• Bulletin of the Korean Chemical Society
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• 제19권11호
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• pp.1175-1179
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• 1998

The aerobic reaction of 2-(acetylpyridine)-S-methyldithiocarbazate (acpy-mdtcH) and 2-(acetylpyridine)-N-phenylthiosemicarbazate(acpy-phTscH) with manganese(Ⅱ) acetate affords Mn(acpy-mdtc)2 and Mn(acpyphTsc)2, respectively. The spectroscopic data and X-ray structure of Mn(acpy-mdtc)2 are reported. Crystal data for Mn(acpy-mdtc)2; C18H20N6S4Mn, mol wt 503.58, monoclinic crystal system(P21/c) a=12.240(5) Å, b= 10.918(l) Å, c=17.651(3) Å, β=105.93(2), and V=2268(l) Å3, Z=4, 5071 data collected with 0°< 2θ < 52.64°, 2995 data with I > 3σ(I), R= 0.046, Rw= 0.065. The ligands act as tridentate NNS donors. The two Mn-S distances are not equal, and respectively 2.512(2) Å and 2.541(2) Å. The average Mn-N (azomethine) length, 2.242(5) Å, is slightly shorter than the average Mn-N (pyridyl) length, 2.262(5) Å. The coordination environment about MN(Ⅱ) center deviates considerably from octahedral geometry. The manganese(Ⅱ)-manganese(Ⅰ) and manganese(Ⅰ)-manganese(0) reduction potentials of Mn(acpy-mdtc)2 are ∼-l.71 and ∼-l.98 V while those of Mn(acpy-phTsc)2 are ∼-l.87 and ∼-2.11 V vs. Ag/Ag+ in dimethyl sulfoxide, respectively.

• Earthquakes and Structures
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• 제25권4호
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• pp.235-247
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• 2023

Bingöl, a city in eastern Türkiye, is located at a very close distance to the Karlıova Region which is a junction point of the North Anatolian Fault Zone and Eastern Anatolian Fault Zone. By bilateral step over of North Anatolian Fault Zone and Eastern Anatolian Fault Zone each other there occurred NorthWest-SouthEast extended right-lateral and NorthEast-SouthWest extended left-lateral fault zones. In this paper, a typical school building located in Bingöl Çeltiksuyu was selected as the case study. Information on the school building and Bingöl Earthquake (2003) have been given in the paper. This study aimed to determine the fragility curves of the school building according to HAZUS 2022, Turkish Seismic Codes 1998, 2007 and 2018. These codes have been introduced in terms of damage limits. Incremental dynamic analysis is a parametric analysis method that has recently emerged in several different forms to estimate more thoroughly structural performance under seismic loads. Fragility analysis is commonly using to estimate the damage probability of buildings. Incremental Dynamic Analysis have performed, and 1295 Incremental Dynamic Analysis output was evaluated to obtain fragility curves. 20 different ground motion records have been selected with magnitudes between 5.6M and 7.6M. Scaling factors of these ground motions were selected between 0.1g and 2g. Comparison has been made between HAZUS 2022 and Turkish Seismic Codes 1998, 2007 and 2018 in terms of damage states and how they affected fragility curves. TSC 1998 has more conservative strictions along with TSC 2018 than TSC2007 and HAZUS moderate and extensive damage limits.

• 한국ITS학회 논문지
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• 제10권4호
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• pp.11-23
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• 2011

