• 제목/요약/키워드: TPP

검색결과 192건 처리시간 0.035초

Lithographic Microfabrication for Nano/Micro-Objects by using Two-Photon Polymerization Technique

  • Lee, Kwang-Sup;Kang, Seung-Wan;Kim, Ran-Hee;Kim, Ju-Yeon;Kim, Won-Jin;Park, Sang-Hu;Lim, Tae-Woo;Yang, Dong-Yol;Sun, Hong-Bo;Kawata, Satoshi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.15-16
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    • 2006
  • Since two-photon polymerization (TPP) emerged as a new technology over a decade ago, a large variety of micro-objects including 3-D micro-optical components, micromechanical devices, and 3-D photonic crystals have been fabricated using TPP with a high spatial resolution of approximately submicron scale to 100 nm. Recent efforts have been made to improve the fabrication efficiency and precision of micro-objects obtained with TPP; in particular, many studies have been carried out with the aim of developing efficient two-photon absorbing chromophores. In this presentation, we will discuss our efforts to develop highly efficient two-photon absorbing materials and also describe recent attempts to enhance the resolution and to improve the fabrication efficiency of nanofabrications based on TPP.

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Use of Chitosan-TPP microsphere as a matrix for the encapsulation of somatic embryos of Capsicum annum var. grossum

  • Senarath, Wtpsk;Stevens, W.F.;Lee, Kui-Jae;Rehman, S.;Lee, Wang-Hyu
    • 한국자원식물학회:학술대회논문집
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    • 한국자원식물학회 2002년도 제9차 국제심포지움 및 추계정기학술발표회
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    • pp.52-52
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    • 2002
  • Chitosan is a key compound of shrimp waste. It is a biopolymer, which is widely used in the field of medical Sciences. Chitosan-TPP (Tripolyphosphate) complex has more or less similar physical properties as Ca-alginate which can be used for the production of synthetic seeds. Possibility of the use of Chitosan-TPP complex as a matrix for encapsulation of somatic embryos was tested against the Ca-alginate complex (2.5w/v Na-alginate, 100mM CaCl2 at pH 5.5). Somatic embryos grown in the induction medium (IM) were drawn into the viscous chitosan solution (1%) and mixed well by inverting the tube carefully. Then the mixture was dropped at regular intervals into the tripolyphosphate (TPP) solution kept on a magnetic stirrer for bead formation. Synthetic seeds formed were washed and transferred into the incubation medium, then allowed either to air-dry or freeze-dry.(중략)

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재활용 메타 아라미드와 TPP 복합용액의 제조 및 면섬유 코팅 후 특성분석 (Characteristics of Recycled m-Aramid and TPP Complex Solutions in Preparation and Cotton Fibers after Coating)

  • 김삼수;이지민;조호현;류규열
    • 한국염색가공학회지
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    • 제25권4호
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    • pp.292-302
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    • 2013
  • Cotton fabrics treated with hybrid materials were developed and prepared. A halogen-free flame retardant and an aromatic amide were blended and applied to cotton fabrics. Thermal and physical properties of the treated cotton fabrics were investigated. The surface of the pure and coated cotton fabrics was characterized by Fourier transform infrared spectroscopy. The elemental composition of the coated surface of the cotton fabric was measured using X-ray photoelectron spectroscopy and compared with that of pure cotton fabric. After being solved in N,N-dimethylacetamide, m-aramid and triphenylphosphine oxide (TPP) were applied to cotton fabrics through a dip-pad-coagulation process. The treated cotton fabrics with recycled m-aramid/TPP resulted in increased limited oxygen index values and thermal resistance.

