• Title/Summary/Keyword: Temperature drift

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Kinetics of Seed Growth of α-Ferric Oxyhydroxide (α-Ferric oxyhydroxide 입자의 핵성장 반응에 관한 연구)

  • Seul, Soo-Duk;Shin, Dong-Ock
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.602-609
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    • 1997
  • The seed formation and growth of $\alpha$-ferric oxyhydroxide with aerial oxidative precipitation from aqueous solution of ferrous sulfate with KOH, NaOH, $Na_2CO_3$ and $K_2CO_3$ as precipitants have been studied by free pH drift experiment. It has been shown that all precipitants give same particle formation and growth path, and average particle length from KOH and NaOH as precipitants was about 1.5 times shorter than that of $K_2CO_3$ and $Na_2CO_3$. When initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$ of KOH was decreased the particle was grown oxyhydroxide seed growth from aqueous solution of ferrous sulfate with KOH has been studied. The influence of the air flow rate, reaction temperature and initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$, on the kinetics of seed growth are investigated by static pH experiment. The oxidation rate of seed growth increased with increase in the air low rate, reaction temperature and initial mole patio. The activation energy of seed growth is 16.16 KJ/mol and the rate equation of seed growth can be written as follows: $-\frac{d[Fe^{2+}]}{dt}=1.46{\times}10^4[P_{o2}]^{0.66}[OH^-]^{2.19}exp(-\frac{16.16}{dt})$.

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Distribution and Migration of Flying Squid, Ommastrephes bartrami (LeSueur), in the North Pacific (북태평양에 있어서 빨강오징어 Ommastrephes bartrami (LeSueur)의 분포 및 회유)

  • GONG Yeong;KIM Yeong Seung;KIM Soon Song
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.2
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    • pp.166-179
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    • 1985
  • The seasonal distribution and migration of flying squid, Ommastrephes bartrami (LeSueur), in the North Pacific were studied by means of mantle length, surface temperature, and catch and effort data of the Korean drift gillnet fishery from 1980 to 1983. The water temperature for the best fishing ranged from $15^{\circ}\;to\;16^{\circ}C$ in May through July and from $13^{\circ}\;to\;18^{\circ}C$ in August through January. High densities of flying squid were found in the thermal fronts with $18^{\circ}C$ isotherm in August and with $15^{\circ}C$ isotherm in September. The densities of flying squid were higher in the western region than in the eastern region in the North Pacific. The high densities of flying squid in the northwestern Pacific were attributed to the high gradients of oceanographic properties in the region. Migration models for flying squid were hypothesized based on the monthly distributions of catch per unit net, mantle length compositions by statistical blocks, and the hydrographic features of the North Pacific. The large flying squid moved to the northern region and to the central Pacific region earlier than the small sized group in the northward migration period (from June to August). Flying squid begin the reverse southward migration from the Subarctic Frontal Zone in autumn with onset of cooling and the development of Oyashio Current. The large sized group starts their southward return migration from more northern waters than the small sized group but the former moves past the later ana reaches the spawing ground first.

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Characterization of Water-Filled Ag/AgCl Reference Electrode

  • Bahn Chi Bum;Oh Sihyoung;Hwang Il Soon;Chung Hahn Sup;Jegarl Sung
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.87-93
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    • 2001
  • Pressure-balanced external Ag/AgCl electrode has been extensively used for both Pressurized Water Reactor (PWR) and Boiling Water Reactor (PWR) environments. The use of KCI-based buffer solution often becomes the source of electrode potential drift due to slow leakage through its porous plug, typically made of zirconia. It is reported that results of our effort to improve the stability of electrode potential by using high purity water as the filling solution in which $Cl^-$ ion activity can be established and maintained at the solubility of AgCl even with the sustained leakage for a long period. Stability tests have been made in boron and lithium mixture solution at $288^{\circ}C$. The electrode potential remained stable within 10 mV over one week period. And after a thermal cycle between 288 to $240^{\circ}C$ the potential shift of Ag/AgCl electrodes did not exceed 15 mV By using the limiting equivalent ionic conductances and Agar's hydrodynamic theory, the thermal liquid junction potential (TLJP) of the electrode has been predicted. The calculated values for the water-fiued Ag/AgCl electrode potential, in which the chlorine concentration in the filling solution was derived from the measured data at ambient temperature, had a good agreement with the experimental values.

