• Title/Summary/Keyword: Temporal Reaction

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Verification of Kinetic Theoretical Prediction of Diffusion-influenced Reversible

  • Yang, Min O;Sin, Guk Jae
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.93-96
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    • 2000
  • A diffusion-influenced pseudo-first order reversible reaction A + B ⇔C + B is investigated by the molecular dynamics (MD) simulation method. Theoretical finding that the temporal evolution of reactants [conditional probabilities] in the reversible system can be expressed by the irreversible survival probability with an effective rate parameter is confirmed even in the presence of solvent particles. We carry out molecular dynamics simulations for both the irreversible and the reversible cases to evaluate the survival and the conditional probabilities for each cases. When the resultant irreversible survival probability is inserted into the proposed relation, the conditional probabilities given by the simulation are exactly reproduced.

A STUDY ON THE INITIAL REACTION OF CRANIOFACIAL COMPLEX TO MAXILLARY HEADGEAR TRACTION BY LASER HOLOGRAPHY (Laser holography를 이용한 상악 headgear견인에 따른 안면두개골의 초기반응에 관한 연구)

  • Kim, Choong-Bae;Yang, Won-Sik
    • The korean journal of orthodontics
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    • v.16 no.2
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    • pp.31-41
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    • 1986
  • The purpose of this study is to examine the initial reaction of craniofacial complex to the traction of headgears which are frequent used in dinical practice by using holographic interference method. Changes in the fringe pattern according to the traction conditions (outer bow length, load amount, direction) were compared. Human dry skull was used as experimental material, the results were as follows. 1. The density of fringes increased with an increase in load. 2. Maxillary headgear affected circummaxillary bones-temporal bone, zygomatic bone, nasal bone, frontal bone, sphenoid bone as well as maxilla. 3. The most upward-backward displacement was observed in a high pull head gear $(30^{\circ})$, this is though to be a optimal direction for supressing the growth of the maxilla.

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The Influence of Wedged Insoles on Lower Extremity Joints during Gait (경사진 안창이 보행시 하지관절에 미치는 영향)

  • Kwon, Min-Jeong;Choi, Hwa-Soon;Chung, Min-K.;Na, Seok-Hee
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.1
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    • pp.19-27
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    • 2007
  • Despite the widespread use of laterally wedged insoles for patients with knee osteoarthritis and medially wedged insoles for controlling rearfoot pronation, an understanding of the effects of wedged insoles was limited and sometimes controversial. The objective of this study was to evaluate the effect of wedged insoles on the kinematics and kinetics of normal gait. Ten male subjects without history of lower limb disorders were recruited. Each subject performed four gait cycles under each of seven conditions; shod with 5$^{\circ}$, 8$^{\circ}$ and 15$^{\circ}$, 8$^{\circ}$ and 15$^{\circ}$ laterally wedged insoles. In order to determine statistical differences among seven conditions, the measured temporal spatial variables, angular displacements, joint moments, and ground reaction forces were compared with a one-way analysis of variance. Some significant changes induced by wedged insoles were apparent in joint moments and ground reaction forces. The medially wedged insole increased the laterally directed ground reaction force and varus moments at the ankle force and varus moments at the ankle and the knee.

Characteristics of Chemical Reaction and Ignition Delay of $H_2$/Air/HFP Mixtures (수소/공기/HFP 혼합기의 화학반응 및 점화지연 특성)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.25 no.1
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    • pp.17-21
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    • 2010
  • The chemistry and ignition delay of hydrogen/air/HFP premixed mixtures was investigated numerically with unsteady perfectly stirred reactor(PSR). The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the temporal concentration variations of major or reactants such as hydrogen and oxygen during autoignition were similar to the spatial distribution of premixed flame while water vapor produced at the ignition temperature was decomposed later, which can be clarified with the relate species production rates that the the re-growth (or shoulder) of OH concentration is a result of F radicals attacking $H_20$ forming OH and HF. For the stoichiometric $H_2$/air mixture inhibited by 20% HFP, HFP thermal decomposition reaction prevails over the radical attack such as H at initial stage. Even though relatively large HFP addition contributes to delay the ignition, chemical effect on the ignition delay is not effective because of late thermal decomposition of HFP. The most small ignition delay was observed at a slightly fuel lean condition ($\phi$ = 0.9), and temperature dependency of ignition delay was clearly shown near 900 K.

