• Proceedings of the Korean Fiber Society Conference
• /
• 1998.10a
• /
• pp.236-239
• /
• 1998

The in situ composites based on poly(ethylene 2,6-naphthalate) and thermotropic liquid crystalline polymer (LCP) have been an area of increasing interest and study, since LCP exhibits high chemical stabilities and excellent thermo mechanical properties such as high strength and modulus. In a binary, however, poor compatibility and interfacial adhesions between two phases frequently results in deteriorated mechanical properties. (omitted)

• Fibers and Polymers
• /
• v.4 no.4
• /
• pp.156-160
• /
• 2003

Poly(ethylene 2,6-naphthalate) (PEN)/Poly(ethylene glycol) (PEG) copolymers were synthesized by two step reaction during the melt copolymerization process. The first step was the esterification reaction of dimethyl-2,6-naphthalenedicarbox-ylate (2,6-NDC) and ethylene glycol (EG). The second step was the condensation polymerization of bishydroxyethylnaphthalate (BHEN) and PEG. The copolymers contained 10 mol% of PEG units with different molecular weights. Structures and thermal properties of the copolymers were studied by using $^1{H-NMR}$, DSC, TGA, etc. Especially, while the intrinsic viscosities of PEN/PEG copolymers increased with increasing molecular weights of PEG, but the glass transition temperature, the cold crystallization temperature, and the weight loss temperature of the copolymers decreased with increasing molecular weights of PEG. Consequently, the hydrophilicities by means of contact angle measurement and moisture content of the copolymer films were found to be significantly improved with increasing molecular weights of PEG.

• Fibers and Polymers
• /
• v.6 no.2
• /
• pp.156-161
• /
• 2005

The gray line-profile method is introduced to find fabric density. Some patterned fabrics like stripe design as well as solid fabrics of basic weave structures are used to verify the efficiency and accuracy of the method. The approach is compared with Fourier transform method. Although the gray line-profile method is concise, it shows good results in both solid and patterned fabrics. In addition, it does not require a pre-processing or filtering technique in space or frequency domain to enhance the image suitable for the analysis. However, the approach is slightly influenced by the filter size for finding the local minimums of profile graph.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.448-456
• /
• 2014

A series of seven Ru(II) complexes bearing NHC ligands have been synthesized. The electronic structures of these complexes were analysed by spectroscopic and electrochemical methods and further examined by theoretical calculations. Data show that absorption maxima are dependent on the HOMO level rather than the HOMO-LUMO gaps.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.407-414
• /
• 2014

Polyacrylonitrile (PAN) copolymers with different methyl acrylate (MA) contents were synthesized via solution polymerization and used as precursors for high-performance PAN ultrafine fibrids. The chemical structures of the copolymers were characterized using Fourier-transform infrared spectroscopy and $^{13}C$ nuclear magnetic resonance spectroscopy. Their particle sizes and aspect ratios increased with increasing viscosity, and the degree of crystallinity increased with decreasing concentration of copolymer solution. In contrast, their peak temperature and heat of exotherm increased with decreasing concentration of the copolymer solution. The aromatization indices (AIs) of the fibrids increased with increasing heat-treatment time; however, the AIs decreased when the heat-treatment temperature was higher than the onset temperature of the copolymers. On the other hand, the crystal sizes of the fibrids decreased with increasing concentration of the copolymer solution when the MA content was held constant.

• Fibers and Polymers
• /
• v.3 no.4
• /
• pp.140-146
• /
• 2002

Non-genotoxic diamines 2,2'-dimethyl-5,5'-dipropoxybenzidine and 5,5'-dipropoxy-benzidine were employed as potential alternatives to benzidine in the synthesis and evaluation of new direct dyes for cotton. Assessment of the resultant dyes indicated that both diamines can be used to prepare new direct dyes having colors and fastness properties that make them comparable to commercial direct dyes, and that the structures of the new direct dyes can be confirmed by negative ion electrospray mass spectrometry (ESMS). The mutagenic properties of new direct dyes were established using the standard Ames Salmonella mammalian mutagenicity assay.