Athermalization and Narcissus Analysis of Mid-IR Dual-FOV IR Optics (이중 시야 중적외선 광학계 비열화·나르시서스 분석)

  • Jeong, Do Hwan;Lee, Jun Ho;Jeong, Ho;Ok, Chang Min;Park, Hyun-Woo
    • Korean Journal of Optics and Photonics
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    • v.29 no.3
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    • pp.110-118
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    • 2018
  • We have designed a mid-infrared optical system for an airborne electro-optical targeting system. The mid-IR optical system is a dual-field-of-view (FOV) optics for an airborne electro-optical targeting system. The optics consists of a beam-reducer, a zoom lens group, a relay lens group, a cold stop conjugation optics, and an IR detector. The IR detector is an f/5.3 cooled detector with a resolution of $1280{\times}1024$ square pixels, with a pixel size of $15{\times}15{\mu}m$. The optics provides two stepwise FOVs ($1.50^{\circ}{\times}1.20^{\circ}$ and $5.40^{\circ}{\times}4.23^{\circ}$) by the insertion of two lenses into the zoom lens group. The IR optical system was designed in such a way that the working f-number (f/5.3) of the cold stop internally provided by the IR detector is maintained over the entire FOV when changing the zoom. We performed two analyses to investigate thermal effects on the image quality: athermalization analysis and Narcissus analysis. Athermalization analysis investigated the image focus shift and residual high-order wavefront aberrations as the working temperature changes from $-55^{\circ}C$ to $50^{\circ}C$. We first identified the best compensator for the thermal focus drift, using the Zernike polynomial decomposition method. With the selected compensator, the optics was shown to maintain the on-axis MTF at the Nyquist frequency of the detector over 10%, throughout the temperature range. Narcissus analysis investigated the existence of the thermal ghost images of the cold detector formed by the optics itself, which is quantified by the Narcissus Induced Temperature Difference (NITD). The reported design was shown to have an NITD of less than $1.5^{\circ}C$.

Design and Fabrication of 4-beam Silicon-Micro Piezoresistive Accelerometer for TPMS Application (TPMS용 4빔 실리콘 미세 압저항형 가속도센서의 설계 및 제작)

  • Park, Ki-Woong;Kim, Hyeon-Cheol
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.49 no.2
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    • pp.1-8
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    • 2012
  • This paper presents the accelerometer which is a key component of TPMS(Tire Pressure Monitoring System). Generally a piezoresistive accelerometer has characteristics of lower cost, better linearity and better immunity about the environmnet noise than a capacitive one. Three types of piezoresistive accelerometers are degined and simulated using ANSYS program. The best one is a piezoresistive sensor which is supported by four beams located at the center of the edge of the mass after comparing the characteristics of resonant frequency of the three types. Considering the sensor size and a simulated maximum stress and maximum displacement, the length of beams is set as $200{\mu}m$. The size of a piezoresistive accelerometer is $3.0mm{\times}3.0mm{\times}0.4mm$. The sensor output is characterized by measuring the output characteristic depending on angle. As a result the offset voltage of the accelerometer is 43.2 mV and its sensitivity is $42.5{\mu}V/V/g$. The temperature bias drift is measured. The shock durability of the sensor is 1500g and the measuring range is 0 ~ 60 g.

Atom-by-Atom Creation and Evaluation of Composite Nanomaterials at RT based on AFM

  • Morita, Seizo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.73-75
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    • 2013
  • Atomic force microscopy (AFM) [1] can now not only image individual atoms but also construct atom letters using atom manipulation method [2]. Therefore, the AFM is the second generation atomic tool following the well-known scanning tunneling microscopy (STM). The AFM, however, has the advantages that it can image even insulating surfaces with atomic resolution and also measure the atomic force itself between the tip-apex outermost atom and the sample surface atom. Noting these advantages, we have been developing a novel bottom-up nanostructuring system, as shown in Fig. 1, based on the AFM. It can identify chemical species of individual atoms [3] and then manipulate selected atom species to the designed site one-by-one [2] to assemble complex nanostructures consisted of many atom species at room temperature (RT). In this invited talk, we will introduce our results toward atom-by-atom assembly of composite nanomaterials based on the AFM at RT. To identify chemical species, we developed the site-specific force spectroscopy at RT by compensating the thermal drift using the atom tracking. By converting the precise site-specific frequency shift curves, we obtained short-range force curves of selected Sn and Si atoms as shown in Fig. 2(a) and 2(b) [4]. Then using the atom-by-atom force spectroscopy at RT, we succeeded in chemical identification of intermixed three atom species in Pb/Sn/Si(111)-(${\surd}3$'${\surd}3$) surface as shown in Fig. 2(c) [3]. To create composite nanostructures, we found the lateral atom interchange phenomenon at RT, which enables us to exchange embedded heterogeneous atoms [2]. By combining this phenomenon with the modified vector scan, we constructed the atom letters "Sn" consisted of substitutional Sn adatoms embedded in Ge adatoms at RT as shown in Fig. 3(a)~(f) [2]. Besides, we found another kind of atom interchange phenomenon at RT that is the vertical atom interchange phenomenon, which directly interchanges the surface selected Sn atoms with the tip apex Si atoms [5]. This method is an advanced interchangeable single atom pen at RT. Then using this method, we created the atom letters "Si" consisted of substituted Si adatoms embedded in Sn adatoms at RT as shown in Fig. 4(a)~(f) [5]. In addition to the above results, we will introduce the simultaneous evaluation of the force and current at the atomic scale using the combined AFM/STM at RT.

