• Title/Summary/Keyword: Temperature stability time

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Characteristics of browning Materials in Perilla Oil and Change of Oxidative Stability of Blended Perilla Oil (들기름에 존재하는 갈색물질의 특성과 혼합 들기름의 산화 안정성 변화)

  • 김영언;김인환;이영철
    • The Korean Journal of Food And Nutrition
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    • v.9 no.4
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    • pp.504-508
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    • 1996
  • This study was performed to investigate the browning intensity and electron donating ability of browning material in perilla oils from seeds roasted at 150~21$0^{\circ}C$ for 10~30 min. It was also investigated the oxidative stability of the blended perilla oil on the basis of sensory property and oxidative stability. The browning intensity in perilla oil increased with the roasting temperature and time increased. The browning intensity of perilla oil from seed roasted at 21$0^{\circ}C$ for 30 min indicated 13 times higher than that of perilla oil from seed at 15$0^{\circ}C$ for 10 min. Electron donating ability on DPPH of browning materials presented in perilla oils increased with the roasting temperature and time increased. The electron donating ability of browning materials in perilla oil from seed reasted at 21$0^{\circ}C$ for 30 min indicated 3 times higher than those of perilla oil from seed at 15$0^{\circ}C$ for 10 min. In conclusion, for the improvement of oxidative stability of perilla oil, perilla seed should be roasted at 21$0^{\circ}C$ for 30 min. These results suggest that browning materials formed between sugars and amino acids attribute to improve quality of oil such as sensory properties and oxidative stabilities. For the improvement of sensory property and oxidative stability of oil, perilla oil from seed roasted at 19$0^{\circ}C$ for 20 min was blended with the oil from seed roasted at 21$0^{\circ}C$ for 30 min as ratio of 85 : 15.

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Combustion Stability and the Properties of Methane/Air Mixture Subjected to Unsteady Flow Fluctuations (비정상 유동의 메탄/공기 혼합기 반응안정성 효과 연구)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.26 no.5
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    • pp.1-6
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    • 2011
  • Flame extinction and the chemistry of stoichiometric methane/air mixture were investigated numerically in the PSR(perfectly stirred reactor). For the study, PSR code was modified to be possible to unsteady calculation, and the sinusoidal fluctuation was subjected to the residence time. In the region of residence time far from the extinction limit, combustion mode was strongly dependent on the frequency. The low frequency excitation provided the quasi-steady behavior on the temperature and the concentrations of related species, but small variation of temperature was observed under high frequency. In the region of residence time near the extinction limit, the mixture subjected above 1 KHz was still reacting even though extinction had to be occurred under quasi-steady concept. The attenuation of extinction limit resulted from that chemical time was comparable to the flow time. The mean mole fractions of both NO and CO were almost same regardless of imposed frequency. However, the average mole fraction of $C_2H_2$ was decreased as increasing frequency, which implies that soot yield might be reduced at the higher frequency of flow excitation. The result provides the basic concept for flame stabilization, and it will be used to design a mild combustor.

Isothermal Phase Transformations and Stability of Retained Austenite during Quenching and Partitioning Process for 0.15C Steel

  • Jin, Jong-Won;Park, Chulho;Kang, Namhyun
    • Journal of Welding and Joining
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    • v.35 no.1
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    • pp.89-94
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    • 2017
  • The microstructure and dilatation for 0.15C steels were investigated to define the phase transformation during the quenching and partitioning (Q&P) process. For the one step Q&P dilatation, the isothermal martensite/bainite transformation occurred because the holding temperature was between $M_s$ and $M_f$. The isothermally transformed martensite/bainite and the athermally transformed martensite were produced by a loss of retained austenite. As the holding time increased, new martensite-start ($M_s$) temperature produced from the final quenching process decreased due to the carbon partitioning from the martensite to the retained austenite. This was the direct evidence of increment for the retained austenite stability. For the two step Q&P dilatation, the isothermal bainitic transformation occurred because the partitioning temperature was larger than the $M_s$ and new $M_s$. The partitioning at $400^{\circ}C$ indicated the short incubation period for the bainite transformation than the $350^{\circ}C$ partitioning because the partitioning at $400^{\circ}C$ should acquire the larger thermal driving force for carbon partitioning than the $350^{\circ}C$ partitioning. A quick drop of $M_s$ and short period of bainite incubation for the $400^{\circ}C$ partitioning steel were also the direct evidence of significant effects of carbon partitioning on the stability of retained austenite.

