• Bulletin of the Korean Chemical Society
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• 제17권11호
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• pp.995-999
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• 1996

A method for the determination of cobalt(Ⅱ) by differential pulse voltammetry using a carbon paste electrode constructed by incorporating 1-(2-pyridylazo)-2-naphthol(PAN) into a conventional carbon paste mixture composed of graphite powder and Nujol oil has been developed. Several influencing factors for the determination of cobalt(Ⅱ) were studied in detail and the optimum analytical conditions were found to be as follows: pH, 4.6; composition of electrode, 20%; temperature of deposition, 43 ℃; time of preconcentration, 15 min. Regeneration of the electrode surface for the continuous uses of the electrode was achieved by exposing the carbon paste electrode to an acidic solution. Response of the electrode was reproducible for the uses of five times and the relative standard deviations were 6.7 and 4.6% for 2.0×10-5 M and 4.0×10-6 M cobalt(Ⅱ), respectively. The calibration curve for cobalt(Ⅱ) obtained by differential pulse voltammetry was divided into two linear ranges of 1.7× 10-6-1.3×10-4 M and 2.0×10-7-8.0×10-7 M. The detection limit was estimated to be 1.3×10-7 M. The effects of coexisting ions were also investigated to test the applicability of the proposed method to the determination of cobalt(Ⅱ) in real samples.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2019년도 학술발표회
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• pp.103-103
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• 2019

본 연구에서는 Terra MODIS 위성영상과 Mapping Evapotranspiration at high Resolution with Internalized Calibration (METRIC) 모형을 이용하여 2012년부터 2017년까지 한반도 전국의 증발산량을 산정하고 플럭스 타워 실측 증발산량과 비교하였다. METRIC은 전 세계에 널리 적용된 바 있는 에너지 수지 기반의 Surface Energy Balance Algorithm for Land (SEBAL) 모형의 개념과 기술을 기반으로 현열(Sensible Heat Flux) 추정 모듈을 개선한 모형이다. 본 연구에서 METRIC 모형은 기존 C#으로 개발되어 있던 SEBAL 코드에서 현열 추정 모듈을 수정하였고 연산 속도 개선을 위해 Python으로 재작성하였다. METRIC 모형의 위성 자료로 Terra MODIS 위성의 MOD13A2(16day, 1km) NDVI, MOD11A1(Daily, 1km) Land Surface Temperature (LST) 및 MCD43A3(Daily, 500m) Albedo를 구축하였으며 500m 공간해상도의 Albedo는 1000m 해상도로 resample하여 활용하였다. 기상자료는 기상청 기상관측소의 풍속, 풍속측정높이, 습도, 10분 간격 이슬점 온도, 일사량 자료를 위성 자료와 같은 공간해상도로 내삽(Interpolation)하여 구축하였다. 모형결과 검증을 위해 국내 플럭스 타워 (설마천, 청미천, 덕유산) 증발산량 관측 자료와의 결정계수(Coefficient of determination, $R^2$), RMSE(Root mean square error) relative RMSE (RMSE%), Nash-Sutcliffe efficiency (NSE) 및 IOA(Index of Agreement)를 산정하고, 기존 SEBAL 모형 결과와의 비교를 통해 본 모형의 개선점을 보이고자 한다.

• 한국태양에너지학회 논문집
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• 제33권3호
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• pp.17-26
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• 2013

The aim of this study is to analyze the performance of a parabolic trough solar collector (PTC) for water heating and to validate the model performance. The simulated model was compared, calibrated and verified with the experimental results. RMSE (Root mean square error) was used to calibrate the convective heat transfer coefficient between the absorber pipe and the ambient air which was the main factor affecting the heat transfer associated with the PTC. The calibrated model was better fitted with the experimental model. The maximum, minimum and mean deviation between the measured and predicted water temperatures differed only $0.81^{\circ}C$, $0.09^{\circ}C$ and $0.31^{\circ}C$ respectively in the calibrated model. RMSE values were decreased from 0.5389 to 0.4910, 0.0134 to 0.0125 and R-squared was increased from 0.9955 to 0.9956 after calibration. The temperature of water was increased from $33.7^{\circ}C$ to $48^{\circ}C$ in 12hour test. The thermal efficiency of the collector was calculated to be 55%. The calibrated model showed good agreement with the experimental data for model validation.

