• Title/Summary/Keyword: Ternary Separation

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A study on the interfacial reactions between electroless Ni-P UBM and 95.5Sn-4.0Ag-0.5Cu solder bump (무전해 Ni-P UBM과 95.5Sn-4.0Ag-0.5Cu 솔더와의 계면반응 및 신뢰성에 대한 연구)

  • ;;Sabine Nieland;Adreas Ostmann;Herbert Reich
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.85-91
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    • 2002
  • Even though electroless Hi and Sn-Ag-Cu solder are widely used materials in electronic packaging applications, interfacial reactions of the ternary Ni-Cu~Sn system have not been known well because of their complexity. Because the growth of intermetallics at the interface affects reliability of solder joint, the intermetallics in Ni-Cu-Sn system should be identified, and their growth should be investigated. Therefore, in present study, interfacial reactions between electroless Ni UB7f and 95.5Sn-4.0Ag-0.5Cu alloy were investigated focusing on morphology of the IMCs, thermodynamics, and growth kinetics. The IMCs that appear during a reflow and an aging are different each other. In early stage of a reflow, ternary IMC whose composition is Ni$_{22}$Cu$_{29}$Sn$_{49}$ forms firstly. Due to the lack of Cu diffusion, Ni$_{34}$Cu$_{6}$Sn$_{60}$ phase begins growing in a further reflow. Finally, the Ni$_{22}$Cu$_{29}$Sn$_{49}$ IMC grows abnormally and spalls into the molten solder. The transition of the IMCs from Ni$_{22}$Cu$_{29}$Sn$_{49}$ to Ni$_{34}$Cu$_{6}$Sn$_{60}$ was observed at a specific temperature. From the measurement of activation energy of each IMC, growth kinetics was discussed. In contrast to the reflow, three kinds of IMCs (Ni$_{22}$Cu$_{29}$Sn$_{49}$, Ni$_{20}$Cu$_{28}$Au$_{5}$, and Ni$_{34}$Cu$_{6}$Sn$_{60}$) were observed in order during an aging. All of the IMCs were well attached on UBM. Au in the quaternary IMC, which originates from immersion Au plating, prevents abnormal growth and separation of the IMC. Growth of each IMC is very dependent to the aging temperature because of its high activation energy. Besides the IMCs at the interface, plate-like Ag3Sn IMC grows as solder bump size inside solder bump. The abnormally grown Ni$_{22}$Cu$_{29}$Sn$_{49}$ and Ag$_3$Sn IMCs can be origins of brittle failure.failure.

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Prepration of Hydoxy Polyimde Membranes and Their Carbon Dioxide Permeation Property (Hydroxy Polyimide 막의 제조와 이산화탄소 투과 특성)

  • Woo, Seung-Moon;Choi, Jong-Jin;Nam, Sang-Yong
    • Membrane Journal
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    • v.22 no.2
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    • pp.128-134
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    • 2012
  • In this study, hydroxy polyimide (HPI) was prepared for non-porous membrane by solvent evaporation method. As the result of gas permeance properties measurement, $CO_2$ permeability was 85 Barrer and the $CO_2/N_2$ selectivity was 23 at $30^{\circ}C$. Flat sheet membrane and hollow fiber membrane were prepared by using ternary system of polymer, solvent and non-solvent additive. Morphologies and gas permeance properties were measured by FE-SEM and bubble flow meter. Each $CO_2$ permeability of 18.28 GPU, 70 GPU and $CO_2/N_2$ selectivity of 6.72, 8.63 at $30^{\circ}C$ in the flat sheet membrane and hollow fiber membrane. Hollow fiber membrane has gas permeance property better than flat sheet membrane.

Morphological, Mechanical and Rheological Properties of Poly(acrylonitrile-butadiene-styrene)/Polycarbonate/Poly$({\varepsilon}-caprolactone)$ Ternary Blends

  • Hong, John-Hee;Song, Ki-Heon;Lee, Hyung-Gon;Han, Mi-Sun;Kim, Youn-Hee;Kim, Woo-Nyon
    • Macromolecular Research
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    • v.15 no.6
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    • pp.520-526
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    • 2007
  • The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.