Oxidative Stability of Tallow Heated by Different Frying Conditions (튀김조건에 따른 가열 우지의 산화안정성)

  • 장영상;양주홍
    • Food Science and Preservation
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    • v.8 no.3
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    • pp.331-337
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    • 2001
  • The oxidative stability of tallow heated was studied by different frying condition (temperature 130, 150, and 180$^{\circ}C$;heating time, each 10hours per day, total 240hrs). Changes of physicochemical parameters such as acid value, peroxide value, iodine value, dielectric constant, content of polar components and polymer, refractive index, smoke point, viscosity and color changes in tallow heated were also measured. Acid value, dielectric constant, refractive index, viscosity, and content of polar component and polymer increased as the tallow was heated longer, whereas iodine value and smoke point decreased and peroxide value was increased and decreased repeatedly. These parameters changed to a greater extent as the heating temperature went up. The color became darkened with the increase of red and yellow values during heating. The decree of coloration was proportional to heating temperature.

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Seasonal characteristics of thermal and chemical stratification in Lake Paldang (팔당호의 계절별 열적 및 화학적 층화 특성)

  • Son, Ju Yeon;Park, Jin Rak;Noh, Hye Ran;Yu, Soon Ju;Im, Jong Kwon
    • Journal of Korean Society on Water Environment
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    • v.36 no.1
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    • pp.1-13
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    • 2020
  • The purpose of this study was to investigate the thermal and chemical stratification in Lake Paldang 2013-2018 weekly using Schmidt's stability index (SSI) and the index of chemical stratification (IC-i). The annual average for SSI was 19.1 g cm/㎠ with the maximum value of 45.3 g cm/㎠ in the summer and the minimum value of 4.8 g cm/㎠ in fall-winter showing seasonal differences as well as increased vertical mixing in the summer. The lake stability increased higher in 2016 as compared with the other period. The most influential factors of thermal stratification were temperature and heavy rainfall. Especially, high water temperature and a prolonged residence duration caused by reduced rainfall and inflows could result in an increase of the stratification period. While decreasing inflow and outflow at the end of the rainfall, the thermal stratification was restrengthened within 7-14 days, and then stabilized rapidly before the rainfall. IC-DO increased with high air temperature in the spring and fall-winter. However increasing sunshine duration and residence time and decreasing rate of outflow caused an increase of IC-DO in the summer. Rainfall (less than 800 mm/year) and discharge (less than 200 CMS) significantly declined in 2015 resulting in IC-DO (0.77) increased more than three times over the other years and bottom water hypoxia occurred. The SSI and IC-i used in this study could be applied to other lakes to understand changes in stratification and mixing dynamics.

Effects of Stability and Volume Fraction of Retained Austenite on the Tensile Properties for Q&P and AM Steels (Q&P와 AM강의 잔류오스테나이트 분율과 안정도에 따른 인장특성 거동)

  • Byun, Sang-Ho;Oh, Chang-Suk;Nam, Dae-Geun;Kim, Young-Seok;Kang, Nam-Hyun;Cho, Kyung-Mox
    • Korean Journal of Materials Research
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    • v.19 no.6
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    • pp.305-312
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    • 2009
  • The effects of Quenching and Partitioning (Q&P) and Annealed Martensite (AM) heat treatment on the microstructure and tensile properties were investigated for 0.24C-0.5Si-1.5Mn-1Al steels. The Q&P steels were annealed at a single phase ($\gamma$) or a dual phase (${\gamma}+{\alpha}$), followed by quenching to a temperature between $M_s$ and $M_f$. Then, enriching carbon was conducted to stabilize the austenite through the partitioning, followed by water quenching. The AM steels were intercritically annealed at a dual phase (${\gamma}+{\alpha}$) temperature and austempered at $M_s$ and $M_s{\pm}50^{\circ}C$, followed by cooling in oil quenching. The dual phase Q&P steels showed lower tensile strength and yieldyield strength than those of the single phase Q&P steels, and tThe elongation for the dual phase Q&P steel was partitioning 100s higher than that of that for the single phase Q&P steels as the partitioning time was less than 100s up to partitioning 100s. For AM steels, the tensile/yield strength decreased and the total elongation increased as the austempering temperature increased. The stability of the retained austenite controlled the elongation for Q&P steels and the volume fraction of the retained austenite controlled the elongation for AM steels.