• 웰빙융합연구
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• 제5권3호
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• pp.27-41
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• 2022

Purpose: In this study, pollutants generated in industrial areas were measured using a Portable Air Quality Measurement System(PAQMS). This study intends to examine in detail improvement measures and operational capabilities to operate a more efficient PAQMS. Research design, data and methodology: This study compares and analyzes the measurement values of the PAQMS and the measurement values of the national air quality measurement network. It is intended to develop a PAQMS corresponding to the data of the national measurement network by minimizing the errors that occur during comparative measurement and analysis and supplementing and improving the problems that occur during the current equipment calibration. Results: A PAQMS is an essential equipment for faster and more accurate measurement and analysis of pollutants in case of untimely measurement and civil complaints due to Micro Climate(local weather and environmental influences). Currently, there are many atmospheric measurement equipment in Korea, but only equipment for each item is produced and sold. Currently, these devices on the market must satisfy various conditions such as stable power, temperature, and humidity to calculate accurate measurement values. Conclusions: Therefore, there is no equipment that satisfies the conditions for performing detailed measurement in the field where accurate measurement is required. In this study, these field work conditions and contents for stable measurement were mentioned in the text.

• 분석과학
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• 제35권4호
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• pp.153-160
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• 2022

A green spectrophotometric method for the determination of cyanide has been proposed using, a green reagent, aqueous extract of blue butterfly pea. The test tube was filled with anthocyanin rich extract (pH 6) and cyanide solution. The reaction was kept constant for 10 minutes at room temperature. The reaction mixture changed color from blue to green as the amount of CN-ions increased. The 620 nm peak intensity increased with CN concentration. Therefore, this wavelength was used for all cyanide analyses. The cyanide calibration curve had a linear range of 0.25-1.00, 1.00-4.00, and 4.00-10.00 mg/L, with a satisfactory correlation coefficient of 0.99 and a LOD of 0.57 mg/L. The recovery ranged from 8.33 to 76.94 percent, indicating that this method is inaccurate at low cyanide concentrations. The intra-day and intermediate precision relative deviations were 0.391-0.871 % and 1.112-1.583 %. An H-bond forms between the C-4 group of the B-carbonyl ring and the HCN molecule according to the B3LYP/TZVP calculation. The method is convenient for cyanide concentrations above the LOQ of 1.09 mg/L, cost-effective, and capable of reducing toxic solvents with acceptable precision. The method could also be used to detect total cyanide in biological, environmental, and industrial waste samples.

• Nuclear Engineering and Technology
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• 제55권5호
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• pp.1718-1733
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• 2023

The virtual Frisch-grid method for room-temperature radiation detectors has been widely used because of its simplicity and high performance. Recently, side electrodes were separately attached to each surface of the detectors instead of covering the entire detector surface with a single electrode. The side-electrode structure enables the measurement of the three-dimensional (3D) gamma-ray interaction in the detector. The positional information of the interaction can then be utilized to precisely calibrate the response of the detector for gamma-ray spectroscopy and imaging. In this study, we developed a 3D position-sensitive 5 × 5 × 12 mm³ cadmium-zinc-telluride (CZT) detector and applied a flattening method to correct detector responses. Collimated gamma-rays incident on the surface of the detector were scanned to evaluate the positional accuracy of the detection system. Positional distributions of the radiation interactions with the detector were imaged for quantitative and qualitative evaluation. The energy spectra of various radioisotopes were measured and improved by the detector response calibration according to the calculated positional information. The energy spectra ranged from 59.5 keV (emitted by ²⁴¹Am) to 1332 keV (emitted by ⁶⁰Co). The best energy resolution was 1.06% at 662 keV when the CZT detector was voxelized to 20 × 20 × 10.

• 대한토목학회논문집
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• 제28권6B호
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• pp.675-681
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• 2008

기상자료가 부족하거나 결측인 지역의 기준 증발산량 산정을 위해서는 Hargreaves 공식의 매개변수 추정을 수행할 필요가 있다. 본 연구에서는 우리나라 전역에 걸쳐 1997년-2006년 기상자료를 바탕으로 Hargreaves 공식을 이용하여 기준 증발산량(이하 ETo)을 산정하였다. 각 지점별로 PM공식에 의해 산정한 값을 증발산량의 정해로 가정하여 Hargreaves 매개변수를 지점별로 추정하였다. 최소의 오차가 발생하도록 Hargreaves 계수를 조정한 후 Root Mean Square Error와 Nash Sutcilffe Coefficient of Efficiency분석을 통하여 추정효율이 크게 향상되는 것을 알 수 있었다. 또한 추정된 매개변수를 바탕으로 기온 자료만의 의한 Hargreaves 증발산량을 추정할 수 있도록 일반화된 하나의 회귀직선을 도출하여 보았다. 온도-Hargreaves 계수의 선형 상관관계를 이용한 Hargreaves 계수의 일반화에서는 개선의 여지가 있지만 만족스러운 결과를 보여주는 것으로 나타났다. 이 연구결과는 우리나라의 수자원, 관개분야 및 환경 운용에 많은 도움이 될 것으로 판단된다.

