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검색결과 417건 처리시간 0.025초

폐윤활유 열분해유의 안정화 특성 연구 (Stabilization Characteristics of the Pyrolyzed Oil from Waste Lubricating Oil)

  • 김승수;김영석;전병희;박찬진;윤왕래;김성현
    • 대한환경공학회지
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    • 제22권6호
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    • pp.1055-1061
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    • 2000
  • 희분식 반응기에서 폐윤활유를 열분해하였을 때 생성된 오일의 타르생성에 관한 속도연구와 오일의 안정화 연구를 수행하였다. 열분해유에서 타르가 생성되는 과정은 직렬반응과 병렬반응이 결합된 lumped kinetic 모델을 제시하여 실험결과와 비교하였다. 제시된 모델로부터 타르를 생성하는 반응속도 결정단계는 열분해 생성유가 중간반응 단계를 거치지 않고 바로 타르가 되는 경로임을 알 수 있었다. 오일의 안정화를 위해 fly ash와 coke를 첨가하였을 때 타르를 생성하는 물질의 제거 및 산화방지 효과가 큰 것을 확인할 수 있었다.

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고체분산체를 이용한 약물의 생체이용율 향상을 위한 전략 (Solid Dispersion as a Strategy to Improve Drug Bioavailability)

  • 박준형;전명관;조훈;최후균
    • KSBB Journal
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    • 제26권4호
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    • pp.283-292
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    • 2011
  • Solid dispersion is one of well-established pharmaceutical techniques to improve the dissolution and consequent bioavailability of poorly water soluble drugs. It is defined as a dispersion of drug in an inert carrier matrix. Solid dispersions can be classified into three generations according to the carrier used in the system. First and second generations consist of crystalline and amorphous substances, respectively. Third generation carriers are surfactant, mixture of polymer and surfactants, and mixture of polymers. Solid dispersions can be generallyprepared by melting method and solvent method. While melting method requires high temperature to melt carrier and dissolve drug, solvent method utilizes solvent to dissolve the components. The improvement in dissolution through solid dispersions is attributed to reduction in drug particle size, improvement in wettability, and/or formation of amorphous state. The primary characteristics of solid dispersions, the presenceof drug in amorphous state, could be determined by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and fourier-transformed infrared spectroscopy (FTIR). In spite of the significant improvement in dissolution by solid dispersion technique, some drawbacks have limited the commercial application of solid dispersions. Thus, further studies should be conducted in a direction to improve the congeniality to commercialization.

디젤 예혼합 압축착화 엔진에서 EGR 및 수소농후가스의 영향 (The Effects of EGR and Hydrogen Enriched Gas on Diesel HCCI Engine)

  • 박철웅;조준호;오승묵
    • 한국자동차공학회논문집
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    • 제19권1호
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    • pp.1-8
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    • 2011
  • In recent years, there has been an interest in early-injection diesel engines as it has the potential of achieving a more homogeneous and leaner mixture close to TDC compared to standard diesel engine. The more homogeneous mixture may result in reduced NOx and soot emissions and higher efficiency in homogeneous charge compression ignition engines. While earlier studies have shown that a reduction in NOx emissions from HCCI engine is possible, there are some significant problems including the control of ignition timing and combustion rate. In order to investigate the effect of EGR and hydrogen enriched gas on combustion characteristics and emissions, an experiments with single cylinder CRDi engine were carried out concerning the formation of various premixed charge, which can achieved by early injection, EGR and hydrogen enriched gas. EGR was not effective to further reduce NOx and PM emissions. It was found that NOx emissions were decreased with an introduction of hydrogen enriched gas and an adequate diesel fuel amount.