Development of Low Irritative, Eco-friendly Nail Polish Including Shellac/gelatin (쉘락/젤라틴을 함유한 저자극·친환경 매니큐어의 개발)

  • Shim, Haeun;Noh, Daeyoung;Kim, Jimin;Kim, Doyeon;Nam, Myungsuk;Kim, Donguk
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.22-27
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    • 2019
  • Nail polish is used to decorate nail beautifully however, it contains lots of toxic materials. Generally, Nail polish consists of film-forming agent, colorant, solvent, surfactant and stabilizer. In this study, to replace toxic chemicals to low irritative, eco-friendly ingredients, we prepared 4 kinds of nail polish and tested safety, stability and performance. Nail polish including shellac/gelatin showed best performance in water-resistance, friability and drying time. When cell toxicity test is done by MTT assay, shellac-gelatin nail polish showed over 70% cell viability at $1,000{\mu}g/mL$ whereas control nail polish in market showed 50% cell viability. At 4 weeks temperature stability test, color was stable at low temperature however it needs formulation improvement at higher temperature.

Processing Conditions and Quality Stability during Storage of Frozen-dried Filefish (말쥐치 동건품의 가공조건 및 저장중의 품질변화)

  • LEE Eung-Ho;KIM Hee-Yun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.2
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    • pp.111-116
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    • 1982
  • For the effective utilization of the fish resources in coastal regions, investigations on processing conditions of frozen-dried product, quality stability of the Product during storage, and utilization as a food material were carried out with the filefish, Navoden modestus. The processing condition was determined with the moisture content and texture of the product. The duality of the product was evaluated on chemical composition, rehydration capacity, TBA value, browning, omission test and sensory score. The conditions for the processing of frozen-dried filefish under the conditions of freezing temperature at $-10^{\circ}C$ and forced air thawing at $56{\pm}2^{\circ}C$ with a velocity of 1 m/sec were as follows : freezing temperature, $-10^{\circ}C$ : freezing time, 10 hours; thawing time, 2 hours ; and repeated number of freezing and thawing, 5 times. The yield, the condition of moisture and protein were $10.2\%,\;23.6\%\;and\;70.6\%$, respectively. The frozen-dried product packed with air and stored at room temperature showed no remarkable changes in TBA value, rehydration capacity, browning during the storage period of 90days. The frozen-dried filefish showed no remarkable differences in the taste, odor and texture, comparing with frozen-dried Alaska pollack on the market.

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Physico-chemical stability of pesticide formulations under different storage conditions (저장조건별 농약제품의 물리.화학적 안정성)

  • Lee, Hee-Dong;Kim, Kwang-Ho;Rhi, Ja-Hyeun;Shin, Wook-Cheol;Park, Hyeon-Ju;Lee, Soo-Hyung;Park, Seung-Soon
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.103-106
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    • 2004
  • To confirm physico-chemical stability of formulated products, this study was conducted under different storage conditions; room temperature and accelerated temperature of $54^{\circ}C$. The tested pesticide formulations were dichlorvos 50% EC, acephate 50% WP, hymexazol 4% DP, thiram 80% WP and isoprothiolane 12% GR. The selected formulations were stored for 10 weeks and 5 years under the given temperature in maximum and contents of active ingredients were also analyzed by GLC or HPLC after each time of storage. The degradation rates of 5 active ingredients under the two conditions showed a similar trend except acephate. Acephate was rapidly decomposed at $54^{\circ}C$ but slowly decomposed at room temperature, and the degradation rate under the accelerated condition was 2.4 to 5-fold higher than that under the room temperature. Consequently, the stability test on active ingredients in pesticide formulations was able to recommend to be carried out under the accelerated condition except acephate. And the physical properties of all formulations tested under two storage conditions were good.

Depolymerization of Chitosan Using H2O2 and Decrease in Molecular Weight upon Storage Time (H2O2에 의한 저분자화 키토산의 제조와 시간경과에 따른 분자량 저하)

  • Kim, Hee-Jung;Jeon, Dong-Won
    • Fashion & Textile Research Journal
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    • v.5 no.5
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    • pp.520-528
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    • 2003
  • Chitosan was depolymerized by oxidizing agent, hydrogen peroxide ($H_2O_2$) and general properties of resulting low molecular weight chitosan(LMWC) were studied. Effect of amount of $H_2O_2$, ratio of $H_2O_2$/chitosan, and reaction temperature were investigated in preparing LMWC. In addition, the reduction of molecular weight of prepared LMWC were measured after a certain time passage. Pre-swelling treatment of starting chitosan affected uniform and mild reaction of depolymerization and increased the solubility of resulting LMWC. Prepared LMWC (Mw 100,000) showed a decrease in Mw by 25-35%. Prepared LMWC(Mw 60,000-70,000) showed a decrease in Mw by 10-15% after 7 months. Therefore, this depolymerizing process can be concluded desirable in terms of stability. In addition, yellowing of pre-swelling treated chitosan upon time passage was insignificant compared with that of untreated chitosan. Therefore, pre-swelling treatment of chitosan before depolymerization would be beneficial in terms of stability of physical state.