• Journal of the korean society of oceanography
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• 제37권1호
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• pp.27-34
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• 2002

We measured the alkenone concentration of bulk sediments from a piston core collected from the Ulleung Basin in the East Sea in order to reconstruct past sea surface temperatures (SST). Sediment ages are well constrained by AMS $^{14}C$ dates of the planktonic foraminifera Globigerina bulloides. Coretop alkenone SST calibration with modern surface temperatures and sediment trap dat (Hong et al., 1996) indicate that the SST estimated from alkenones most likely represent the temperatures of late fall. Downcore variations in the alkenone saturation index indicate that between 19 and 15 kyr BP the surface waters were about $3^{\circ}C$ warmer than today. Between 15 and 11 kyr BP, the temperatures were about $3^{\circ}C$ lower than today. A rapid SST increase of about $3^{\circ}C$ occurred at approximately 10 kyr BP. After considering the factors which might influence the SST reconstruction from the $U^{k'}_{37}$ values, we conclude that the alkenone temperature estimates are reliable. The reason for glacial warming in the East Sea is not clear, although there is a possibility that it could be caused by shift in the season of maximum alkenone production from summer during the last glaciation to late fall during the Holocene. Cooling between 15 and 11 kyr BP may be due to inflow of cold water into the East Sea such as via the Oyashio Current or ice-melt water. Warming at the early Holocene could be due to inflow of the Tsushima Current into the East Sea through the Korea Strait.

• 한국치위생학회지
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• 제16권5호
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• pp.783-790
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• 2016

Objectives: The purpose of this study is to evaluate the non-enzymatic antioxidants stabilities in dentifrices by ascorbic acid and tocopherol according to the chemical condition. Methods: For the analysis of two antioxidants, HPLC UV detector system was used. HPLC was performed using sodium sulfate, acetonitrile(ACN), methanol(MeOH) and measuring absorbance at 240-295 nm. To confirm general pH reaction of two compounds, buffer solution was prepared for the analysis. The dentifrice was titrated by pH so as to examine the change of elapsed time in dentifrice. Linearity of calibration curve of two antioxidants was measured. Results: Each compound showed good linearity at optimized wavelength as well as showing good precision. General pH reaction of two antioxidants was examined. Ascorbic acid showed the highest residue(63.23%) at pH 10 and the lowest residue(2.77%) at pH 4. Tocopherol showed the highest residue(55.70%) at pH 7 and the lowest residue(3.31%) at pH 4. As a result of changing elapsed time of antioxidants in dentifrice by pH, components were remained stably at low temperature($39.2^{\circ}F$) and pH 7. Conclusions: It is necessary to keep dentifrice including ascorbic acid and tocopherol, and non-enzymatic antioxidants at pH 7 and low temperature for improving chemical stability.

• 대한공간정보학회지
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• 제1권2호
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• pp.185-194
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• 1993

원격탐측은 초기에는 자연현상이나 지표대상물의 개략적인 분포와 변화를 추출하는데 사용되어 왔으나 최근에는 식물의 분광특성을 이용한 농업조사, 산림조사나 지하자원탐사, 해양상의 수온 및 해류분포조사, 기상조사 등 많은 분야에 응용되고 있다. 본 연구에서는 이와 같은 원격탐측의 많은 응용분야 중에서 해양으로 배출되는 공장온배수의 확산범위를 조사하기 위하여 지구자원 탐사위성인 LANDSAT-5호에 탑재되어 있는 TM에 의해 얻어진 영상과 지상탐측기인 열적외주사기 Thermo Tracer에 의해 얻어진 열적외 영상을 이용하였다. LANDSAT TM영상의 Band 6은 열적외 Band로서 NASA의 CSFC에서 제공한 변환식 및 사후검정값을 이용하여 Band 6의 gray level값으로부터 해수온도 분포를 추출하였으며, Thermo Tracer의 열적외 영상은 TH1100 Series의 Processing mode를 이용하여 온도분포를 얻었다. 이와 같은 영상을 분석한 결과 근해의 수심이 얕은 지역의 해수온도는 담수온도와 내륙온도의 영향을 크게 받고 있음을 알 수 있었으며, 온배수의 확산범위 및 면적을 시각적 및 정량적으로 나타낼 수 있었다. 또한 열적외선 주사영상을 이용하여 보다 세부적인 확산범위를 제시할 수 있었으며 LANDSAT영상결과와 거의 동일한 결과를 나타냄을 알 수 있다.