Post-TPP Trade Policy Options for ASEAN and its Dialogue Partners: "Preference Ordering" Using CGE Analysis

  • Ji, Xianbai;Rana, Pradumna B.;Chia, Wai-Mun;Li, Changtai
    • East Asian Economic Review
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    • 제22권2호
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    • pp.177-215
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    • 2018
  • Trump's withdrawal from the Trans-Pacific Partnership (TPP) and his "America First" trade agenda ignite a second round of interest in mega-free trade agreements in the Asia-Pacific. Countries are evaluating alternative trade policy actions in a post-TPP era. Using national real GDP gains estimated by a modified GTAP model to construct "preference ordering" for 10 Association of Southeast Asian Nations members and their six regional dialogue partners, this paper comes up with several policy-oriented findings. First, when multilateral agreements are not possible, countries are better off with a regional trading agreement than without one. Second, the Regional Comprehensive Economic Partnership is likely to have higher beneficial impacts than the Comprehensive and Progressive Agreement for Trans-Pacific Partnership. Third, for dual-track countries, implementing both agreements is better than each separately. Fourth, impacts of open regionalism are likely to be higher than those of a closed and reciprocal one. Going forward, this paper argues that countries should adopt a "multi-track, multi-stage" approach to trade policy.

"This Unfavorable Poll Result for My Candidate Doesn't Affect Me but Others": Third-Person Perception in Election Poll Coverage

  • Shin-Il Moon;Yunjin Choi;Sungeun Chung
    • Asian Journal for Public Opinion Research
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    • 제11권4호
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    • pp.274-303
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    • 2023
  • The third-person perception phenomenon can consistently be found in opinion poll news, but it remains unknown what determines the degree of the third-person perception (TPP) about specific election poll news. We investigated how respondents' preferred candidate's status in the poll affects the perceived impact of polling news on both themselves (PMI1) and on others (PMI3) as well as TPP (PMI3 - PMI1). We also examined the effect of subjective political knowledge and the perceived level of political knowledge of others on TPP. An online experiment was conducted in the context of a gubernatorial election in South Korea, in which the leading candidate in the poll and the question order (self-question first vs. other-question first) were manipulated. The results indicated that PMI1 and PMI3 were greater when the respondent's preferred candidate was leading in the poll. TPP did not differ depending on subjective knowledge, but it was greater when the others were non-experts (vs. experts). Lastly, question order was found to be a method factor that affected both PMI1 and PMI3. The theoretical and practical implications of these findings are discussed.

Adsorption Behavior and Mechanism of Tripolyphosphate on Synthetic Goethite

  • Zhong, Yong;Sheng, Dandan;Xie, Fazhi;Li, Guolian;Li, Hui;Han, Xuan;Xie, Wenjie;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제56권2호
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    • pp.146-152
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    • 2019
  • In order to study the transport behavior of tripolyphosphate (TPP) in aqueous solutions, the adsorption process of TPP on synthetic goethite, which exists stably in supergene environment, has been systematically studied. The adsorption properties under different conditions (pH, electrolyte presence, and temperature) were investigated. The adsorption of TPP in the presence of humic acid (HA)/fulvic acid (FA) has also been discussed in this paper. The results indicated that the adsorption capacity quickly increased within the first hour and equilibrium was reached within 24 h. The adsorption capacity decreased from 1.98 to 0.27 mg·g-1 upon increasing the pH from 8.5 to 11.0, whereas the adsorption of TPP on goethite hardly changed with increasing electrolyte concentration. The results of analysis of the kinetic and isothermal models showed that the adsorption was more in accord with the pseudo second-order equation and Freundlich model. The adsorption capacity decreased obviously regardless of the order of addition of TPP, HA, and goethite. Subsequent addition of FA led to a large increase in the adsorption capacity, which might be attributed to the adsorption ability of FA. According to the predictions of the kinetic and isothermal models and the spectroscopic evidence (X-ray diffraction (XRD), Fourier Transform infrared spectroscopy (FT-IR), and scanning electron microscope (SEM)), the adsorption mechanism may be mainly based on surface complexation and physical adsorption.

