• Title/Summary/Keyword: Technical measurements

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Studies on the Absorption Behavior of Dye and Pigment Ink for Ink-Jet Printing (잉크제트용 염료잉크와 안료잉크의 흡수거동에 관한 연구)

  • Lee, Hee-Myung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.2 s.110
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    • pp.47-56
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    • 2005
  • In technology of ink-jet coating, Image quality from correlation between paper and ink depends on the properties of printer and ink as well as those of paper material. Generally, According to the quality of ink that consists of colorants from 5 to 20 percent, It seems that absorption behavior of each ink is different. In this study, we studied to estimate the effects of dye and pigment ink on the absorption and printing properties using 2-type papers on the market and 3-type silica-based coated papers whose pore structure is different. Using the theory of contact angle to evaluate the absorption property, it was possible to measure the baseline length between paper and ink, volume of droplet as well as contact angle. Also, It was possible to calculate wetting energy(mN/m) and spreading coefficient(mN/m) using the surface tension of each ink. These measurements were available to estimate ink-jet qualities.

The Effect of Cellulase on the Pore Structure of Cellulose Fibers

  • Park, Sun-Kyu;Venditti Richard A.;Abrecht David G.;Jameel Hasan;Pawlak Joel J.;Lee, Jung-Myoung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.43-49
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    • 2006
  • The surface and pore structure of cellulose fibers have a significant impact on the properties and performance in applications. Cellulase enzymatic hydrolysis of cellulose fibers can result in changes to the surface and pore structure thus providing a useful tool for fiber modification. This research characterizes these changes using various test methods such as fiber dimension, water retention value, hard-to-remove water content, freezing and non-freezing bound water content, polymer adsorption, and crystallinity index. For a high-dosage enzyme treatment (0.10 g/g), the fiber length was significantly decreased and the fibers were 'cut' in the cross direction, not in the axial direction. The swelling capacities as measured by the WRV and HR water content increased for the high-dosage treatment. Three independent measurements (non-freezing bound water, polymer adsorption, and crystallinity index) are in good agreement with the statement that the amorphous regions of cellulose fibers are a more readily available substrate relative to crystalline regions. Based on the experimental results obtained herein, a model was proposed to explain surface and pore structure modification of cellulose fibers via enzymatic treatment.

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Preparation of Functional Antibiotic and Deodorization Pigments Using Surface Modification Method for Special Papermaking

  • Cho, Jun-Hyung;Lee, Yong-Won;Min, Dong-Jin
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.417-421
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    • 2006
  • In this study, colloidal Ag solution was spouted on the surface of the inorganic pigment using the hybridizer system and the spray nozzle. Then, the surface of the inorganic pigment was modified by titanium dioxide in order to possess antibacterial ability. Nano-sized colloidal Ag was made by using a seed sol method in this study. It was confirmed that the size of particle per unit weight becomes enlarged, as the addition of $AgNO_{3}$ increased, and as the time of reaction increased, in the manufacturing process of nano-sized colloidal Ag. The antibacterial measurement of the inorganic pigment showed that the growth of fungus was reduced as the reaction time increased. It was measured that the antibacterial activity was excellent at fixed time frame, after the antibacterial ability appeared in $5{\sim}7$ hours of the antibacterial inoculation experiment. The experiment of titanium dioxide's Photocatalyst effect showed $60{\sim}70%$ efficiency in about 80 minute reaction time of the dissolution results regarding measurements of benzene. It was shown that more than 90% of the dissolution efficiency was achieved in the reaction time of about 30 minute.

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KINETICS OF POLYELECTROLYTE ADSORPTION ON CELLULOSIC FIBRES

  • Lars Wagberg;Sjolund, Anna-Karin
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.34-42
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    • 1999
  • The present investigation has focused up on the study of the adsorption of three different molecular mass fractions of a polyDiMethylDiAllylAmmoniumChloride (DMDAAC) (8750(LM\ulcorner), 48000(MM\ulcorner) and 1200000(HM\ulcorner)) on bleached chemical fibres. Both kinetics of adsorption and equilibrium adsorption measurements have been conducted and each adsorption has been measured by polyelectrolyte titration. The results show that the LM\ulcorner polymer can reach all of the charges in the fibre wall whereas the MM\ulcorner and HM\ulcorner can only reach the external surfaces of the fibres. It is also shown that the kinetics of adsorption of the LMw polymer is not at all affected by the presence of a saturated layer of HMw polymer on the surface of the fibres. Finally, the results from the investigation show that it is possible to have full coverage of the external surface of the fibres by a high molecular mass polymer and a full coverage of the internal surface of the fibres with a low molecular mass polymer. This is true if the high molecular masspolymer is added first followed by addition of the low molecular masspolymer.