WISE AND AKARI

  • Blain, Andrew W.
    • 천문학논총
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    • 제27권4호
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    • pp.367-373
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    • 2012
  • The first all-sky mid-/far-infrared survey by IRAS in the 1980s, has been followed by only two more, by AKARI, from 2006, and WISE in 2010. I discuss some features of the WISE survey, and highlight some key results from early extragalactic observations that have been made by the science team during the operation of the telescope, and the post-operation proprietary period during which the public release data products were being generated. The efficient survey strategy and very high-data rate from WISE produced a catalogue of 530 million objects that was released to the public in March 2012. The WISE survey strategy naturally provided the deepest coverage at the ecliptic poles, where matched comparison fields were obtained using Spitzer, and where AKARI also observed deep fields. I describe some of the follow-up work that has been carried out based on the WISE survey, and the prospects for enhancing the WISE data by combining the AKARI survey results are also discussed. While the all-sky AKARI survey is less deep than the WISE catalogue, and is still being worked on by the AKARI science team, it includes a larger number of bands, extends to longer wavelengths, and in particular has very complementary band passes to WISE in the mid-infrared waveband, which will provide enhanced spectral information for relatively bright targets.

Effects of Surface Nitrification on Thermal Conductivity of Modified Aluminum Oxide Nanofibers-Reinforced Epoxy Matrix Nanocomposites

  • Kim, Byung-Joo;Bae, Kyong-Min;An, Kay-Hyeok;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제33권10호
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    • pp.3258-3264
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    • 2012
  • Aluminum oxide ($Al_2O_3$) nanofibers were treated thermally under an ammonia ($NH_3$) gas stream balanced by nitrogen to form a thin aluminum nitride (AlN) layer on the nanofibers, resulting in the enhancement of thermal conductivity of $Al_2O_3$/epoxy nanocomposites. The micro-structural and morphological properties of the $NH_3$-assisted thermally-treated $Al_2O_3$ nanofibers were characterized by X-ray diffraction (XRD) and atomic force microscopy (AEM), respectively. The surface characteristics and pore structures were observed by X-ray photoelectron spectroscopy (XPS), Zeta-potential and $N_2$/77 K isothermal adsorptions. From the results, the formation of AlN on $Al_2O_3$ nanofibers was confirmed by XRD and XPS. The thermal conductivity (TC) of the modified $Al_2O_3$ nanofibers/epoxy composites increased with increasing treated temperatures. On the other hand, the severely treated $Al_2O_3$/epoxy composites showed a decrease in TC, resulting from a decrease in the probability of heat-transfer networks between the filler and matrix in this system due to the aggregation of nanofiber fillers.

Glidarc 워터젯 플라즈마를 이용한 톨루엔 분해 특성 (Decomposition Characterist of Toluene Using a Glidarc Water-jet Plasma)

  • 김성천;전영남
    • 한국대기환경학회지
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    • 제24권3호
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    • pp.329-335
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    • 2008
  • Volatile organic compounds emitted to the atmosphere can cause adverse effects on human health and participate in photochemical smog formation reactions. The destruction of a series of VOCs has been carried out by non-thermal plasma in other researches. And the characteristic of non-thermal plasma was operated at atmospheric pressure and low temperature. A new type non-thermal plasma reactor was investigated combined Glidarc plasma with water jet in this research. Also, it was found that the water-jet had an significant effect on the toluene removal efficiency. But too much water content does not favor toluene decomposition by decreasing of reaction temperature. The input toluene concentration, gas flow rate, water flow rate and specific energy input were used as experiment variables. The toluene removal efficiency, energy efficiency and specific energy input were 75.3%, 146.6 g/kWh and $1.12kWh/m^3$ at a water flow rate of 100 mL/min.

Fabrication and Characterization of the Ti-TCP Composite Biomaterials by Spark Plasma Sintering

