to that of Sn-3.0Ag-0.5Cu. While the 0.03 wt% Pd addition to the Sn-1.2Ag-0.7Cu-0.4In decreased the solderability and reliabilities of solder joint, the 0.1 wt% Mn addition was proved to be beneficial especially for the mechanical shock reliability compared to those of Sn-3.0Ag-0.5Cu and Sn-1.0Ag-0.5Cu compositions. It was considered to be due that the Mn addition decreased the Young's modulus of low Ag content Pb-free solders.

New data on Phase Relations in the System Cu-Fe-Sn-S (4성분계 Cu-Fe-Sn-S의 상관관계에 대한 새로운 데이터)

  • Jang, Young-Nam;Moh, Guenter
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.1
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    • pp.43-50
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    • 1991
  • Two solid solution-type phases has been experimentally found in the quaternary system Cu-Fe-Sn-S:$(Fe, Cu, Sn)_{1+x}$ and $Cu_{2-x}Fe_(1+x}SnS_4$. These solid solutions are stable around the CuS-FeS-SnS referecne plane in the composition tetrahedron. One is the sphalerite-type monosulfide solid solution which has a extensive stability range with varying degrees of sulfur/metal ratio 9.7-1.0/1.0. The other is tetrahedrite-type phase $Cu_{2-y)Fe_{1+y}SnS_4(y_{max}=0.4)$ which is stable along the $Cu_2FeSnS_4-FeS$ tie line, but shows no phase transformation in the subsolidus range and decomposes incongruently at the range of 835-862${\circ}C$, depending on the compositional variation. Particularly, the latter phase shows the characteristic superstructure reflections, indicating that it is a derivative of sphalerite structure. The stability field of these two sphalerite-type phases are defined on the basis of diffraction pattern and optical homogeneity of the synthetic materials at the temperature range of 700-400${\circ}C$.

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Surface Checking Reduction Effect of Preservative-treated Korean Larch Round-woods with Various Physical Treatments (물리적 처리에 따른 낙엽송 방부원주목의 표면할렬 방지효과)

  • Pang, Sung-Jun;Oh, Jung-Kwon;Lee, Sang-Joon;Park, Jun-Ho;Jang, Sung-Il;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.1
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    • pp.107-115
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    • 2017
  • In this study, the surface check reduction effect of preservative-treated Korean larch round-wood was investigated by applying three physical treatments, such as incising, kerfing, and kiln-drying. Moreover, the possibility of long-term service life was also checked by comparing the depth of surface check and the penetration depth of preservative. A rapid gradient of wood moisture content between surface and center causes a surface check. Thus, the effect of reducing surface check was carried out at the lowest equilibrium moisture content (EMC) condition, temperature ($2^{\circ}C$), humidity (44.6%), in outdoor locations in Korea until the test specimens reach to the 8.6% EMC. As a result, the preservative-treated specimens without incising, kerfing, kiln-drying (Type C) could not ensure the long-term service life due to a large surface check. Because the surface check depth of all specimens was deeper than the penetration depth of preservative. In case of the incising treated specimens (Type I), 80% of them, the depth of surface check was not deeper than the penetration depth of preservative. However, when a kerfing was additionally treated (Type B), a possibility of happening deeper surface check than penetration depth of preservative was increased rather than Type I.

Properties of Ternary or Quaternary High Strength Concrete Using Silica Fume & Meta Kaolin (실리카퓸과 메타카올린을 사용한 다성분계 고강도콘크리트의 특성)

  • Park, Cho-Bum;Kim, Ho-Su;Jeon, Jun-Young;Kim, Eun-Kyum;Ryu, Deug-Hyun
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.307-315
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    • 2008
  • In this study, it is investigated the properties of high strength concrete using mineral admixture, on the purpose of use of meta kaolin for the substitutive materials to silica fume which is so expensive. The plain mixtures are 3 degrees which are ordinary portland cement, blast furnace slag cement and OPC included fly ash 20%, and silica fume and meta kaolin are substituted for the each plain mixtures in the range of 20%. The results of experiment showed as follows. In case of silica fume was only used, the viscosity and slump flow of fresh concrete were much decreased, on the contrary air content increased. But as usage of meta kaolin increased, to being increase the viscosity of fresh concrete, slump flow increased and air content and usage of super-plasticizer were decreased. Accordingly the workabilities of concrete were against tendency between silica fume and meta kaolin. The compressive strength, velocity of ultrasonic pulse and unit weight were increased according to usage of meta kaolin, the properties of hardened concrete were judged that they are affected with air content of fresh concrete, so it is very important to control air content of high strength concrete. Therefore, the use of meta kaolin is prospected to the substitutive material of silica fume, in case of using silica fume and meta kaolin, it is judged that the optimum usage of silica fume and meta kaolin is about 10% respectively, considering workability and strength of concrete.