Sol-Gel Encapsulation as Matrix for Potentiometric Nitrite-Selective Membranes Doped with Chloro (5, 10, 15, 20-Tetraphenylporphyrinato) Cobalt (III)

  • Zhou, Hao;Meyerhoff, Mark E.;Bi, Kai-Shun;Park, Sung-Bae
    • 전기화학회지
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    • 제12권4호
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    • pp.335-341
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    • 2009
  • Organic-inorganic hybrid sol-gel matrices were used as hosts for chloro (5, 10, 15, 20-tetraphenylporphyrinato) cobalt (III) (Co[TPP]Cl), a known ionophore for nitrite. The sol-gel precursor was prepared by the reaction of (3-isocyanopropyl) triethoxysilane with 1,4-butanediol. An appropriate amount of the anion-exchanger, tridodecylmethylammonium chloride (TDMAC) and the plasticizer, tributylphosphate (DBP) were used as membrane additives. On mixing with an acidic catalyst, the sol-state precursors slowly gelled, yielding a membrane in which the active components, Co[TPP]Cl and TDMAC, were encapsulated. The performances of the sol-gel membrane-based electrodes were compared to those of Co[TPP]Cl-based poly(vinyl chloride) (PVC) membrane electrodes. Membranes with a molar ratio of Co[TPP]Cl: TDMAC (1 : 0.1) showed reasonable response slopes toward nitrite. The response slopes were typically 53 mV/decade between $10^{-5.4}$ and $10^{-1.0}\;M$. Selectivities toward nitrite over hydrophilic and small anions such as chloride were somewhat inferior to those observed with PVC-based membranes, but selectivities over lipophilic anions were quite similar. Reduced asymmetry potentials due to protein adsorption were found to occur with the sol-gel matrix relative to PVC-based films when the sensors were employed as a detector in flow-through configuration.

가로림만 조력발전소 가동에 따른 조석체계 변화 예측 (Prediction of Tidal Regime According To Garolim Tidal Power Plant operation)

  • 강석구;이광수;박진순;염기대
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.639-643
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    • 2007
  • Tidal regime change with general hydrolic condition change is examined, according to Garolim Tidal Power Plant (TPP) operation. Numerical model has been developed for the Yellow and East China Seas region, in order to consider the tidal regime change by the TPP operation. The changes of tidal elevation and tidal current inside the Garolim bay are also investigated in details, along with examining the change of the tidal flat area with operation. The field measurement for the tide and current have been carried out for the validation of the numerical model and for understanding the state of current system in the present state.

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예산 제약을 고려한 다용량 복수 순회구매자 문제 (Heterogeneous Multiple Traveling Purchaser Problem with Budget Constraint)

  • 최명진;이상헌
    • 한국경영과학회지
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    • 제35권1호
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    • pp.111-124
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    • 2010
  • In the last decade, traveling purchaser problem (TPP) has received some attention of the researchers in the operational research area. TPP is a generalization of the well-known traveling salesman problem (TSP), which has many real-world applications such as purchasing the required raw materials for the manufacturing factories and the scheduling of a set of jobs over some machines, and many others. In this paper we suggest heterogeneous multiple traveling purchaser problem with budget constraint (HMTPP-B) which looks for several cycles starting at and ending to the depot and visiting a subset at a minimum traveling cost and such that the demand for each product is satisfied and the cost spent for purchasing the products does not exceed a given budget threshold. All the past studies of TPP are restricted on a single purchaser. Therefore we randomly generated some instances. CPLEX is used for getting optimal solutions in these experiments.

In(III)-, Tl(III)-porphyrin을 촉매제로 한 시클로알칸의 히드록시화 반응 (Hydroxylation of Cycloalkanes Catalyzed by In(III)-, Tl(III)-Porphyrin)

  • 나훈길
    • 한국응용과학기술학회지
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    • 제17권1호
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    • pp.15-21
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    • 2000
  • The catalytic hydroxylation of several cycloalkanes in dichloromethane have been investigated using In(Ⅲ)-, Tl(Ⅲ)-porphyrin complexes as a catalyst and NaClO, $NaClO_{2}$, $H_{2}O_{2}$ as a terminal oxidant. Porphyrins were TPP and ($F_{20}$)TPP (TPP = tetraphenylporphyrin) and substrates were cyclopentane, cyclohexane, cycloheptane and cyclooctane. The substrate conversion yield was discussed according to the substituent effect and hinderance effect of metalloporphyrin and the radius effect of non-redox metal ion. The conversion yield of cycloalkane followed the order of $ C_{5} $ < $ C_{6}$ < $ C_{7}$ = $ C_{8}$. In this experimental condition $NaClO_2$ was rather efficient terminal oxidant than NaClO and $H_{2}O_{2}$.