The Effects of Start and Finish Distance on the Gait Variables during Walking (보행 시작과 멈추는 거리가 보행 변인에 미치는 영향)

  • Lim, Bee-Oh;An, Seung-Hyun;Lee, Sang-Woo;Do, In-Young
    • Korean Journal of Applied Biomechanics
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    • v.17 no.1
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    • pp.17-27
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    • 2007
  • It is essential for gait analysis to know the distance information. The purpose of this study was to investigate the effects of start and finish distance on the gait variable during walking. Six adolescent participated in this study. Start condition was given by six conditions.: walking forward from (1) one step, (2) three steps, (3) five steps, (4) ten steps, (5) one step after standing walk, and (6) three steps after standing walk, before contacting the force plate. Stop condition was given by four conditions. : stop after (1) one step, (2) two steps, (3) three steps, and (4) ten steps, passing force plate. Repeated measured one-way ANOVA was utilized for data analysis, and the significant level was set at .05. The largest change from the difference of gait velocity exists between the variables of ground reaction force. There were no significant differences in spatio-temporal and posture(angle) variables, as well as ground reaction force variables with walking over the three steps. There were significant differences in gait velocity, knee angle at heel contact, vertical impulse and ankle angle at toe off in short distance.

The Kinetic Analysis of the Lower Extremity Joints when Performing Uchi-mata by Uke's Posture in Judo (유도 허벅다리걸기 기술 발휘 시 받기 자세에 따른 하지관절의 kinetic 분석)

  • Yoon, Hyun
    • Korean Journal of Applied Biomechanics
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    • v.15 no.2
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    • pp.167-183
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    • 2005
  • The purpose of this study was to analyze the kinetical variables of the lower extremity joints when performing uchimata(inner thigh reaping throw) by uke(receiver)'s two posture(shizenhon tai), jigohon tai), by voluntary resistance level(VRL) in judo. The subjects, who were for 3 male Korean national representative judokas(elite group : EG) and 3 male representative judokas of Korean University(non-elite group: NEG), and were filmed 4 DV video cameras(60fields/sec.), that posture of uke were shizenhon-tai (straight natural posture), jigohon-tai(straight defensive posture), VRL of uke was 0%. The selected trials were subject to 3-dimensional film motion analysis and ground reaction force(MRF) analysis. The kinetical variable of this study were temporal, postures( ankle and knee angle of attacking leg), that were computed through video film analysis, MRF at events were obtained from the ground-reaction force analysis by AMTI force plate system. When performing uchi-mata according to each posture and by VRL, from the data analysis and discussion, the conclusions were as follows : 1) Temporal variables : total time-required(TR) when performing uchi-mata was shown EG 0.13sec the shorter than NEG(o.77sec.) in shizenhon-tai. and EG 0.17sec the shorter than NEG(o.76sec.) in jigonhon-tai. Also, all of two groups' jigohon-tai(0.68sec.) were faster than shizenhon-tai(0.71 sec.). 2) The posture variables : The angle of ankle in attacking when performing were plantar flexion in EG, and dorsi flexion in NEG by shizenhon-tai and jigohon-tai posture. The angle of knee in attacking when performing were extension in EG and NEG, but range of extension in EG were larger than in NEG. 3) MRF : Vertical MRF when performing uchi-mata was shown the strongest in the 2nd stage of kake phase(2.23BW) by EG in both posture, and it was same value by NEG(2.23BW), but shizenhon-tai (2.28BW), jigohon-tai(1.64BW), respectively.

Comparison of Complications in Direct and Indirect Osseointegration of Prosthetic Auricular Reconstruction (인조귀 부착술에서 직접 및 간접골통합법의 합병증에 대한 비교)

  • Park, Mu Shik;Han, Ki Hwan;Kim, Jun Hyung
    • Archives of Plastic Surgery
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    • v.32 no.3
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    • pp.293-298
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    • 2005
  • Osseointegrated prosthetic auricular reconstruction can be classified as either direct or indirect. In the $Br{\aa}nemark $ system of direct osseointegration, implants are placed into the mastoid process of the temporal bone. In the Epitec system of indirect osseointegration, implants are inserted into a three-dimensional carrier plate that is fixed to the mastoid by means of screws. We experienced forty-four cases using the indirect system and seventeen cases using the direct system. We compared with two systems by complications, such as skin reaction, implant loosening, implant loss. There were no specific differences in the skin reaction around the implants and abutments in relation to age or system used. The degree of skin reaction was different according to the conditions around the implant: in cases of virgin microtia, a skin flap was used to cover the implant, in contrast to grafted skin coverage for failed autogenous reconstruction. In both systems, the skin reaction was more severe and frequent in skin flap than in grafted skin. Loosening of the implant was more frequent in the direct system; however, accidental detachment of the implant from the abutment was more frequent in the indirect system. To reduce complications of skin reaction in osseointegrated prosthetic auricular reconstruction, it is important for soft tissue around implant to immobilize. Therefore, grafted skin is better than skin flap as soft tissue around implant. And immobilization of soft tissue around implant by wound dressing is major facter.