The Changing Characteristics of Office Location in Central Seoul (서울 도심 사무활동입지의 변화와 특성)

  • Kee-Bom Nahm
    • Journal of the Economic Geographical Society of Korea
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    • v.1 no.2
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    • pp.85-102
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    • 1998
  • The Changing Characteristics of Office Location in Central Seoul In recent years, central Seoul has been experiencing a dynamic transformation. In the process of reorganization of urban industrial structure including tertiarization and quaternarization of the economic base of Seoul, business services are growing very rapidly and large scale urban renewal projects are agilely implemented. Downtown office activities become a nucleus for economic performance of Seoul and high-rise office buildings steer the landscape transformation of central Seoul. Even though there appear to exist some evidences that office districts have dispersed to several subcenters, major office activities are still concentrated in the central Seoul. This paper redefines office industry in a narrow meaning comprising only relevant economic sectors and office buildings as office activity-functioning units. It then explores the industrial networking and territorial specialization of office activities focusing on the dual process of concentration and dispersion in Seoul. The changing characteristics of the downtown linkages of office activities in this post-industrial era transforms the spatial economy of central Seoul into more flexible and volatile, while territorial concentration of power and control functions are fortified at the same time. Finally, the paper addresses the development of manufacturing-tertiary-quaternary industrial complex, which can be regarded as new industrial clusters, selling cultural economy of urban space and possessing placeness or images for clients and customers, in relation to urban competitiveness and territorial specialization of large metropolitan areas.

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Mineralogy, Geochemistry, and Formation of Ferromanganese Nodules from the KONOD-1 Site, Northeastern Equatorial Pacific (북동(北東) 적도(赤道) 태평양(太平洋)(KONOD-1) 망간 단괴(団塊)의 은물조성(銀物組成), 화학분석(化學成分)과 성인(成因))

  • Kang, Jung-Keuk;Han, Sang-Joon
    • 한국해양학회지
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    • v.23 no.3
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    • pp.110-122
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    • 1988
  • Between the Clarion and Clipperton fracture zones of the Northeastern Pacific, nodules and crusts were collected from abyssal plain and hills by the Korea Ocean Research and Development Institute in December, 1983 aboard the R/V KANA KEOKI of the Hawaii Institute of Geophysics. Mineralogical and geochemical data of bulk nodules are obtained and compared with analyses of other studies. Mechanisms of nodule formation are discussed based on these data. Generally, the nodules of the KONOD-1 site are composed of todorokite and ${\delta}-MnO_2$. The contents of Mn, Fe, Ni, and Cu of the bulk nodules are variable and the average contents of metals are slightly lower (Mn, 21.40%; Ni, 0.9%; Cu, 0.8%) than those of nodules from other abyssal plains between the Clarion and Clipperton fracture zones. High Mn/Fe (average 3.9; maximum 5.9) and Cu/Ni (average 0.8; maximum 1.0) ratios are similar to the nodules that were formed diagenetically in the northeast Pacific. The chemical characteristics of the KONOD-1 nodules reflect their sedimentary environments; nodules with higher diagenetic signatures occur in areas of thin Quaternary siliceous ooze, and nodules of lower diagenetic influence occur in topographically irregular abyssal hill areas.

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High-resolution Echo Facies Analysis of Sedimentary Deposits around Dok-Island Volcanoes (독도 화산군 주변 퇴적층의 고해상 탄성파상 분석)