Separation of Taxol from Taxanes by NP-HPLC (정상 액체 크로마토그래피를 이용한 taxane으로부터 taxol의 분리)

  • Chang, Kyung Kon;Row, Kyung Ho;Chung, Sung Taik
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.286-291
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    • 1997
  • Taxol which is recognized as a powerful anticancer reagent was extracted from yew extract and separated by NP-HPLC (Normal-PhaseHigh Performance Liquid Chromatography). The experiments were performed in the isocratic mode with $5{\mu}l$ to $100{\mu}l$ injection volume and 1ml/min mobile phase flow rate. The major mobile phase was hexane and small amounts of ethanol, methanol, 1-propanol and isopropanol were added to change the retention behavior. Prior to a real sample, the artificial mixture of taxol, cephalomannine and 10-deacetyltaxol was tested. They are hard to be separated because of similar chemical structures. The experimental results showed that the proper composition of mobile phase for separating the three components was found 96% hexane and 4% ethanol(vol.%) or 96% hexane, 2% 1-propanol and 2% methanol(vol.%). Compared to the run time of 80 minutes for the binary system, the mixture was separated within 50 minutes with the less amount of mobile phase for the ternary system. Finally, $1{\mu}g$ of taxol was separated from yew tree extracts under the optimum operating conditions.

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A Study on the Precipitation Behavior of $Al_2Ti$ Phase in $L1_0$-TiAl and $L1_2-(Al,Cr)_3Ti$ ($L1_0$-TiAl 및 $L1_2-(Al,Cr)_3Ti$ 중에 $Al_2Ti$상의 석출거동에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.1
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    • pp.20-25
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    • 2008
  • Structural studies have been performed on precipitation hardening and microstructural variations found in Ti-Al-Cr ternary $L1_0$- and $L1_2$-phase alloys using transmission electron microscopy. Both the $L1_0$ and $L1_2$ phase alloys harden by aging at 973 K after solution annealing at higher temperatures. The amount of age hardening of the $L1_2$ phase alloy is larger than that of the $L1_0$ phase alloy. The phase separation between $L1_0$ and $L1_2$ phase have not been observed by aging at 973 K. But $Al_2Ti$ was formed in each matrix alloy during aging. The crystal structure of the $Al_2Ti$ phase is a $Ga_2Zr$ type in the $L1_0$ and a $Ga_2Hf$ type in the $L1_2$ phase, respectively. At the beginning of aging the fine coherent cuboidal $Al_2Ti$-phase are formed in the $L1_0$ phase. By further aging, two variants of $Al_2Ti$ precipitates grow along the two {110} habit planes. On the other hand, in the $L1_2$ phase, the $Al_2Ti$ phase forms on the {100} planes of the $L1_2$ matrix lattice. After prolonged aging the precipitates are rearranged along a preferential direction of the matrix lattice and form a domain consisting of only one variant. It is suggested that the precipitation of $Al_2Ti$ in each matrix alloy occurs to form a morphology which efficiently relaxes the elastic strain between precipitate and matrix lattices.

Crystal structure of Mn-Co-Ni thermistor (Mn-Co-Ni 서미스터의 결정구조 분석)

  • Lee, Jung-Il;Mhin, Sungwook;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.5
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    • pp.225-229
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    • 2015
  • This study was performed to investigate crystal structure of cubic spinel-type monophase oxide composed of the Mn-Co-Ni ternary system. Starting material was prepared by mixing Mn, Co, Ni oxides then evaporation to dryness. The XRD patterns were analyzed by in-situ XRD as increasing temperature from room temperature to $1400^{\circ}C$ in air atmosphere. The cubic spinel phase was existed in a temperature range from $900^{\circ}C$. However, separation of NiO phase was detected from $1300^{\circ}C$, which was the origin of deterioration in the crytallinity. The surface morphology of the manufactured NTC thermistors were analyzed by FE-SEM for comparison of good and bad samples.

A study on permeation of $CO_2-N_2-O_2$ mixed gases through a NaY zeolite membrane under permeate evacuation mode (진공모드에서 NaY 제올라이트 막의 $CO_2-N_2-O_2$ 혼합기체의 투과거동 연구)

  • Jeong, Su Jung;Yeo, Jeong-Gu;Han, Moon Hee;Cho, Churl Hee
    • Membrane Journal
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    • v.23 no.5
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    • pp.352-359
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    • 2013
  • In the present study, $CO_2$ permeation through a hydrophilic NaY zeolite membrane was studied under permeate evacuation mode for $CO_2$ single gas, $CO_2-N_2$ and $CO_2-O_2$ binary mixtures, and $CO_2-N_2-O_2$ ternary mixture. It was reconfirmed that the $CO_2$ permeation was governed by surface diffusion and the $CO_2$ selectivity was induced from blocking effect of adsorbed $CO_2$ molecules. The $CO_2$ permeance measured in permeate evacuation mode was much lower than that done in He sweeping mode, but was comparable to that obtained under feed pressurization mode. The NaY zeolite membrane showed a considerable $CO_2$ separation for $14%CO_2-80%N_2-6%O_2$ mixture : $CO_2$ permeance was about $1{\times}10^{-7}mol/m^2secPa$ and $CO_2$ selectivity was more than 10. Therefore, it was concluded that NaY zeolite membrane was one of promising membranes for post-combustion CCS process.