Effect of White Water Quality on the Adsorption of Cationic PAM on Fibers (백수의 수질이 양이온성 PAM의 흡착에 미치는 영향)

  • Lee, Ji-Young;Lee, Hak-Lae;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.1 s.109
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    • pp.1-9
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    • 2005
  • Many factors which affect the adsorption of cationic polymers on fibers and fines have been investigated by many researchers that include contact time, pH, collision frequency, properties of cationic polymers and adsorbent, etc. But the effect of white water quality on the adsorption of cationic polymer have not been examined throughly. In this study, the adsorption of cationic PAM was analyzed as a function of white water quality. The adsorption of the cationic PAM was analyzed by two analysis methods, Kjeldahl nitrogen content measurement and electrokinetic measurements. When the distilled water was used, adsorbed amount of C-PAM and zeta-potential of fibers increased as a function of the addition of C-PAM. When closure level increased, nitrogen content of fibers increased indicating that the cationic PAM was adsorbed. Zeta-potential of fibers, however, showed no significant change with the increased addition of C-PAM. This showed that adsorption of C-PAM was not reflected by zeta-potential of fibers due to the deteriorated efficiency of C-PAM by the anionic contaminants in white water.

Mathematical and experimental study of hydrogen sulfide concentrations in the Kahrizak landfill, Tehran, Iran

  • Asadollahfardi, Gholamreza;Mazinani, Safora;Asadi, Mohsen;Mirmohammadi, Mohsen
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.572-581
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    • 2019
  • The emission of hydrogen sulfide (H2S) from the Kahrizak landfill was studied. Firstly, the field measurements were conducted in the summer and winter seasons; and the samples were analyzed using Jacob method. We predicted the H2S concentrations in the downwind using AERMOD and ISCST3. According to the AERMOD, the maximum concentration of H2S in the summer and winter were 117 ㎍/㎥ and 205 ㎍/㎥ respectively. The downwind concentrations reached zero at the distance of 35 km from the leachate treatment plant. The Geometric mean bias, Geometric variance, Fractional bias, Fraction of predictions within a factor of two of the observations and Normalized mean square error for the AERMOD were 0.58, 1.35, -0.12, 1.91 and 0.042, respectively in the summer and 1.39, 1.35, -0.05, 1.46 and 0.027 in the winter; and for the ISCST3, were 0.85, 1.03, 0.02, 1.45 and 0.04 in the summer and 1.18, 1.03, 0.15, 1.16 and 0.04 in the winter. The results of the AERMOD were compared with the ISCST3 and indicated that the AERMOD performance was more suitable than the ISCST3.

Evaluation of homogenized thermal conductivities of imperfect carbon-carbon textile composites using the Mori-Tanaka method

  • Vorel, Jan;Sejnoha, Michal
    • Structural Engineering and Mechanics
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    • v.33 no.4
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    • pp.429-446
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    • 2009
  • Three-scale homogenization procedure is proposed in this paper to provide estimates of the effective thermal conductivities of porous carbon-carbon textile composites. On each scale - the level of fiber tow (micro-scale), the level of yarns (meso-scale) and the level of laminate (macro-scale) - a two step homogenization procedure based on the Mori-Tanaka averaging scheme is adopted. This involves evaluation of the effective properties first in the absence of pores. In the next step, an ellipsoidal pore is introduced into a new, generally orthotropic, matrix to make provision for the presence of crimp voids and transverse and delamination cracks resulting from the thermal transformation of a polymeric precursor into the carbon matrix. Other sources of imperfections also attributed to the manufacturing processes, including non-uniform texture of the reinforcements, are taken into consideration through the histograms of inclination angles measured along the fiber tow path together with a particular shape of the equivalent ellipsoidal inclusion proposed already in Sko ek (1998). The analysis shows that a reasonable agreement of the numerical predictions with experimental measurements can be achieved.