• Fibers and Polymers
• /
• v.1 no.2
• /
• pp.71-75
• /
• 2000

Intermolecular cyclization of 2-alkylamino-3-chloro-5,6-dicyanopyrazine 2 in the presence of tributylamine in N,N-dimethylformamide (DMF) gave 5,10-disubstituted-2,3,7,8-tetracyano -5,10-dihydrodipyrazino〔2,3-b:2',3'-e]pyrazines 3, which showed strong mesomorphic property and were anticipated as new chromophoric system for functional dye materials. Absorption spectra, fluorescent properties and other physical properties were correlated with their chemical structures. Vanadyl oligomeric porphyrazine with long alkyl groups synthesized from 3 had satisfactory solubility in tetrahydrofuran (THF), diethyl ether and dimethylsulfoxide (DMSO). The syntheses and characterization of vanadyl polymeric porphyrazines derived from 3 with long alkyl groups are reported.

• The Research Journal of the Costume Culture
• /
• v.22 no.1
• /
• pp.16-27
• /
• 2014

This study investigated the characteristics of and changes in hemp textile production practices at Gurye in Jeollanam-do in modern times. To do this, in this study, both a literature review and fieldwork research were utilized as research methods. The literature review focused on Gurye's hemp data, and the fieldwork research involved two separate trials. Male and Female residents of Gurye who had experience in the area of hemp production from the 1920s to the 1980s participated in this study. The results were as follows. First, regarding hemp fiber cultivation in Gurye, hemp cultivation continued to the 1970s and there were no changes in hemp cultivation practices during the Japanese colonial-era. Second, there have been very important changes in hemp kilns over time. In the 1950s, there were both single-body kilns and separate-body kilns in Gurye. Later, specifically in the 1950s, a new type of kiln using an iron pot appeared, and the most modern kilns were concrete structures. Third, in Gurye, women cooperatively removed hemp husks immediately after stemming, subsequently bleaching the hemp by soaking it in lye or caustic soda. Over time, there have been changes in ash types and in soaking periods. Fourth, loom types changed from the traditional Korean back-strap loom to the treadle loom in the 1930s- to 1940s. Fifth, since the 1970s, the hemp textile output levels of Gurye have been reduced due to the westernization of clothing styles, the inflow of Chinese hemp fiber and government regulations pertaining to hemp cultivation.

• Composites Research
• /
• v.16 no.2
• /
• pp.33-40
• /
• 2003

In order to overcome one of the most pronounced shortcomings of conventional laminated composites, such as the low damage tolerance due to delamination, the thermoplastic materials and 3D (three-dimensional) preforms have been utilized in the manufacture of composite materials. From the newly developed process termed as the co-braiding, hybrid yarns of the thermoplastic fibers (PEEK) and reinforcing fibers (carbon) have been fabricated. In order to further enhance the delamination suppression, through thickness fibers have been introduced by way of 3D weaving technique in the fabrication of textile preforms. The preforms have been thermoformed to make composite materials. Complete impregnation of the PEEK into the carbon fiber bundles has been confirmed. For the comparison of mechanical performance of 3D woven composites, quasi-isotropic laminates using APC-2/AS4 tapes have been fabricated. Tensile and compressive properties of both the composites have been determined. Furthermore. the open hole, impact and CAI(Compression After Impact) tests were also carried out to assess the applicability of 3D woven textile reinforced thermoplastic composites in aerospace structures.

• The Korean Fashion and Textile Research Journal
• /
• v.22 no.2
• /
• pp.233-239
• /
• 2020

We proposed a simple process of fabricating electroconductive textiles by coating conductive polymer PEDOT:PSS (Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)) on biocompatible PLA (Poly Lactic Acid) nanofiber web for application to smart healthcare. Electroconductive textiles were obtained by a drop-coating process using different amounts of PEDOT:PSS solutions., DMSO (dimethyl sulfoxide) was then used as an additive in the post-treatment process to improve conductivity. The surface morphology of the specimens was observed by FE-SEM. The chemical structures of the specimens were characterized using FTIR. The electrical properties (linear and sheet resistance) of the specimens were measured. The effect of the bending angles on the electrical properties was also investigated to confirm their applicability as wearable smart textiles. FE-SEM and FTIR analysis confirmed that the deposition of PEDOT:PSS on the PLA nanofiber web surface was successful. The conductivity of the PEDOT:PSS/PLA nanofiber web was enhanced up to 1.5 ml with an increasing amount of PEDOT:PSS solutions, but there was no significant difference at 2.0 ml. The optimum condition of PEDOT:PSS deposition was established to 1.5 ml. Even when the specimen coated with 1.5 ml was bent every 30°, the change in the electrical resistance values was still low within 3.7 Ω. It confirmed that stable electrical performance was maintained and proved the applicability as a flexible textile sensor.