• Title/Summary/Keyword: Tertiary structure

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The granite in Korean peninsula and its Geotechnical characteristics (한반도에 분포하는 화강암과 화강암반의 지질공학적 특성)

  • Lee, Byung-Joo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.875-883
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    • 2008
  • The amount of granite distribution area occupies about 40 - 50% of Korean Peninsula. The granite irregularly Intruded through preCambrian to Tertiary times but in Jurassic time so called, Daebo granite most widely crops out in Korean Peninsula. In addition to Bulkuksa Grante which intruded at Cretaceous time crops out at the southern part of Korean Peninsula and in northern part Triassic Songrim Granite is distributed. These granites have equigranular texture and are relatively isotropic. Their uniaxial compressive strength is above $1,500kg/cm^2$ and also seismic velocity is over 2,000m/sec. When these rocks receive a weathering action, the feldspar weathers first and the quartz grains remain plentifully to make the "Masato(Korean name)". Also when the granite receives a weathering action, quite often it make sheeting joint which is topographically parallel to the earth surface and also make a (so called, onion structure. These weathering phenomena easily make a land sliding when it is heavy rain and weathering surface is irregular.

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Synthesis and Characterization of New Tetraaza Macrocycles Bearing Two or Four N-Methoxyethyl Pendant Arms and Their Copper(II) and/or Nickel(II) Complexes

  • Kang, Shin-Geol;Kim, Hyun-Ja;Kwak, Chee-Hun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2701-2704
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    • 2010
  • This work shows that both L2 and L3 bearing two and four N-$(CH_2)_2OCH_3$ groups, respectively, can be prepared selectively by the reaction of $L^1$ with 1-bromo-2-methoxyethane. The di-N-substituted macrocycle $L^2$ readily forms its copper(II) and nickel(II) complexes. The N-$(CH_2)_2OCH_3$ groups in $[CuL^2]^{2+}$ are coordinated to the metal ion, whereas those in $[NiL^2]^{2+}$ are not involved in coordination. Interestingly, $L^3$ reacts with $Cu^{2+}$ ion to form $[Cu(HL^3)]^{3+}$, in which one tertiary amino group is not involved in coordination.

The Second Study on the Effectiveness of Nursing Organization (간호조직 효과성에 관한 2차 연구)

  • 박영주;이숙자;장성옥
    • Journal of Korean Academy of Nursing
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    • v.27 no.2
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    • pp.253-263
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    • 1997
  • This second study on the effectiveness of nursing organization was designed to test the relationships between effectiveness of nursing organizations and structural variables that had been significant variables in the first study, the group design variable and the personal characteristic variables that had not been analyszed in the first study based on personal resource productivity model. The data were collected through self-reported questionnaires completed by 605 nurses working in hospitals in seoul and 782 patients being hospitalized in 5 tertiary hospitals in Seoul. The results showed that according to the canonical correlation analysis, the managing job design, nursing delivery system. nurse's age, career. and formalization were revealed as predicting variables of a nurses' job satisfaction and patients satisfaction among the five hospitals. Hospitals in which the team nursing method was used showed a higher score in nurses' job satisfaction and patient satisfaction than in hospitals which used the functional nursing model.

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Development and Morphology of pelvetia siliquosa Tseng et Chang (Phaeophyta) In Culture

  • Yoon, Jang-Taek;Gong, Young-Gun;Chung, Gyu-Hwa
    • Journal of Aquaculture
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    • v.16 no.1
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    • pp.37-43
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    • 2003
  • The present study reports morphology and developmental pattern off siliquosa cultured in a laboratory condition. The zygote was spherical with a diameter of 85 ${\mu}{\textrm}{m}$. During development the polarized zygote divided horizontally and the lower daughter cell divided horizontally into 2 cells. The upper cell was divided repeatedly in horizontal and vertical directions to form a cylinder-like structure, which subsequently developed into secondary and tertiary dichotomous branches. Optimum temperature for zygote release and fertilization was 25C. Injury inflicted by slicing was cured by epidermal differentiation, and adventitious branches; the branches emerging from the pith cells, however, developed no rhizoid. Adventitious branch formation rate was over 88% in all plates supplemented with 0.5 mg/L IAA and peaked at 98% under 0.5 mg/L IAA plus 0.5-5.0 mg/L NAA treatment. NAA stimulated the differentiation of adventitious branches at a wide range of concentrations, while IAA, 2,4-D and kinetin exhibited dose-dependent stimulation.

