• Title/Summary/Keyword: Temperature stability time

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Study on the storage stability of allyl chloride and carbon disulfide in tedlar bags (테들라 백에서의 알릴클로라이드와 이황화탄소 보존성 연구)

  • Lee, Jinseon;Kim, Kijoon;Yoon, Junheon;Cho, Seokyeon
    • Analytical Science and Technology
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    • v.26 no.6
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    • pp.381-386
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    • 2013
  • The sixty nine chemicals that are closely linked to chemical accident are designated as the substances requiring preparation for accidents and managed for public health under the Toxic Chemicals Control Act. In this study, storage stability of allyl chloride (AC) and carbon disulfide (CD), which are highly inflammable and volatile in tedlar bags, was studied for gaseous chemicals sampling. Storage stability was studied considering storage temperature ($2^{\circ}C$, $25^{\circ}C$), chemical concentration (low conc. ppm, high conc. ppm) and storage time (0, 48, 96, and 144 hr). Also, the stability of bags containing one type of chemical substance and the bags containing a mixture of chemicals was compared against each other. As a result, two chemicals showed decreasing storage stability based on storage time. Also two chemicals presented statistical significance of concentration and mixing type.

Analyses on Thermal Stability and Structural Integrity of the Improved Disposal Systems for Spent Nuclear Fuels in Korea

  • Lee, Jongyoul;Kim, Hyeona;Kim, Inyoung;Choi, Heuijoo;Cho, Dongkeun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.spc
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    • pp.21-36
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    • 2020
  • With respect to spent nuclear fuels, disposal containers and bentonite buffer blocks in deep geological disposal systems are the primary engineered barrier elements that are required to isolate radioactive toxicity for a long period of time and delay the leakage of radio nuclides such that they do not affect human and natural environments. Therefore, the thermal stability of the bentonite buffer and structural integrity of the disposal container are essential factors for maintaining the safety of a deep geological disposal system. The most important requirement in the design of such a system involves ensuring that the temperature of the buffer does not exceed 100℃ because of the decay heat emitted from high-level wastes loaded in the disposal container. In addition, the disposal containers should maintain structural integrity under loads, such as hydraulic pressure, at an underground depth of 500 m and swelling pressure of the bentonite buffer. In this study, we analyzed the thermal stability and structural integrity in a deep geological disposal environment of the improved deep geological disposal systems for domestic light-water and heavy-water reactor types of spent nuclear fuels, which were considered to be subject to direct disposal. The results of the thermal stability and structural integrity assessments indicated that the improved disposal systems for each type of spent nuclear fuel satisfied the temperature limit requirement (< 100℃) of the disposal system, and the disposal containers were observed to maintain their integrity with a safety ratio of 2.0 or higher in the environment of deep disposal.

Stability of Cefditoren in Three Oral Liquid Preparations (경구용 시럽제 중 세프디토렌의 안정성에 관한 연구)

  • Kim, Hye-Kyung;Gwak, Hye-Sun
    • Korean Journal of Clinical Pharmacy
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    • v.16 no.1
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    • pp.28-33
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    • 2006
  • The stability of cefditoren in three kinds of oral liquid preparations at 4 and $25^{\circ}C$ was studied for 90 days. Two tablets of 100 mg cefditoren pivoxil were mixed with 200 mL of each oral liquid syrup, which is Pebron syrup (oxolamine citrate 10 mg/mL), $Mucopect^{(R)}$ syrup (ambroxol hydrochloride 3 mg/mL) or $Tyrenol^{(R)}$ suspension (acetaminophen encapsulated 32 mg/mL). Three samples of each formulation were refrigerated $(4^{\circ}C)$ and three were stored at room temperature $(25^{\circ}C)$. At predetermined time, samples were assayed by stability-indicating HPLC method. The chromatographic analysis after deliberate degradation showed no evidence of any breakdown product likely to interfere with the chromatographic peak of the parent substance. The relation between cefditoren pivoxil concentration and peak area was linear from 10 to $150{\mu}g/mL\;(r^2=0.9998)$. The analysis method was precise, with coefficients of variation no greater than 3.6%. Cefditoren was stable in $Mucopect^{(R)}$ syrup up to 4 weeks regardless of the temperature; in $Tyrenol^{(R)}$ suspension and Pebron syrup, it was stable for at least 28 and 45 days, and 7 and 45 days at 25 and $4^{\circ}C$, respectively. The percentages of initial cefditoren concentration remaining after 90 days were $51.5{\pm}1.8\;and\;80.9{\pm}5.6%,\;61.7{\pm}7.8\;and\;70.2{\pm}7.3%,\;and\;39.9{\pm}3.2\;and\;81.4{\pm}5.5%$ in $Mucopect^{(R)}$ syrup, $Tyrenol^{(R)}$ suspension and $Pebron^{(R)}$ syrup at 25 and $4^{\circ}C$, respectively. The pH variations of all test solutions were minimal, which was within 0.5. The results indicated that the stability of cefditoren was significantly affected by liquid solutions mixed with cefditoren, and storage tempertature.