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Vegetation Characteristics of Coastal Sand Dune in the East Coast (동해안 해안사구의 식생특성)

  • Han, Young-Hoon;Lee, Yong-Ho;Kim, Jong-Bong;Cho, Kwang-Jin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.16 no.1
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    • pp.55-69
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    • 2013
  • The phytosocialogical study on the coastal sand dune vegetation of the East Coast was carried out. 180 phytosociological relev$\acute{e}$s of 62 sites in the East Coast were used in this study. In addition, already published syntaxa and the phytosociological hierarchy in Korea and Japan were used and comparative analyses of syntaxonomy, synecology, syngeography, and syndynamics were performed in the study. In this study, the flora was investigated 30 families, 66 genera, 77 taxa and 3 vegetation types were identified : the coastal drift-line annual communities (Calystegio soldanellae-Salsoletum komarovii), the dune glasslands communities (Elymo-Caricetum kobomugi, Carex kobomugi typical community, Elymus mollis community, Calystegia soldanella community, Zoysia macrostachya community, Cynodon dactylon community, Carex pumila community), and the dune shrubs communities (Linario-Viticetum rotundifoliae, Vitex rotundifolia community, Rosa rugosa community). The aspect of transition in the coastal sand dune vegetation of the East Coast were identified as follows : (1) reduced constancy degree and cover degree of Glehnia littoralis in each community; (2) lack of Ischaemum anthephoroides in Linario-Viticetum rotundifoliae (3) simplified species composition in Vitex rotundifolia community. Unstable habitat condition by external interference seemed to has caused the reduction of 2 taxa, Glehnia littoralis and Ischaemum anthephoroides, that usually grow in the second dune. In addition, we found changes in the distribution of the dune shrub communities influenced by rising temperature of the East Coast as results of the global warming. The results on the distribution of the dune shrub communities in this study demonstrated that the limit of the Rosa rugosa community made $0^{\circ}$ 44'N to the North and the vegetative limit of the Vitex rotundifolia community made $0^{\circ}$ 28'N to the North, respectively compared with the previously phytosociological studies. This study investigated the coastal sand dune vegetation, syntaxonomy, habitat condition and human disturbunce of the East Coast, and this will provide important information as basic data for the coastal ecosystem.

Report of East Sea Crossing by Underwater Glider (수중 글라이더를 이용한 동해 횡단 사례 보고)

  • Park, Yo-Sup;Lee, Shin-Je;Lee, Yong-Kuk;Jung, Seom-Kyu;Jang, Nam-Do;Lee, Ha-Woong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.2
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    • pp.130-137
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    • 2012
  • The underwater glider using conception of Lagrangian method, is a new observation platform to understand the properties of the ocean vertically. In 2011 March, KORDI made a first successful autonomous trip from Hupo to west coast of Uleungdo piloting Littoral Glider of Alaska Native Technology LLC. The journey considered many environmental variables and route vigilantly selected, the glider covered 177 km horizontally and took approximately 6 days (153 hours). Despite the existence of 1 kt eddy current, Sound velocity sampling was conducted from 5 meters and reaching maximum of 200 meters depth at each dive. It successfully collected sound velocity and temperature profile at every 5 seconds totaling up to 1408 profiles using SVT&P sensor. During the flight it was also a mission to check the diverse modes of the glider i.e. spiral, waypoints, heading, drift and hover could function without a defect in a given situation. These modes were thoroughly monitored and it could be considered that the glider handled it well during the flight. As a result of this test flight, it was evident that the given underwater glider could operate under 2kt current environment with users defined heading and depth, also with the payload up to 5 kg without changing internal buoyancy.

