• Title/Summary/Keyword: TS imbalance

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Kinetics and Mechanism of the Addition of Anilines to β-Nitrostilbenes in Acetonitrile

  • Sung, Dae-Dong;Kang, Sang-Soo;Lee, Jong-Pal;Jung, Dae-Il;Ryu, Zoon-Ha;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1670-1674
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    • 2007
  • Addition reactions of anilines (XC6H4NH2) to β-nitrostilbene (YC6H4CH=C(NO2)C6H4Y') have been investigated in acetonitrile at 30.0 oC. The magnitude of βX values (=0.11-0.34) indicates relatively earlier transition state for additions with anilines than with benzylamines. The signs of ρY and ρY' are positive with Δρ = ρY?ρY' = 0.04, demonstrating a TS imbalance with a negative charge development on the Cβ in the TS. The signs of cross-interaction constants ρXY (<0), ρXY' (<0) and ρYY' (>0) are consistent with bond forming and breaking processes. The relatively weak normal kinetic isotope effects involving deutarated nucleophiles, kH/kD>1, suggest an early, hydrogen-bonded, 4-member cyclic TS.

Direct acceleration feedback control of a washing machine during spinning process (드럼 세탁기 탈수시 가속도 피드백 제어)

  • Lee, Chin-Won;Seichiro, Suzuki;Sun, Hee-Bok
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1642-1647
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    • 2003
  • The market of the horizontal axis washing machine (drum washing machine) has been growing drastically in Korea by about 80% annually since 2000. As market grows fast, the customerTs demands concerning quality becomes more strict and various. Imbalance sensing is a key technology to reduce the NVH problem in a washing machine, because the laundry is time-variant and uncontrollable source of imbalance, which can cause more than 200kgf exciting force. In this paper, imbalance-sensing methods are briefly reviewed, new acceleration sensing circuits are examined, and finally the control algorithm of spinning process is proposed and validated.

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3D Dual-Fusion Attention Network for Brain Tumor Segmentation (뇌종양 분할을 위한 3D 이중 융합 주의 네트워크)

  • Hoang-Son Vo-Thanh;Tram-Tran Nguyen Quynh;Nhu-Tai Do;Soo-Hyung Kim
    • Proceedings of the Korea Information Processing Society Conference
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    • 2023.05a
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    • pp.496-498
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    • 2023
  • Brain tumor segmentation problem has challenges in the tumor diversity of location, imbalance, and morphology. Attention mechanisms have recently been used widely to tackle medical segmentation problems efficiently by focusing on essential regions. In contrast, the fusion approaches enhance performance by merging mutual benefits from many models. In this study, we proposed a 3D dual fusion attention network to combine the advantages of fusion approaches and attention mechanisms by residual self-attention and local blocks. Compared to fusion approaches and related works, our proposed method has shown promising results on the BraTS 2018 dataset.

Experimental Evaluation of Levitation and Imbalance Compensation for the Magnetic Bearing System Using Discrete Time Q-Parameterization Control (이산시간 Q 매개변수화 제어를 이용한 자기축수 시스템에 대한 부상과 불평형보정의 실험적 평가)

  • ;Fumio Matsumura
    • Journal of KSNVE
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    • v.8 no.5
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    • pp.964-973
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    • 1998
  • In this paper we propose a levitation and imbalance compensation controller design methodology of magnetic bearing system. In order to achieve levitation and elimination of unbalance vibartion in some operation speed we use the discrete-time Q-parameterization control. When rotor speed p = 0 there are no rotor unbalance, with frequency equals to the rotational speed. So in order to make levitatiom we choose the Q-parameterization controller free parameter Q such that the controller has poles on the unit circle at z = 1. However, when rotor speed p $\neq$ 0 there exist sinusoidal disturbance forces, with frequency equals to the rotational speed. So in order to achieve asymptotic rejection of these disturbance forces, the Q-parameterization controller free parameter Q is chosen such that the controller has poles on the unit circle at z = $exp^{ipTs}$ for a certain speed of rotation p ( $T_s$ is the sampling period). First, we introduce the experimental setup employed in this research. Second, we give a mathematical model for the magnetic bearing in difference equation form. Third, we explain the proposed discrete-time Q-parameterization controller design methodology. The controller free parameter Q is assumed to be a proper stable transfer function. Fourth, we show that the controller free parameter which satisfies the design objectives can be obtained by simply solving a set of linear equations rather than solving a complicated optimization problem. Finally, several simulation and experimental results are obtained to evaluate the proposed controller. The results obtained show the effectiveness of the proposed controller in eliminating the unbalance vibrations at the design speed of rotation.