  • Lee, Yong-Kuk;Han, Sang-Joon;Yoon, Seok-Hoon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.2
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    • pp.103-113
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    • 2001
  • This study presents Quaternary sedimentation pattern around Dok-Island volcanoes (Dok Island and Dok Seamount), based on analysis of high-resolution (chirp) echo characters. Echo facies If, showing sharp, continuous bottom echo without subbottom reflectors, is recorded mainly from the flat tops of the volcanoes. This facies indicates sands and gravels (re) deposited by shallow marine processes. Echo facies IIA in the basin floor and basal slopes of the volcanoes and Oki Bank is characterized by semi-prolonged bottom and several parallel subbottom echoes. This facies reflects hemipelagic settling with intermittent influences of turbidity currents in the slope areas. Echo facies IIC is recorded from acoustically-transparent debrite masses on the basal slopes of the volcanoes and Oki Bank. Echo facies IIIA is characterized by irregular hyperbolic echoes in the slope areas of the volcanoes. It suggests hard rock basement or irregular volcanic edifices. Echo facies IIIC shows regularly-overlapping hyperbolic bottom echoes. It is interpreted to represent rock-fall deposits (talus) accumulated in the mid-slope area. Echo characters and topography suggest that the tops of Dok-Island volcanoes were flattened and lowered by shallow-marine erosional processes. The eroded sediments were transported to and deposited in the base of slope and basin plain mainly by debris flows and turbidity currents along submarine canyons and valleys.

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Effects of N-/C-Terminal Extra Tags on the Optimal Reaction Conditions, Activity, and Quaternary Structure of Bacillus thuringiensis Glucose 1-Dehydrogenase

  • Hyun, Jeongwoo;Abigail, Maria;Choo, Jin Woo;Ryu, Jin;Kim, Hyung Kwoun
    • Journal of Microbiology and Biotechnology
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    • v.26 no.10
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    • pp.1708-1716
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    • 2016
  • Glucose dehydrogenase (GDH) is an oxidoreductase enzyme and is used as a biocatalyst to regenerate NAD(P)H in reductase-mediated chiral synthesis reactions. In this study, the glucose 1-dehydrogenase B gene (gdhB) was cloned from Bacillus thuringiensis subsp. kurstaki, and wild-type (GDH-BTWT) and His-tagged (GDH-BTN-His, GDH-BTC-His) enzymes were produced in Escherichia coli BL21 (DE3). All enzymes were produced in the soluble forms from E. coli. GDH-BTWT and GDH-BTN-His showed high specific enzymatic activities of 6.6 U/mg and 5.5 U/mg, respectively, whereas GDH-BTC-His showed a very low specific enzymatic activity of 0.020 U/mg. These results suggest that the intact C-terminal carboxyl group is important for GDH-BT activity. GDH-BTWT was stable up to 65℃, whereas GDH-BTN-His and GDH-BTC-His were stable up to 45℃. Gel permeation chromatography showed that GDH-BTWT is a dimer, whereas GDH-BTN-His and GDH-BTC-His are monomeric. These results suggest that the intact N- and C-termini are required for GDH-BT to maintain thermostability and to form its dimer structure. The homology model of the GDH-BTWT single subunit was constructed based on the crystal structure of Bacillus megaterium GDH (PDB ID 3AY6), showing that GDH-BTWT has a Rossmann fold structure with its N- and C-termini located on the subunit surface, which suggests that His-tagging affected the native dimer structure. GDH-BTWT and GDH-BTN-His regenerated NADPH in a yeast reductase-mediated chiral synthesis reaction, suggesting that these enzymes can be used as catalysts in fine-chemical and pharmaceutical industries.

Characteristics of Landslide Occurrence and Change in the Matric Suction and Volumetric Water Content due to Rainfall Infiltration (강우침투에 의한 산사태 발생 및 모관흡수력과 체적함수비의 변화 특성에 관한 연구)

  • Seo, Won-Gyo;Choi, Junghae;Chae, Byung-Gon;Song, Young-Suk
    • The Journal of Engineering Geology
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    • v.27 no.4
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    • pp.475-487
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    • 2017
  • We performed landslide flume tests to analyze characteristics of landslide occurrence and change in the ground materials due to rainfall infiltration. The test apparatus is composed of flume, rainfall simulator, and measurement sensors and landslides were triggered by heavy rainfall (Intensity=200 mm/hr) sprinkled at the above of an artificial slope. The measurement sensors for matric suction and volumetric water content were installed with 3 sets at shallow (GL-0.2 m), middle (GL-0.4 m), and deep depth (GL-0.6 m) in the slope and the tests were performed with in-situ, loose, and dense condition of each weathered soils of granite, gneiss, and mudstone. The analyses show that surface erosion was dominant in initial time of the test due to heavy rainfall and then landslides occur following locally happened transverse tension cracks. The characteristics of landslide were both shallow failure because of a spread of wetting front induced by the rainfall infiltration and retrogressive failure. While the matric suction was decreased rapidly without any precursor in the soil saturation, the volumetric water content was increased gradually, reached its maximum value, and then decreased rapidly with landslide.