  • Mondal, Dibakar;Park, Hyun-Kuk;Oh, Ik-Hyun;Lee, Byong-Taek
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.53.2-53.2
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    • 2011
  • Ti metal has superior mechanical properties along with biocompatibility, but it still has the problem of bio-inertness thus forming weaker bond in bone/implant interface and long term clinical performance as orthopaedic and dental devices are restricted for stress shielding effect. On the other hand, despite the excellent biodegradable behavior as being an integral constituent of the natural bone, the mechanical properties of ${\beta}$-tricalcium phosphate $(Ca_3(PO_4)_2;\;{\beta}-TCP)$ ceramics are not reliable enough for post operative load bearing application in human hard tissue defect site. One reasonable approach would be to mediate the features of the two by making a composite. In this study, ${\beta}$-TCP/Ti ceramic-metal composites were fabricated by spark plasma sintering in inert atmosphere to inhibit the formation of $TiO_2$. Composites of 30 vol%, 50 vol% and 70 vol% ${\beta}$-TCP with Ti were fabricated. Detailed microstructural and phase characteristics were investigated by FE-SEM, EDS and XRD. Material properties like relative density, hardness, compressive strength, elastic modulus etc. were characterized. Cell viability and biocompatibility were investigated using the MTT assay and by examining cell proliferation behavior.

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중간층 조건에 따른 Cr-Mo-N 막의 상형성 및 마찰마모 거동 연구 (Tribology and Phase Evolution of Cr-Mo-N Coatings with Different Interlayer Condition)

  • 양영환;여인웅;박상진;임대순;오윤석
    • 한국표면공학회지
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    • 제44권6호
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    • pp.269-276
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    • 2011
  • Phase evolution and tribological behavior of Cr-Mo-N multi compositional films with different interlayer were investigated. The films were deposited by hybrid PVD (Physical Vapor Deposition) system consisted of dc unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) sources. A pure molybdenum (Mo) was used as sputtering target and also a pure Cr was used as AIP target to form the Cr-Mo-N films. Various growth planes were found, no textured surface, in all of the multi composition films. Maximum value of microhardness was measured in Cr-Mo-N film with Mo interlayer as 29 GPa. Composition film was mainly showed the aspect of the adhesive wear than CrN film. The friction coefficient was decreased from 0.6 for pure CrN coating to 0.35 for Cr-Mo-N film with Mo interlayer. This result may come from the formation of metal oxide tribo-layer which is known as solid lubricant during the wear test.

Inhibitory Effects of Super Reductive Water on Plant Pathogenic Fungi

  • Hur, Jae-Seoun;Kim, Hae-Jin;Oh, Soon-Ok;Koh, Young-Jin;Kwak, Young-Se;Lee, Choong-Il
    • The Plant Pathology Journal
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    • 제18권5호
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    • pp.284-287
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    • 2002
  • The antifungal activity of super reductive water (SRW) against plant pathogenic fungi was examined to extend its application to integrated pest management (IPM) for plant diseases. Diluted solutions ($\times$1/10, $\times$1/25, and $\times$1/50) of SRW inhibited fungal growth of kiwifruit soft rot pathogen, Diaporthe actinidiae, in a concentration dependent manner, When kiwifruits were inoculated on wounds with mycelium blocks, stock and diluted solutions successfully inhibited the disease development. In addition to the high pH of the SRW, fungistatic activity was also considered as the cause of the antifungal effect against the pathogen. Whereas conidial germination of Magnaporthe grisea was not affected by the diluted SRW solutions, appressorium formation was significantly inhibited in a concentration dependent manner, With little harmfulness to human health and environment SRW could be used to control plant pathogenic fungi, particularly appressorium-forming fungal pathogens.

Al-Fe 레이저 오버레이층 경계면에서의 금속간화합물 거동 (Intermetallic Compounds Behavior at Laser Overlay Interface of Aluminum and Fe-based Powder)

  • 강남현;유연곤;이창우;김정한
    • Journal of Welding and Joining
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    • 제25권3호
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    • pp.51-56
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    • 2007
  • A $CO_2$ laser overlay was conducted by using a Fe-based powder on the AC2B aluminum substrate. Cracks and intermetallic compounds (IMC) were observed inconsistently along the interface between the overlay and post-molten layer. A scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) detected some Fe-rich IMC ($Fe_3Al$, FeAl) as well as the brittle Al-rich IMC ($Fe_2Al_5,\;FeAl_3$). Micro vickers hardness proved the formation of Al-rich IMC ($FeAl_3$) along the interface by showing HV0.1 $800{\sim}900$. Furthermore, nano indentation was successfully applied to investigate the behavior of IMC more precisely than the micro vickers hardness.