Effect of Additive-added Epoxy on Mechanical and Dielectric Characteristics of Glass Fiber Reinforced Epoxy Composites (유리섬유강화 에폭시 레진 복합체의 기계적, 유전체 특성에 미치는 첨가제 함유 에폭시 영향)

  • Vu, Cuong Manh;Nguyen, Liem Thanh;Nguyen, Thai Viet;Choi, Hyoung Jin
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.726-734
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    • 2014
  • Three different types of additives, thiokol, epoxidized natural rubber (ENR) and epoxidized linseed oil (ELO), were dispersed in an epoxy matrix before being used in glass fiber (GF) composites, and their effects on the mechanical and dielectric properties of epoxy resin and glass fiber reinforced epoxy composites (GF/EP) were examined. The addition of each of 7 phr ENR, 9 phr ELO and 5 phr thiokol into the epoxy resin increased the fracture toughness significantly by 56.9, 43.1, and 80.0%, respectively, compared to the unmodified resin. The mode I interlaminar fracture toughness of the GF/EP at propagation was also improved by 26.9, 18.3 and 32.7% when each of 7 phr ENR, 9 phr ELO, and 5 phr thiokol, respectively, was dispersed in the epoxy matrix. Scanning electron microscopy showed that the additives reduced crack growth in the GF/EP, whereas their dielectric measurements showed that all these additives had no additional effect on the real permittivity and loss factor of the GF/EP.

Comparison of cellulose DP measurements using the CED (Cupriethylene diamine) and NMMO(N-methylmorpholine-N-oxide) (CED(Cupriethylene diamine)과 NMMO (N-methylmorpholine-N-oxide)를 이용한 셀룰로오스의 중합도 측정법의 비교)

  • Lee, Min-Woo;Park, Ji-Soon;Park, Dong-Hui;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.5
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    • pp.62-66
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    • 2010
  • Cellulosic materials were dissolved by NMMO(N-methylmorpholine-N-oxide) and CED (Cupriethylene diamine), respectively, to measure their DPs (degrees of polymerization) by using viscometer. We changed cellulose DPs by applying various amounts of low intensity electron-beam radiation to the cellulosic materials. NMMO is environmental-friendly, non-toxic, and biodegradable organic cellulose solvent and used industrially because of its high cellulose dissolving power and high solvent recovery ratio. The cellulose DP measurement results using these two different chemicals were correlated highly ($R^2$ >0.95). It was also found that cellulose with high DP was dissolved more easily in NMMO than CED. In addition, NMMO method gave more higher resolution in the measurement.

Preparation of Activated Carbon from Wastepaper and Adsorption of Endocrine Disrupting Chemicals

  • Okayama, Takayuki;Matsushita, Kiyofumi;Sasuzuki, Hiroma;Shimada, Masahiro
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.279-284
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    • 2006
  • Activated carbon is proposed as a new application of wastepaper recycling other than the paper-making. Waste kraft bag is considered to be a suitable raw material for activated carbon because of its low ash content. Small pellets of wastepaper squeezed out from the continuous kneader were carbonized in a nitrogen atmosphere and activated using carbon dioxide. The BET specific surface areas of activated carbon prepared from waste kraft bag was $1,285m^{2}/g$, which is higher than commercially available activated carbons. The activated carbon prepared from wastepaper has a well-developed porous structure, particularly in mesopore and macropore ranges. As a result, activated carbon with iodine adsorption capacity of 1,400 mg/g was obtained from waste kraft bag. In this paper, adsorption amount of Bisphenol A (BPA) was determined to investigate adsorbability of activated carbon from waste kraft bag. Adsorption measurements were on solutions ranging from $0.1{mu}g/L\;to\;100mg/L$. The activated carbon from waste kraft bag gave higher BPA adsorbabilities over a wide range, compared with commercially available activated carbons.

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