• Title/Summary/Keyword: Tail gas

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Preparation of ultrafine aluminum oxide powders by using R.F. induced plasma (고주파 유도 플라즈마를 이용한 산화 알루미늄 초미세분말 제조)

  • Masahiro Kagawa
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.269-277
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    • 1995
  • Ultrafine TEX>$Al_2O_3$ powders were prepared from $AlCl_3$ and $Al_2(SO_4)_3$3 by using inductively coupled plasma (lCP) of ultrahigh temperature (above 5000 K) in heat source. The prepared $Al_2O_3$ powders had ${\alpha} - group ({\alpha}, {wdelta} ;and; {\theta})$ phase, a narrow size distribution and around 20 nm in meansize. It could be suggested that gas - solid reaction growth and interparticle sintering occured at the center of ICP tail flame (X = 500 mm) through the results of deposited aggregates - flock, whisker and platy on MgO polycrystal plate. And the formation mechanism of $Al_2O_3$ powders In spray - ICP reactor were described from upper results.

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The Optical and IR Properties of Peculiar early-type galaxies from Stripe82 and WISE Data

  • Hong, Jueun;Im, Myungshin
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.90.2-90.2
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    • 2012
  • Galaxy merging plays a important role to the formation and evolution of galaxy. Early-type galaxies are believed to be formed by galaxy merging. We combined 3 color images in g,r,i band using Stripe82 image of which the surface brightness is 2 mag deeper than that of SDSS image. We classified early-type galaxies which have the merging features, the evidence of galaxy mergers through careful visual inspection. We investigated the IR properties of early-type galaxies with the merging feature using WISE data. We analyzed the star formation according to the type of galaxy. Early-type galaxies with the merging feature show the higher star formation than non-merging galaxies, but the difference is not significant. This results implies that quite a few early-type galaxies might be formed by dry merger, not wet merger. Meanwhile, the most of ULIRGs show tidal tail, on the other hand, early-type galaxies show tidal tail including shell structure. It suggests that ULIRGs have more gas and it might be in early stage of galaxy merging, early-type galaxies might be in the late stage of galaxy merging.

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A study on the effect of additives in insulating oil under uniform electric field (평등전계중의 절연유에 미치는 첨가물의 영향)

  • 국상훈
    • 전기의세계
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    • v.30 no.6
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    • pp.357-365
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    • 1981
  • When electronegative gas SF$_{6}$ is dissolved and charged with insulating oil, the effect caused in the process by electronegative characteristic is studied and also the pressure effect caused by electronegative SF$_{6}$ acting on the liquid-level is examined respectively. When inert gas Ar is used to find a pressure effect acting on the liquid-level, its effect on dielectric strength is considered in the experiment. With three kinds of impulse voltage different in the duration of wave front and wave tail, a brief experiment if carried out ot see the effects on the dielectric breakdown characteristic as the wave is changing; either if I$_{2}$ and SF$_{6}$ are added to the insulating oil, or if the oil pressure is increased by Ar the dielectric strength becomes great and the longer the duration of wave front is, the greater the increase of the breakdown voltage, because I$_{2}$ added by a small quantity brings about some hirderance in the formation of gas phase. Likewise, the greater the changed pressure is, the greater the incerase of the breakdown voltage. When SF$_{6}$ is charged, the electronegative characteristic is prevailing at the time of low balanced pressure, and the pressure effect at the time of high balanced pressure.ressure.

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Optimization of Ammonia Decomposition and Hydrogen Purification Process Focusing on Ammonia Decomposition Rate (암모니아 반응기의 분해 효율 최적화를 통한 암모니아 분해 및 수소 정제 공정 모델 연구)

  • DAEMYEONG CHO;JONGHWA PARK;DONSANG YU
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.594-600
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    • 2023
  • In this study, a process model and optimization design direction for a hydrogen production plant through ammonia decomposition are presented. If the reactor decomposition rate is designed to approach 100%, the amount of catalyst increases and the devices that make up the entire system also have a large design capacity. However, if the characteristics of the hydrogen regeneration process are reflected in the design of the reactor, it becomes possible to satisfy the total flow rate of fuel gas with the discharged tail gas flow rate. Analyzing the plant process simulation results, it was confirmed that when an appropriate decomposition rate is maintained in the reactor, the phenomenon of excess or shortage of fuel gas disappears. In addition, it became possible to reduce the amount of catalyst required and design the optimized capacity of the relevant processes.