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Stability Test and Quantitative and Qualitative Analyses of the Amino Acids in Pharmacopuncture Extracted from Scolopendra subspinipes mutilans

  • Cho, GyeYoon;Han, KyuChul;Yoon, JinYoung
    • Journal of Pharmacopuncture
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    • v.18 no.1
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    • pp.44-55
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    • 2015
  • Objectives: Scolopendra subspinipes mutilans (S. subspinipes mutilans) is known as a traditional medicine and includes various amino acids, peptides and proteins. The amino acids in the pharmacopuncture extracted from S. subspinipes mutilans by using derivatization methods were analyzed quantitatively and qualitatively by using high performance liquid chromatography (HPLC) over a 12 month period to confirm its stability. Methods: Amino acids of pharmacopuncture extracted from S. subspinipes mutilans were derived by using O-phthaldialdehyde (OPA) & 9-fluorenyl methoxy carbonyl chloride (FMOC) reagent and were analyzed using HPLC. The amino acids were detected by using a diode array detector (DAD) and a fluorescence detector (FLD) to compare a mixed amino acid standard (STD) to the pharmacopuncture from centipedes. The stability tests on the pharmacopuncture from centipedes were done using HPLC for three conditions: a room temperature test chamber, an acceleration test chamber, and a cold test chamber. Results: The pharmacopuncture from centipedes was prepared by using the method of the Korean Pharmacopuncture Institute (KPI) and through quantitative analyses was shown to contain 9 amino acids of the 16 amino acids in the mixed amino acid STD. The amounts of the amino acids in the pharmacopuncture from centipedes were 34.37 ppm of aspartate, 123.72 ppm of arginine, 170.63 ppm of alanine, 59.55 ppm of leucine and 57 ppm of lysine. The relative standard deviation (RSD %) results for the pharmacopuncture from centipedes had a maximum value of 14.95% and minimum value of 1.795% on the room temperature test chamber, the acceleration test chamber and the cold test chamber stability tests. Conclusion: Stability tests on and quantitative and qualitative analyses of the amino acids in the pharmacopuncture extracted from centipedes by using derivatization methods were performed by using HPLC. Through research, we hope to determine the relationship between time and the concentrations of the amino acids in the pharmacopuncture extracted from centipedes.

"A survey of Elementary School Children,s Concept of Temperature" (국민학교 아동의 온도개념 형성에 관한 조사)

  • Kim, Hyun-Jae;Kim, Han-Ho
    • Journal of The Korean Association For Science Education
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    • v.10 no.1
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    • pp.95-118
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    • 1990
  • This students ideas in science are diverse and unique It is realized that children's preconceptions and misconceptions established before lessoning hgve a crucial in fluence on the following education. so it is meaningful to analyse the children's concept of temperature for the better teaching strategy in this study. This survey of the Elementary school children's concept is designed for the subtopics of temperature as the relation between heat and temperature, He relation between volume(size) and temperature, the temperature of change of state on water, the temperature of substances in the condition of thermal equilibrium. Using Clinical method, this research was executed to 306 children at elementary school. The network method or the analyse of questionnaires were used to analyse the children's response. Findings of this survey are as follow. Students are already familiar with such concept as this increase of temperature by geating, but they think every substance is not the case. Many students appears to believe that the temperature of an object(substance) is related to its size(vloume) Qualitative tasks are difficult than qualitative ones. This trend appear highly in the low grade students. Don't know the temperature of change of state on water and it's stability They think that the temperature is determined by the heating time(period) and the temperature of heating source. Students think, in general that temperature of substance in the condition of thermal equilibrium is different.

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Studies on Rheological Properties of Dough and Stability of Frozen Dough (밀가루의 이화학적(理化學的)인 성질(性質) 및 냉동(冷凍)반죽의 안정성(安定性))

  • Suh, Sook Chool;Song, Hyung lk;Chung, Ki Taek
    • Current Research on Agriculture and Life Sciences
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    • v.5
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    • pp.75-80
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    • 1987
  • We investigated physico-chemical properties of hard wheat flours for frozen yeast-raised breadmaking and freezing stability of frozen dough prepared by the straight no-time method. The general Composition of wheat flours were : moisture ; 14.0%, ash ; 0.48%. protein ; 13.15%, and dry gluten ; 13.43%. In farinograph data, development time and water absorption were 5.5 mimutes and 62 %, respectively. Amylograph maximum viscosity was 500 BU. Resistance to extention increased with the time and their extensibility decreased in the extensigraph data. From these results obtained from these physico-chemical properties, it was confirmed that the used wheat flours were most suitable for bread-baking. Considering effect of gassing power on cold storage period and fermentation time, it was effective that dough temperature should be adjusted to $20^{\circ}C$ in order to decrease freezing injury and maintain freezing stability.

