• 한국의류산업학회지
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• 제24권6호
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• pp.801-811
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• 2022

In this study, we constructed a database of dyeing concentrations of all reactive dyes used for dyeing linen according to the thickness of the linen fabric and attempted to improve the reproducibility of the dyeing process for the commercialization of linen fabric materials. Linen fabric is a natural cellulose material that is comfortable and suitable for eco-friendly trends. It is a typical summer material with excellent breathability and thermal conductivity, quick moisture absorption and dissipation, and a cool touch. Dyeability and fastness were evaluated depending on the thickness of the linen fabric using a monochlorotriazine (MCT) reactive dye and bifunctional yellow, red, and blue dyes. All three colors of the MCT reactive dye and bifunctional dyes exhibited a darker shade as the fiber thickness of the marker increased. Fastness to washing was excellent at grades 4-5 or higher, regardless of the color of the dye and the number of linen fabrics. Although some color-fastness differences were noted, with the color change occurring most frequently with blue color, the fastness variations with dye type were mostly similar. The results of this study are expected to facilitate the selection of reactive dyes according to the thickness of the linen fabric based on the basic data from the laboratory, which will aid in the mass production of linen fabric and benefit the fashion industry.

• 한국염색가공학회지
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• 제27권4호
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• pp.270-274
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• 2015

Molecules always show broad absorption band envelopes, and this results from the vibrational properties of bonds. The width of an absorption band can have an important influence on the color of a dye. A narrow band imparts a bright, spectrally pure color to the dye, whereas a broad band can give the same hue, but with a much duller appearance. Typically, half-band widths of cyanine dyes are about 25nm compared to value of over 50nm for typical merocyanine dyes. Thus, cyanine dyes are exceptionally bright. The factors influencing the width of an absorption band can be understood with reference to the Morse curves. The width of the absorption band depends on how closely the bond order of the molecules in the first excited state resembles that in the ground state. We have quantitatively evaluated the "molecular structure-absorption band shape" relationship of dye molecules by means of Pariser-Parr-Pople Molecular Orbital Method(PPP-MO).

• 한국염색가공학회지
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• 제24권2호
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• pp.97-105
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• 2012

Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/$cm^2$. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.

• 한국염색가공학회지
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• 제6권4호
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• pp.46-53
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• 1994

Polymer cationic agent was prepared by the initial polymerisation of epichlorohydrin followed by amination with diethylamine. Cotton fibre treated with the polymer (6~8% o.w.f.) is highly cationic and exhibit increased substantivity for reactive dyes under neutral to weakly acid conditions. The modified substrate could be dyed with reactive dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of Reactive dye can be attributed to both van der waals force and electrostatic attraction.

• 한국의류산업학회지
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• 제1권4호
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• pp.363-369
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• 1999

Artemisia princeps was used for the natural dye stuff extraction and concentration to produce the condensed dye liquid. Using this liquid, the silk and the cotton fabrics were dyed. And then the K/S value, color difference were measured in order to determine the dyeability and the antimicrobial activity. The K/S value of silk were much higher than those of cotton. In terms of the silk fabric, the premordanting method was most efficient of the mordanting method. The various surface colors on the dyed fabric were resulted according to used mordants and mordanting methods. The dye fastness was significantly improved when mordants were added. Among them, Cr-mordant improved more than 1 level. The Cu-mordant showed the greatest antimicrobial activity on both of mordant treated silk and cotton.

• 한국염색가공학회지
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• 제4권4호
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• pp.104-109
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• 1992

양모의 반응성 방염처리제(DRB, DRM, DRS, DRN)를 합성하고 이들과 sulphamic acid(SA)를 방염(dye resist) mechanism을 이용하여 방오처리에 응용, 그 효과를 검토하였다. 방오효과는 SA>DRB>DRM>DRS>DRN의 순으로 우수하였다. DCCA처리 양모의 경우는 SA처리 양모만이 방오효과를 나타내었다. 4종류의 합성된 반응성 방염처리제는 DCCA 처리 앙모에 dye assist 효과를 나타내었다. 80% 이상의 방오효과만이 시각적으로 오염을 구분할 수 없었으므로 SA 처리방법은 방오가공에 응용 가능하나, DRB 처리법은 약간의 개선이 필요했다. 이러한 방염처리방법을 방오가공에 응용할 때에 양모 carpet 등의 습윤오염(커피나 쥬스 등 색소성 오염)의 감소효과가 기대 되어 진다.

• 한국염색가공학회지
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• 제8권5호
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• pp.17-24
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• 1996

Dye solutions were tested in order to find the optimal condition of ozonation and determine the progress of degradation, i.e., change of the parameters characterizing the dye solutions. From the results of our experiment we can conclude that almost all of the color was removed within a 10 minute time period. An ozone oxidation results in the effective removal of COD(60%). but the elimination of the total organic carbon(TOC) was not successful, only about 15~40% of TOC was removed from dyeing wastewater in 30 minutes. The color removal is much effective in using ozonation method.

• 한국염색가공학회지
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• 제9권6호
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• pp.1-9
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• 1997

Four aminoazobenzene disperse dyes derived from different N-ethyl-N-substitutedalkylanilines and 2-chloro-4-nitroaniline, were synthesized and their chemical structure were analyzed by 500 MHz NMR spectroscopy. The wavelength of maximum absorption of the synthesized dyes, which was dependent on the electron withdrawing ability of the substituent, was in the range of 499.5~526.0nm. As terminal substituent became polar, the dyeing rate of disperse dye increased, and the exhaustion rate of dyes having cyano or hydroxy group became lower, that of the dye having acetoxy group higher. The wash fastness of polyester fabric dyed with disperse dyes possessing the polar group improved probably due to the increased dye-fiber interaction.

• 한국염색가공학회지
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• 제19권5호
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• pp.17-23
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• 2007

As polyvinyl alcohol(PVA) filament yarn is commercially used in many fields due to its high strength and modulus properties. This research was carried out to study the dyeing behavior of PVA and to find out appropriate dye for better dyeing. As the dyeing behavior of PVA fiber is similar to cellulose due to the same functional group, reactive and vat dyes were selected for the dyeing. Color strength of PVA fibers treated with vat dyes was found to be better than those with reactive dyes, because of the low fixation of reactive dye on fibers. Most of the reactive dye may became hydrolyzed, and flushed away with water in washing. Colorfastness to laundering was shown to be very high for both of the reactive-dyed and vat-dyed PVA fibers.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.36-36
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• 2011

We synthesized new dye sensor based on indole compound. Through the UV-vis absorptions, we analyzed chemosensing properties to explain metal binding properties. The peak absorptions increased at 472 nm when added metal cations($Cd^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Fe^{2+}$, $Zn^{2+}$, $Ni^{2+}$ and $Cr^{3+}$) and gradually decreased the peak at 516 nm. Thus, this UV-Vis absorption behavior clearly showed the metal binding reaction. To measure energy level of used dye sensor, HOMO/LUMO energy value was calculated with cyclovaltagramm(CV) and using computational calculation method, in which we estimated the optimum structure of dye sensor. CV and computational calculation method, both compared to find suitable geometric structure. (with almost same energy values.) From the computational calculation, dye sensor has plane structure. So, Amine and ketone in the dye sensor faced each other and makes position to bind metal cations. In addition, these positions was supported pull-push electron system and generated MLCT process, when the dye sensor was bonded with the metal cations and resulted chemosensing properties. Through the electrochemical and computational calculation method analyze, we proposed the chemosensing principles that the dye sensor bind the metal cation between ketone and amine. Finally, the formation type of metal ion bindings was determined by Job's plot measurements.