Separation of $H_2$/$N_2$ Gas Mixture by SiO$_2$-B$_2$O$_3$ Membrane (SiO$_2$-B$_2$O$_3$ 막에 의한 수소/질소 혼합기체 분리)

  • Kang Tae-Bum;Park Jin-Ho
    • Membrane Journal
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    • v.14 no.4
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    • pp.312-319
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    • 2004
  • The porous SiO$_2$-B$_2$O$_3$ membrane was prepared from Si(OC$_2$$H_5$)$_4$-($CH_3$O)$_3$B-C$_2$$H_5$OH-$H_2O$ system by sol-gel method. In order to investigate the characteristics of this membrane, we examined that using BET, IR spectrophotometer, X-ray diffractometer, SEM and TEM. At $700^{\circ}C$, the surface area of SiO$_2$-B$_2$O$_3$ membrane was 354.398 $m^2$/, the median pore diameter was 0.0048 ${\mu}{\textrm}{m}$, and the particle size of SiO$_2$-B$_2$O$_3$ membrane was 7 nm. The separation properties of the gas mixture ($H_2$/$N_2$) through the SiO$_2$-B$_2$O$_3$ membrane was studied as a function of pressure. The real separation factor($\alpha$) of SiO$_2$-B$_2$O$_3$ membrane for $H_2$/$N_2$ gas mixture was 4.68 at 155.15 cmHg and $25^{\circ}C$. The real separation factor($\alpha$), head separation factor($\beta$) and tail separation factor((equation omitted)) were increased as the pressure of permeation cell increased.

THE NITROUS OXIDE CONCENTRATION IN BREATHING ZONE ACCORDING TO SCAVENGING METHODS DURING DEEP SEDATION OF PEDIATRIC DENTAL PATIENTS (소아치과 환자의 깊은 진정시 호기가스 제거 방법에 따른 호흡대역에서 Nitrous Oxide 농도 변화)

  • Lee, Chung-Won;Yoon, Hyung-Bae
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.1
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    • pp.124-131
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    • 2003
  • The concentration of nitrous oxide in dental environment has increased especially in pediatric department. In pediatric department frequently met the behavior disordered patients who need the deep sedation. As the deeply sedated patients could not respond well to verbal command, the amount of mouth breathing would be increased especially with mouth prop which backward transposition of mandible. Inhalation of low concentration of nitrous oxide for a long duration has caused various side effects such as spontaneous abortion and inhibition of methionine synthetase activity which is harmful to DNA synthesis. For evaluation of factors of mouth breathing during deep sedation. The author measured the concentration of nitrous oxide in breathing zone by the change of the scavenging methods. One is drain the gas through the tail part of reservoir bag of Jackson Ree's system naturally. Another is scavenge from tail portion of reservoir bag with negative pressure. Last one is scavenge from nasal mask with negative pressure. The nitrous oxide concentration in breathing zone was the lowest in nasal part drainage but high above the recommended concentration of NIOSH. The order of nitrous concentration in breathing zone was: natural drainage, tail part with negative pressure, nasal part with negative pressure. This would reflect the order of resistance of nasal airway and showed the amount of mouth breathing. From the above experiment, the resistance of nasal airway by the increment of gas flow in corrugating tube and reservoir bag would be one of the causative factors of mouth breathing in deeply sedated patients.

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Catalytic Technologies for Nitric Acid Plants N2O Emissions Control: In-Duct-Dependent Technological Options (질산제조 플랜트 N2O 제거용 촉매기술: 적용위치별 기술옵션)

  • Kim, Moon-Hyeon
    • Journal of Environmental Science International
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    • v.21 no.1
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    • pp.113-123
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    • 2012
  • A unit emission reduction of nitrous oxide ($N_2O$) from anthropogenic sources is equivalent to a 310-unit $CO_2$ emission reduction because the $N_2O$ has the global warming potential (GWP) of 310. This greatly promoted very active development and commercialization of catalysts to control $N_2O$ emissions from large-scale stationary sources, representatively nitric acid production plants, and numerous catalytic systems have been proposed for the $N_2O$ reduction to date and here designated to Options A to C with respect to in-duct-application scenarios. Whether or not these Options are suitable for $N_2O$ emissions control in nitric acid industries is primarily determined by positions of them being operated in nitric acid plants, which is mainly due to the difference in gas temperatures, compositions and pressures. The Option A being installed in the $NH_3$ oxidation reactor requires catalysts that have very strong thermal stability and high selectivity, while the Option B technologies are operated between the $NO_2$ absorption column and the gas expander and catalysts with medium thermal stability, good water tolerance and strong hydrothermal stability are applicable for this option. Catalysts for the Option C, that is positioned after the gas expander thereby having the lowest gas temperatures and pressure, should possess high de$N_2O$ performance and excellent water tolerance under such conditions. Consequently, each de$N_2O$ technology has different opportunities in nitric acid production plants and the best solution needs to be chosen considering the process requirements.