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A Study on the Thermal Stability of Duplex High Mn-Steel Structure (고 망간강 2상 혼합조직의 열적 안정성에 관한 연구)

  • Wey, Myeong Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.13-22
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    • 1992
  • The thermal stability of duplex high Mn-steel structure have been investigated using 15%Mn~1.0~2.4%C steels which are composed of ${\gamma}$-and ${\theta}$-phases in the range of temperature from 900 to $1100^{\circ}C$, and time from 50 to 300h. The results are as follows ; 1) The grain growth in single-phase region proceeds by grain boundary migration and the relation between mean radius $\bar{r}$ and annealing time t is described as follows ; $\bar{r}^2-{\bar{r}_0}^2=k_0{\cdot}t$ 2) The grain growth of duplex, (${\gamma}+{\theta}$), strucrure is slower than that single phase because the chemical composition of ${\gamma}$-and ${\theta}$-phases differs esch others. 3) The grain of (${\gamma}+{\theta}$) duplex structure grow slowly in a mode of Ostwald ripening. Because grain boundaries of ${\gamma}$-phase migrate under a restriction of pinning by ${\theta}$-phases. 4) In the duplex structures. the dispersed structures change to the dual-structures, as the volume fraction of the dispersed second-phase increase. Consequently, the growth-law, which is controlled by boundary-diffusion change to that of the volume diffusion-mechanism.

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Effect of Dewaxing Ratio of Beeswax-treated Hanji by Heat and Pressure Method on Aging Behavior of Dewaxed Hanji (가온 가압법에 의한 밀랍도포한지의 탈랍율이 탈랍지의 열화 거동에 미치는 영향)

  • Cho, Byoung-Uk;Choi, Do-Chim;Jo, Byoung-Muk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.15-21
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    • 2012
  • The optimum dewaxing ratio in dewaxing treatment by the heat and pressure method was investigated by considering aging stability of dewaxed Hanji. Commercial Hanji was coated with beeswax and thermally aged at $150^{\circ}C$ for 24 hours. Then it was dewaxed using the laboratory sheet press equipped with hot plates on both top and bottom sides. Dewaxing ratio was controlled by pressing temperature and time. Four type of dewaxed Hanji samples with different dewaxing ratio were prepared and thermally aged at $150^{\circ}C$. Then the aging stability of dewaxed Hanji samples was evaluated in terms of optical and strength properties. It was found that the aging stability of dewaxed Hanji was superior with higher dewaxing ratio. The result concluded that, in the aspect of aging stability, the coated beeswax in beeswax-treated Hanji shall be completely removed if the coated wax would be dewaxed.

Stability Study of the Pigment Extract from Yangha (Zingiber mioga ROSC) (양하 추출액의 색소 안정성 연구)

  • Kim, Myung-Hyun;Han, Young-Sil
    • Korean journal of food and cookery science
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    • v.32 no.3
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    • pp.325-332
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    • 2016
  • Purpose: The purpose of this study was to investigate the stability of anthocyanin pigment extract from Yangha (Zingiber mioga ROSC). Methods: Yangha extract was investigated for the effects of metal ion, temperature, light, heating time, sugars, and organic acids on the stability of anthocyanin pigments. Results: Yangha pigment was more stable than other anthocyanin pigments at unstable temperatures. The stability of anthocyanin pigment significantly decreased one day after exposure to light. All tested sugars decreased the abundance of Yangha pigments, with highest levels in the presence of sucrose, and progressive decrease in the presence of maltose, fructose, glucose and galactose, in order. Among the organic acids tested, citric acid and malic acid were the most effective in stabilizing the Yangha pigment, followed by acetic acid and formic acid. Most metal ions except $Fe^{2+}$ were effective in stabilizing the pigment. Conclusion: These results provide useful reference data for the use of pigments from Yangha in processed foods.

Changes in the Moisture Stability of $CaS:Eu^{2+}$ Phosphors with Surface Coating Methods

  • Yoo, Sun-Hwa;Kim, Chang-Keun
    • Macromolecular Research
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    • v.17 no.11
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    • pp.907-911
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    • 2009
  • To improve the moisture stability of the $CaS:Eu^{2+}$ red phosphor, surface coatings with silica nanoparticles were performed using five different methods, i.e., $P_1$, $P_2$, $P_3$, $P_4$, and $P_5$. The phosphors were coated with silica nanoparticles using a dip coating method ($P_1$) and sol-gel method ($P_2$). The phosphors were coated using a solution containing silica nanoparticles and poly(1-vinyl-2-pyrrolidone), PVP, $(P_3$). The phosphors were also coated with silica nanoparticles by reacting with the 1-vinyl-2-pyrrolidone (VP) monomer ($P_4$) or by reacting with mixtures containing VP and tetraethylorthosilicate ($P_5$). A decrease in the photoluminescence (PL) intensity was observed regardless of the coating methods. However, the moisture stability of the phosphors was enhanced by the coating when aged in a temperature-controlled humidity chamber. Among these methods, the $P_4$ (or $P_5$) method exhibited the greatest increase in moisture stability of the phosphors. The coated phosphors showed a relatively constant intensity with aging time, whereas the uncoated phosphor showed a decrease.