이 연구는 시계열 과거 속도자료를 활용하여 유사한 패턴 변화를 보이는 요일을 그룹핑하는 알고리즘을 개발하였다. 알고리즘에 적용할 이력자료 시간적 범위는 과거 2개월치 자료를 사용하였으며, 공간적 범위는 도시부도로를 대상으로 하였다. 이 연구에서 제안한 알고리즘은 크게 거시적인 관점과 미시적인 관점으로 나누어 요일별 패턴분류를 수행하였다. 먼저 거시적인 관점에서 요일별 첨두/비첨두 시간대와 요일별 속도변화가 크게 나타나는 중점시간대를 도출하였다. 미시적인 관점에서는 거시적인 관점에서 도출된 중점시간대를 대상으로 요일간 속도 차이를 개별(요일별) 혹은 그룹간의 유사성을 비교하여 단계적으로 분류하는 2단계 속도 군집 알고리즘(Two-step speed clustering algorithm, TSC)을 개발하였다. TSC 알고리즘은 중점시간대의 매 가공주기(또는 제공주기)마다 요일별(월~일) 속도차이를 토대로 그룹핑하는 1단계와 1단계에서 도출된 각 그룹의 평균과 요일간의 속도차이를 비교하여 재할당하는 2단계로 구성된다. TSC 알고리즘은 실제 지점검지기에서 수집된 시간대별 시계열 자료를 토대로 개발 및 성능평가가 수행되었다. 따라서, 교통정보센터에서 수집 가공 저장되는 과거이력자료를 이용하여 요일별 패턴분류 수행이 가능하고 알고리즘 구현도 실제 가공체계에 적용하기 용이하다. 이 연구에서 제안한 알고리즘은 통행패턴기반 정보가공 알고리즘 개발, 요일별 반복정체구간 운영관리, TOD에 근거한 신호운영 개선 등 교통운영 및 관리 전반에 적용이 가능하다.

• 전기의세계
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• 제28권8호
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• pp.8-12
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• 1979

이글은 다음과 같이 구성되어 있다. 1. 머릿말 2. 열자극전류의 기본원리 3. TSC 측정방법 4. 쌍극자분극 5. 포획, 공간전하 6. 이온 공간전하분극 7. 결론

• 전기의세계
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• 제30권11호
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• pp.671-680
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• 1981

영구쌍극자를 함유한 판상시료 양면에 전극을 접촉한 계의 TSC에 관해서 쌍극자의 완화시간이 단일인 경우와 분포된 경우로 구분하여 설명하기로 한다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1981년도 하계 학술회의초록집
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• pp.103-104
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• 1981

• 대한전기학회:학술대회논문집
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• 대한전기학회 1981년도 하계 학술회의초록집
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• pp.112-114
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• 1981

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1156-1158
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• 1995

Charge decay, thermally stimulated current(TSC), charging and discharging currents(I) are measured for negatively corona-charged polymers. In this study, we will make an experiment in charge decay on polymer surface, TSC, polarity effect and the others in order to analysis it's mechanism. Especially polyvinylidene fluoride(PVDF) film is the best functional material which has been so far. Therefore, It's worthy of notice to investigate it's characteristic. And then some other functional polymers will be focused on. An experimental result was missed out for the shortage of setting. So, this thesis will be explained on the theory and direction of reseach hereafter.

• 대한전기학회논문지
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• 제40권8호
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• pp.808-815
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• 1991

The behavior of space charge in PE/ionomer blends has been investigated using the thermally stimulated current (TSC) technique. In the blends, at least two TSC peaks over the temperature range from -50 to 100\ulcorner are observed, one at -5 ~ 10\ulcorner (a peak) and the others at above 60\ulcorner (a peak). The a peak is assigned as the orientation of dipoles from the ionomer component. Two a peaks seem to be related to the charge trapping at sites related to the crystalline phases. One a peak is associated with the ionic interfaces and the other with the ethylene chains without the ionic interfaces. The amount of charges stored in PE/Surlyn 1652 blends increases as the poling field increases over the field range of +8 ~ +30 kV/mm, whereas that in PE/Surlyn 1601 blends increases slightly at low poling fields and then decreases at high poling fields above +10 kV/mm. Exact reasons for such a dirrerence are not known at this point.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.163-166
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• 1995

It was investigated the properties of TSC (Thermally Stimulated Current) to understand carriers behavior from long ago. Activation Energy of their properties is very important to verify electrical characteristics. So, for many years, many researchers were worked to get the activation energy, more compeletely. But, if boundary conditions were not satisfied, the values of activation energy contained several errors. In this work, to obtain the activation energy related to charged particles, the peak temperature Tp and the slope of tangential line on any coordinates of Arrhenius plot are applied. The calculation process can be denied with by computer, and the result of observation shows that the cures of calculation data and simulation data coincide very compeletely.