Characteristics of Surface Sedment and Seasonal Variation of Suspended Sediment in the Masan Bay, South Coast of Korea (한국 남해 마산만의 표층퇴적물 특성과 부유퇴적물의 계절별 변화 양상)

  • Choi, Jae Ung;Woo, Han Jun;Choi, Dong Lim;Lee, Tae Hee
    • Journal of Wetlands Research
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    • v.8 no.3
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    • pp.67-77
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    • 2006
  • Sedimentological investigations on surface and suspended sediments were performed in Masan Bay of the South Sea in order to reveal recent changes in depositional environments concerning anthropogenic influence. Surface sediments had been classified as 3 sediment facies: mud, slightly gravelly mud, and gravelly mud. In general, mud facies with more than 60% of silt is predominant and slightly gravelly mud facies occurs at the watercourse of bay's central area. The silt-dominant mud faices appears to be predominant before and after dredging. Temperature and salinity changes during one tidal cycle for each season suggest that water columns were stratified without vertical mixing regardless of the season due to weak intensity of tide from the effect of geographical features. The effect of freshwater discharge from the land seems to be insignificant. The strongest current was observed during ebb tide in spring and autumn while observed during flood tide in summer and winter. Net sediment flux (fs) and net suspended sediment transport (Qs) for suspended sediment were determined by remaining drift developed here. Net suspended sediment transport loads were seaward with $62.02{\times}10^3kgm^{-1}$, $31.84{\times}10^3kgm^{-1}$ in spring and fall, respectively, and landward with $18.23{\times}10^3kgm^{-1}$, $3.22{\times}10^3kgm^{-1}$ in summer and winter, respectively.

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A STUDY ON THE FOOD OF THE GOBY, SYNECHOGOBIUS HASTA (풀망둑 Synechogobius hasta (TEMMINCK et SCHLEGEL)의 먹이 조사)

  • PAIK Eui-In
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.2 no.1
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    • pp.47-62
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    • 1969
  • A goby, Synechogobius hasta (Temminck et Schlegel) was studied to investigate the food consumed and the biological change of the food organisms, and the fish were sampled from the closed tributary and the lower Part of the Naktong River, near Pusan, during the period from November of 1967 to December of 1968. The fish were sampled from four stations (Fig. 1), the total number of fish being 1,295 and they were grouped and analysed monthly. The content of the alimentary canal was analysed in three categories according to modified Nilsson's method (Dahl 1962) with a slight alteration: 1) The number of each item of stomach contents was counted and the percentage of each item in proportion to the total number of food organisms is indicated by the letter 'N' representing numerical percentage in Table 2. 2) The percentage of fish which contained any items of food organisms in proportion to the total number of fish caught in a given season is indicated by the letter 'O' representing frequency of occurrence. 3) Dominant groups of food items were selected and the percentage of the number of each dominant item in proportion to the number of the food organisms belonging to the dominant groups is indicated by the letter 'D' representing dominance. All food organisms were classified in 50 food item categories and then they were grouped in 13 main groups (Fig. 2-1), and they were further divided into 1) obligatory bottom animals, 2) organic drifts and 3) actively swimming forms; according to the conditions of the animal communities within the habitat. Since the majority of its food was composed of the obligatory bottom animals ($94.6\%$), the fish appeard to be a typical bottom feeder. And the dominant food organisms of the fish is generally determined by the local composition of the benthic fauna within the fish habitat. And their seasonal rhythm occurs among the food organisms in the stomach by the biological interaction. Locality variation in the population of the same food organism occurs due to the difference of food organisms in the habitat of the fish at Seonam and Garak, and at Seongsan and Hadan the condition of the niche for the fish in the both regions seems to be the same since the composition and the seasonal variation of the organisms were the same. The results may be summarized as follows: 1) The goby mainly feed on the animals of bottom fauna, and the food organisms are deter-mined by the food compositions within the habitat. 2) Seasonal variation of the stomach content shows the seasonal rhythm due to the biological variation of the population and their interaction. 3) The goby shows no preference on specific food, and the food is composed of a variety of animals. 4) Major food items of the goby are Polychaeta, Palaemon modestus, Isopoda, Gammaridea, Insecta (nymphs and larvae), Ilyoplax deschampsi, and Paratye compressa. 5) Logitudinal succession oil the population of the food organisms is apparently recognized within the community of Seongsan, Garak and Seonam. 6) The goby begins to descend toward the estuary and sea around April when the water temperature reaches $20^{\circ}C$, and they begin to return to river waters in September.

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