Numerical Study on the Effect of Exhaust Flow Pattern under Real Running Condition on the Performance and Reliability of Closed-Coupled Catalyst (실 운전조건에서의 배기유동패턴이 근접장착 촉매변환기의 성능 및 신뢰성에 미치는 영향에 관한 수치적 연구)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.54-61
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    • 2004
  • The engine-out flow is highly transient and hot, and may place tremendous thermal and inertial loads on a closed-coupled catalyst. Therefore, time-dependent and detailed flow and thermal field simulation may be crucial. The aim of this study is to develop combined chemical reaction and multi-dimensional fluid dynamic mathematical model and to study the effect of unsteady pulsating thermal and flow characteristics on thermal reliability of closed-coupled catalyst. The effect of cell density on the conversion performance under real running condition is also investigated. Unlike previous studies, the present study focuses on coupling between the problems of pulsating flow pattern and catalyst thermal response and conversion efficiency. The results are expressed in terms of temporal evolution of flow, pollutant and temperature distribution as well as transient characteristics of conversion efficiency. Fundamental understanding of the flow and thermal phenomena of closed-coupled catalyst under real running condition is presented. It is shown that instants of significantly low values of flow uniformity and conversion efficiency exist during exhaust blowdown and the temporal varaition of flow uniformity is very similar in pattern to one of conversion efficiency. It is also found that the location of hot spot in monolith is directly affected by transient flow pattern in closed-coupled catalyst.

Temporal changes in the abundance of the fish-killing dinoflagellate Karlodinium veneficum (Dinophyceae) in Tongyeong, Korea

  • Park, Tae-Gyu;Ok, Yu-Ran;Park, Young-Tae;Lee, Chang-Kyu
    • ALGAE
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    • v.26 no.3
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    • pp.237-241
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    • 2011
  • The toxic dinoflagellate Karlodinium veneficum has been implicated in numerous fish kill events around the world. Since this species commonly co-occurs with other morphologically similar dinoflagellates, field monitoring of this species in natural waters via light microscopy only has been problematic. In this study, we investigated temporal changes in K. veneficum's abundance in the waters of Obido, Tongyeong, using a species-specific real-time polymerase chain reaction (PCR) assay. The field survey, from April to December 2010, revealed K. veneficum occurred at low densities (12 to 425 cells $L^{-1}$) during this time and that cell numbers peaked in June (early summer in Korea), indicating this species generally occurs in the warmer season (mostly at $16.9-22.3^{\circ}C$ and 33.4-34.5‰) in the Obido area.

The Relation between asymmetric weight-supporting and gait symmetry in patients with stroke (뇌졸중 환자의 체중지지 비대칭과 보행 대칭성의 관련성)

  • Lee, Yong-Woo;Shin, Doo-Chul;Lee, Kyoung-Jin;Lee, Seung-Won
    • Journal of the Korean Society of Physical Medicine
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    • v.7 no.2
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    • pp.205-212
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    • 2012
  • Purpose : The aim of this study was to investigate the relationship between weight-supporting asymmetry and gait symmetry in patients with stroke. Methods : Sixty two stroke patients with hemiplegia stood quietly with eye opens on a force platform to calculate weight-supporting asymmetry from vertical reaction force. The GAITRite was used to evaluate their gait parameters. The data were analyzed using Pearson correlation. Results : The results of this study was showed that the medio-lateral index (ML) was correlated with symmetry rate (SR), symmetry index (SI), and Gait asymmetry (GA) of step time and length but stronger correlation with spatial gait symmetry than temporal symmetry. In gait symmetry, step length has stronger correlation with weight-supporting asymmetry than step time. Conclusions : The results of this study shows weight-supporting asymmetry was correlated with more spatial gait symmetry than temporal symmetry.