Preparation of Microporous Silica Membrane from TEOS-$H_2O$ System and Separation Of $H_2$-$N_2$ Gas Mixture (TEOS-$H_2O$계로부터 다공성 실리카 막의 제조 및 수소-질소 혼합기체의 분리)

  • 강태범;이현경;이용택
    • Membrane Journal
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    • v.10 no.2
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    • pp.55-65
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    • 2000
  • The porous silica membrane was prepared from Si(${OC}_2H_5)_4-H_2O$ system by sol-gel method. To investigate the characteristics of gels and porous silica membrane, we examined gels and porous silica membrane using TG-DTA, X-ray diffractometer, IR spectrophotometer, BET, SEM and TEM. The optimum mole ratio of Si(OC$_2$H$_{5}$)$_4$ : $H_2O$ $C_2$H$_{5}$OH for porous silica membrane was 1 : 4.5 : 4. The porous silica membrane was obtained by heat treatment of the gel above 700 $^{\circ}C$. The specific surface area of sintered gel was 3.8 $m^2$/g to 902.3 $m^2$/g at 100 $^{\circ}C$ to 1100 $^{\circ}C$ The pore size of sintered gel was in the range 20 $\AA$~ 50$\AA$. The particle size of sintered gel was 15 nm to 30 nm at 30$0^{\circ}C$ to 700$^{\circ}C$. The performance of the porous silica membrane was investigated for the separation of $H_2$/$N_2$ gas mixture. Gas separation through porous silica membrane depends upon Knudsen flow and surface flow. The veal separation factor($\alpha$) of $H_2$/$N_2$ was 5.17 at 155.15 cmHg and $25^{\circ}C$. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor( $\bar{B}$) increased as the pressure of permeation cell Increased.sed.

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Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP-Silica-PEI Composite Membranes (PTMSP-Silica-PEI 복합막에 의한 수소-질소 혼합기체 분리)

  • Lee Hyun-Kyung;Choi Youn-Jung
    • Membrane Journal
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    • v.14 no.4
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    • pp.304-311
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    • 2004
  • The poly(1-trimethylsilyl-1-propyne) (PTMSP) and silica-filled PTMSP membranes were prepared by casting from a toluene solution on porous polyetherimide (PEI). FT-IR spectrum, GPC and SEM pictures have been taken to characterize the membranes. The particle size of membrane decreases as silica content of the membrane increases from 23 to 60 wt%, and a uniform distribution of the silica is observed. The separation properties of the gas mixture (32 mol% $H_2$/ 68 mol% $N_2$) through the composite membranes were studies as a function of pressure and percentage of silica. Selectivity values of $H_2$/$N_2$ increased as the pressure of permeation cell and silica content of the membrane increased. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor((equation omitted)) of PTMSP-PEI composite membrane were 2.28, 1.58, and 1.44 respectively at $\Delta$P 30 psi and $25^{\circ}C$. $\alpha$, $\beta$, and (equation omitted) of PTMSP-Silica-PEI composite membrane for 60 wt% silica were 3.34, 1.95, 1.72 at $\Delta$P 30 psi and $25^{\circ}C$.

Study on the Effect of Phenol Compound-Cold Therapy plus Exercise Therapy on the Muscle Pain Induced by Carrageenan (페놀 화합물 냉치료와 운동요법의 병행적용이 Carrageenan에 의하여 유발된 근육 통증에 미치는 영향에 관한 연구)

  • Kim, Myoung-Seoup
    • PNF and Movement
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    • v.7 no.3
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    • pp.29-38
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    • 2009
  • Purpose : The aim of this study is to examine the effect of the phenol compound-cold therapy plus exercise therapy on the carrageenan(CAR)-induced muscle pain. Method : Mice were injected 0.1ml of 2% CAR into the gastrocmemius(GAS) muscle for the induction of muscle pain. After 4 hours from the injection of CAR, the cold therapy with 1% syringic acid was done to GAS muscle. After 2 hours from cold therapy, the exercise therapy such as muscle stretching, climing- and declining-movements was performed three times interval of 10 minutes in each experimental group. After 4, 10 and 24 hours from CAR-induced muscle pain, the measurements of muscle diameter, paw withdrawal latency(PWL) and, tail flick latency(TFL) were carried out. Results : In this study, the thickness of GAS muscle in CAR-induced muscle pain significantly increased compared with control. While, the thickness of GAS muscle adopted cold syringic acid-therapy with exercise-therapy group was significantly decreased than that of CAR-induced muscle pain. In the measurements of PWL and TFL, cold syringic acid-therapy with exercise-therapy group was remarkably increased than CAR-induced muscle pain group in PWL and TFL. All measurements were showed significantly different between the treated-group and the treated-time. Conclusions : From these results, it is suggested that the cold syringic acid-therapy with exercise-therapy such as muscle stretching, climing- and declining-movement was effective in the prevention of CAR-induced muscle pain by the decrease of muscle thickness and the increase of PWL and TFL.

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