Probing the Movement of Helix F of $\alpha_1$-Antitrypsin

  • Baek, Je-Hyun;Kim, Jun;Yu, Myeong-Hee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2002.06b
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    • pp.31-31
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    • 2002
  • $\alpha$$_1$-Antitrypsin is a member of the serine protease inhibitor (serpin) family that share a common tertiary structure. The reactive site loop (RSL) of serpins is exposed at one end of the molecule for protease binding. Upon cleavage by a target protease, the RSL is inserted into the major $\beta$-sheet A, which is a necessary process for formation of a tight inhibitory complex.(omitted)

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Thermodynamic Studies on the Interaction of Copper Ions with Carbonic Anhydrase

  • Sarraf, N.S.;Mamaghani-Rad, S.;Karbassi, F.;Saboury, A. A.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1051-1056
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    • 2005
  • The interaction of bovine carbonic anhydrase II with copper ions was studied by isothermal titration microcalorimetry, circular dichroism, UV spectrophotometry and temperature scanning spectrophotometry methods at 27 ${^{\circ}C}$ in Tris buffer solution at pH = 7.5. It was indicated that there are three non-identical different binding sites on carbonic anhydrase for $Cu^{2+}$. The binding of copper ions is exothermic and can induce some minor changes in the secondary and tertiary structure of the enzyme, which does not unfold it, but can result in a decrease in both activity and stability of the enzyme.

Analysis of the Structure-stability Relationship of Cold-adapted Lipase PsLip1 from Homology Modeling

  • Choo, Dong-Won
    • Genomics & Informatics
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    • v.9 no.2
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    • pp.79-84
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    • 2011
  • Two initial models of cold-adapted lipase PsLip1 have been constructed, based on homology with the bacterial lipases Chromobacterium viscosum (CvLip) and Pseudomonas cepacia (PcLip), whose X-ray structures have been solved and refined to high resolution. The mature polypeptide chains of these lipases have 84% similarity. The models of Mod1 and Mod2 have been compared with the tertiary structures of CvLip and PcLip, respectively, and analyzed in terms of stabilizing interactions. Several structural aspects that are believed to contribute to protein stability have been compared: the number of conserved salt bridges, aromatic interactions, hydrogen bonds, helix capping, and disulfide bridges. The 3-dimensional structural model of PsLip1 has been constructed in order to elucidate the structural reasons for the decreased thermostability of the enzyme in comparison with its mesophilic counterparts.

Ring-Opening Reaction of 2,2-gem-Diphenylaziridine (2,2-gem-Diphenylaziridine의 開環反應)

  • Hahn, Chi-Sun;Nam-Goong, Ha-Il;Kang, Yong-Ik
    • Journal of the Korean Chemical Society
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    • v.13 no.3
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    • pp.229-232
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    • 1969
  • A study of the ring-opening reaction of 2,2-gem-diphenylaziridine by treating with acetic acid has been undertaken. The structure of the ring-opened product was confirmed as 1,1-diphenyl-2-aminoethyl acetate. It is most likely that the reaction proceeds through the cleavage of a bond between nitrogen and tertiary carbon atoms in the aziridine ring, followed by the formation of a carbonium ion intermediate.

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Solution Polymerization of Acrylonitrile Using a Cosolvent System (DMSO/TBA) (혼합 용매계 (DMSO/TBA)를 이용한 아크릴로니트릴의 용액 중합)

  • ;;;Kim Bum-Sik
    • Textile Coloration and Finishing
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    • v.15 no.3
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    • pp.127-131
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    • 2003
  • Acrylonitrile(AN) was solution-polymerized in dimethyl sulfoxide(DMSO) and tertiary butyl alcohol(TBA) at 30, 40, $50^\circ{C}$ using a low temperature initiator, 2,2'-azobis(2,4-dimethylvaleronitrile) (ADMVN). The low temperature polymerization using ADMVN, DMSO, and TBA is to be successful in obtaining high molecular weight polyacrylonitrile(PAN) with less branches by solution polymerization. Throug a polymerization of AN in DMSO at $30^\circ{C}$, PAN having viscosity-average molecular weight$(M_v)$ of 931,000 was obtained. And then, during AN solution polymerization in DMSO and TBA using a cosolvent system the in-situ formation of microfibrillar structure has been discovered at the cosolvent composition of 24/1$(V_{DMSO}/V_{TBA})$. The simultaneous process of gelation and phase separation of long chain molecules may explain the in-situ formation of PAN fibers during polymerization.

Studies on the Synthesis of Diphenylphenylamidophosphate for Flame retandant agents of EPS and It's the effect of Flame Retardandy and properties in panel production (방염스티로폴 약제 개발과 방염판넬 생산시 물성에 관한 연구)

  • Lee, Kwang-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.2
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    • pp.185-191
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    • 2001
  • Diphenylpropylamidophosphate(DPPAP) was synthesized as flame retardant for Expanded Polystyrene(EPS). Structure of DPPAP was investigated by the m, NMR, DSC. We make FR panels with EPS beads which treated with DPPAP and expanded by expand machines. FR panels were used in this study after formation by form machines and then cutting by cutting machines. The following conclusions were obtained: 1. The new synthetic agent was developed without the use of solvent such as pyridine or tertiary amine in the synthesis of DPPAP which served as flame retardant for EPS. 2. The flame retandancy effect of EPS treated with DPPAP was found excellent in LOI tests. 3. The properties of FR EPS panels treated with DPPAP did not difference.

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