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The Role of Universities in Research and Development and Technical Services (R & D & TS) in Korea

  • Kim, Sheung-Kown
    • IE interfaces
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    • v.2 no.1
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    • pp.79-96
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    • 1989
  • Abundant hard-working and well-educated human resources were the important sources of the spectacular economic success during the last decades. In contrast to the past sources of economic growth during the 1970's when labor and capital along with economies of scale were the dominant factors (the university has played an important role in the national economic success by supplying quality labour and intellectual talent.), the level of science, technological innovation and capital inputs will be of vital importance for future economic growth in Korea. The balance of payments in technology transfer together with the current state of R & D activities has been reviewed and some of the issues and problems underlying the university system that tend to hinder research in collaboration with research institutes and industries have been outlined. Serious imbalance in the allocation of research funds among research sectors was identified as the most serious problem to be fixed. The importance of science and technology education in private universities for the enhancement of the national level of science and technology has been re-examined. Also research and development in engineering and technical services has been emphasized. In conclusion, ways to bolster the role of universities in the research environment in cooperation with industry and research institutes have been suggested.

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A Comparative Study on the Theory of Lee jaema and Chang ts' ungcheng (이제마(李濟馬)와 장종정(張從正)의 학술사상(學術思想)에 대한 비교(比較) 연구(硏究))

  • Ch’ oi, yeikwen;Kim, kyungyo
    • Journal of Sasang Constitutional Medicine
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    • v.8 no.2
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    • pp.41-68
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    • 1996
  • This thesis is a try for examining the historical characteristics of Constiutional medicine. For this purpose, I have examined their theory, and made a comparison carefully. Through this study, I have obtained several results as following. Both Chang and Lee lived in the time of change, which was unstable and uncertain. Under the condition, they both rejected following the existing trends of learned circles, and developed new thoughts and clinical techniques. They rejected superstitious beliefs and fatalism, and conducted the pursuit of experimental knowledge and rationale idea. Clinical experience was the very base of their study. They both criticized the bad habits of abuse of tonifing medication and health seeking. Especially Lee regarded control of emotion and regulation of a way of life as the best way for preservation of one's health. Chang regarded pathogenic factors as the ultimate factor of diseases, and strived for eliminating pathogenic factors, but L brought to a conclusion that the final factor of diseases was what is called "heart" itself, and emotional changes were the most essential causes of disease. It can be said that the pathogenesis insisted by Chang can be called The insistence that pathologic factors are the very etiology of all the disease (邪氣致病論), or all the diseases result from pathologic factors. And his whole remedy can be summarized as following, A study on the method of eliminating pathogenic factors. But the purpose of Constitutional medicine is to correct imbalance intrinsic to one's internal organs. In this aspect, Constitutional medicine is a "regulatory medicine". Depending on the classification of six vital substances, Chang classified all disease into six categories. These were based on symptoms and sings represented. While classification of diseases made by Lee was likely to rely upon constitutional characteristics. Chang thought that the three remedies made up of perspiration, purgation, vomiting were the most efficient way of eliminating pathogenic factors. Lee, however, thought those weren't methods of eliminating pathogenic factors but the best ways restoring one's self-regulation power. Chang thought that all the febrile disease essentially has a tendency in properties to belong to "heat", but Lee pointed out that pathologic processes are variable in accordance with constitutional features. They both regarded pathogenesis of diabetes as fire. That is to say, fire is the most essential factor of diabetes. And there are many risk factors such as inappropriate foods, drugs, climate, etc., but Lee thought what is most important is heart. Putting all accounts together, medical characteristics of Chang are similar to those of T aiyinjen and Shaoyangjen, and have no relation to those of those of Shaoyinjen. Therefore we can conclude that Chang understood pathologic processes of disease of T aiyinjen and Shaoyangjen, whether he knew about constitutional features or not.

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