Phase Equilibria and $^{13}C$ NMR Analysis of the Double Semi-Clathrates Containing TBAB (TBAB를 포함하는 혼합 하이드레이트의 상평형 및 $^{13}C$ NMR 분석)

  • Lee, Seung-Min;Park, Sung-Min;Lee, Young-Jun;Lee, Sung-Won;Seo, Yong-Won
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.367-371
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    • 2011
  • TBAB (tetra-n-butyl ammonium bromide) forms a semi-clathrate with water under atmospheric pressure conditions and recently has attracted great attention due to its usage as a thermodynamic promoter in gas storage and separation process using gas hydrate formation. In this study, we measured the three-phase (hydrate (H) - liquid water ($L_{w}$)-vapor (V)) equilibria of the ternary $CH_{4}$+TBAB+water and $CO_{2}$+TBAB+water mixtures at the TBAB concentrations of 5 and 32 wt% to investigate promoting characteristics of TBAB. The greater promotion effect of TBAB was observed at 32 wt% than at 5 wt%. This result was in good agreement with that from pure TBAB semi-clathrate phase diagram under atmospheric pressure conditions. Through $^{13}C$ NMR analysis of the $CH_{4}$+TBAB semi-clathrate, it was found that $CH_{4}$ molecules are enclathrated in the cages of the double semi-clathrate and the position of resonance peak from encaged $CH_{4}$ molocules in the double semi-clathrate is the same as that from encaged $CH_{4}$ molocules in the pure $CH_{4}$ hydrate of structure I.

Adsorption of Dyes with Different Functional Group by Activated Carbon: Parameters and Competitive Adsorption (활성탄에 의한 작용기가 다른 염료의 흡착: 파라미터 및 경쟁 흡착)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.151-158
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    • 2022
  • In this paper, parameter characteristics such as pH effect, isotherm, kinetic and thermodynamic parameters and competitive adsorption of dyes including malachite green (MG), direct red 81 (DR 81) and thioflavin S (TS), which have different functional groups, being adsorbed onto activated carbon were investigated. Langmuir, Freundlich and Temkin isotherm models were employed to find the adsorption mechanism. Effectiveness of adsorption treatment of three dyes by activated carbon were confirmed by the Langmuir dimensionless separation factor. The mechanism was found to be a physical adsorption which can be verified through the adsorption heat calculated by Temkin equation. The adsorption kinetics followed the pseudo second order and the rate limiting step was intra-particle diffusion. The positive enthalpy and entropy changes showed an endothermic reaction and increased disorder via adsorption at the S-L interface, respectively. For each dye molecule, negative Gibbs free energy increased with the temperature, which means that the process is spontaneous. In the binary component system, it was found that the same functional groups of the dye could interfere with the mutual adsorption, and different functional groups did not significantly affect the adsorption. In the ternary component system, the adsorption for MG lowered a bit, likely to be disturbed by the other dyes meanwhile DR 81 and TS were to be positively affected by the presence of MG, thus resulting in much higher adsorption.

Gas Hydrate Phase Equilibria of $CO_2+H_2$ Mixture in Silica Gel Pores for the Development of Pre-combustion Capture (연소 전 이산화탄소 회수기술을 위한 실리카겔 공극 내에서의 이산화탄소+수소 혼합가스 하이드레이트의 상평형)

  • Kang, Seong-Pil;Jang, Won-Ho;Jo, Wan-Keun
    • Clean Technology
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    • v.15 no.4
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    • pp.258-264
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    • 2009
  • Thermodynamic measurements were performed to show the possibility of recovering $CO_2$ from fuel gas (the mixture of $CO_2$ and $H_2$) by forming gas hydrates with water where water was dispersed in the pores of silica gel particles having nominal 100 nm of pore diameter. The hydrate-phase equilibria for the ternary $CO_2+H_2$+water in pores were measured and $CO_2$ concentrations in vapor and hydrate phase were determined under the hydrate-vapor two phase region at constant 274.15 K. It was shown that the inhibition effect appeared due to silica gel pores, and the corresponding equilibrium dissociation pressures became higher than those of bulk water hydrates at a specific temperature. In addition, direct measurement of $CO_2$ content in the hydrate phase showed that the retrieved gas from the dissociation of hydrate contained more than 95 mol% of $CO_2$ when 42 mol% of $CO_2$ and balanced Hz mixture was applied. Compared with data obtained in case of bulk water hydrates, which showed just 83 mol% of $CO_2$ where 2-stage hydrate slurry reactor was intended to utilize this property, the hydrate formation in porous silica gel has enhanced the feasibility of $CO_2$ separation process. Hydrate formation as not for slurry but solid particle makes it possible to used fixed bed reactor, and can be a merit of well-understood technologies in the industrial field.