• 한국농공학회논문집
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• 제53권6호
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• pp.85-91
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• 2011

Three different types of wetlands (unplanted wetland, reed planted wetland, cattail planted wetland) were constructed at the mouth of Seokmoon reservoir with 910 $m^2$ each to examine the effects of wetland plant on pollutant removal rate in constructed wetland, and operated for 9 years (2002~2010). Water depth of the wetland was maintained at 0.3~0.5 m, flow rate was about 40~200 $m^3$/day, and retention time was managed at about 1~5 days. There was no difference in removal rate of SS, TN, and TP between reed wetland and cattail wetland. Removal rate of SS and TN in planted wetland with reed and cattail were higher than unplanted wetland, whereas removal rate of TP in unplanted wetland was higher then planted wetland. The monthly variation of removal rate in planted wetlands was high compared with unplanted wetland. From the long term monitoring results, SS and TN removal rates of period3 (2008~2010) were higher than period1 (2002~2004) in planted wetland, whereas TP removal rate was decreased as time goes on. Overall, pollutant removal rate in constructed wetland was more influenced by existence of plants than by plant species. Although constructed wetland is operated long term period, SS, TN, and TP removal rate (SS 90 %, TN 60 %, TP 40 %) can be maintained high values.

• 대한환경공학회지
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• 제33권4호
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• pp.231-236
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• 2011

본 연구는 알루미늄 응집에 의한 인 제거 공정에 마그네슘 및 칼슘과 같은 2가의 금속이온을 첨가하였을 경우 인의 응집특성에 미치는 영향을 조사하였다. 인을 제거하기 위한 최적 알루미늄 응집 pH는 약 5~6 사이이며, 그 이상 pH에서는 TP 제거효율이 감소하였다. 마그네슘이나 칼슘과 같은 2가의 금속이온을 알루미늄 응집공정에 함께 사용할 경우 pH 6 이상 에서도 TP 및 $H_nPO_4^{n-3}$ 제거효율은 안정적으로 95% 이상을 유지하였다. 응집초기 $Al^{3+}/H_nPO_4^{n-3}$ (Al/P) 몰비가 3 이상에서 TP 제거효율이 80% 이상 높게 유지되었으며, 응집 후 잔류 TP 농도를 0.2 mg/L 이하로 제어하기 위해서는 Al/P 몰비는 약 6 이상 이었다. 마그네슘이나 칼슘 이온을 알루미늄 응집공정에 함께 사용할 경우 TP 제거를 위한 최적의 알루미늄 대비 마그네슘 및 칼슘 이온의 몰비($Al^{3+}/Mg^{2+}$ or $Ca^{2+}$)는 모두 2이었다. 알루미늄 응집공정에 마그네슘이나 칼슘 이온을 함께 사용하면, 동일한 양의 TP를 제거하기 위한 알루미늄 응집제 주입량이 감소하였고, 결과적으로 최종 슬러지 발생량도 감소하였다.

• 상하수도학회지
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• 제24권4호
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• pp.407-412
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• 2010

The purpose of this study was to investigate removal efficiencies of contaminants in night soil treatment plant using the B3 system. The samples were collected from retaining tank and settlement tank in Yechon night soil plant. We experimented concentrations of BOD, COD, SS, TN and TP. Concentration data were processed using removal efficiencies by season and correlation analysis with pilot running parameters. Removal efficiencies of total organic carbon was over 96%, TN was 98% during summer, 80.9% during winter. In the case of TP, the highest removal efficiencies was 94.1% during fall and the lowest removal efficiencies was 82% during spring. Results of correlation analysis showed two positive correlation groups and one negative group. Positive correlations were among temperature, BOD and TN. The others were pH, BOD, COD, SS, TN and TP. Negative correlation were among MLSS, BOD, COD, SS, TN, TP.

• 대한환경공학회지
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• 제36권9호
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• pp.609-613
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• 2014

본 연구는 미세조류 생장에 중요한 영향인자인 N/P ratio가 미세조류의 생장과 하수의 영양염류 제거에 미치는 영향을 알아보고자 하였다. 실험을 위하여 1-70까지의 다양한 N/P ratio를 준비하였으며, 미세조류는 Botryococcus braunii를 사용하였다. 실험결과 바이오매스 생산을 위하여 필요한 N/P ratio는 5-30이었다. TN의 제거율은 N/P ratio 1-30까지는 82%, 31-70까지는 73-78%의 제거율을 나타내어 TN 제거를 위한 N/P ratio는 1-30까지가 가장 좋았다. TP의 제거율 N/P ratio 1-20까지는 80% 이상의 높은 제거율을 나타내었지만, 20 이상부터는 급격하게 하락하여 50 이상에서는 22% 정도의 제거율로 변화가 없이 일정하였다. 따라서 바이오매스 생산량과 하수에서의 TN, TP의 제거를 위한 N/P ratio는 1-30이 가장 좋은 비율로 나타났다. TN, TP 제거율과 바이오매스의 생산량 상관관계는 TP 제거율과 바이오매스 생산량의 상관계수가($R^2$) 0.9126으로 상관관계가 매우 높았으나, TN 제거율과 바이오매스 생산량과의 상관관계는 찾을 수가 없었다. 이는 하수에서 TP의 함량이 TN의 함량보다 바이오매스 생산량에 밀접한 관계가 있음을 알 수 있다.

• 한국환경복원기술학회지
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• 제9권5호
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• pp.22-31
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• 2006

AnnAGNPS model would be applied to simulate the pollutant removal capacity with the buffer strip in the Deachung reservoir watershed. In 2002, 2,270 tons of TN and 221 tons of TP were discharged from the nonpoint source pollutants in this watershed. During the rainy season, from June to September, 66.4% of TN and 71.9% of TP resulted from nonpoint source loads. AnnAGNPS model was also used to simulate the nutrients removal capacity from the buffer strip under the condition that the present landuse would be changed to forest. As the result of simulation, the removal rates of nutrients from the buffer strip of Daecheong reservoir watershed are 406 tons of TN, 39 tons of TP, which means reduction rates are TN 17.9%, TP 17.8%, respectively.

• 한국수자원학회논문집
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• 제47권12호
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• pp.1135-1143
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• 2014

본 연구에서는 사상성 조류로 구성된 수질정화시설의 수질정화효율을 평가하고자 충남 서산시 음암면에 소재한 성암저수지 유입하천 홍수부지에 test-bed를 설치하고 유입하천수를 대상으로 현장적용실험을 실시하였다. 수질항목별로 정화효율을 평가한 결과, SS 80.9%, COD 74.6%, T-N 76.8%, T-P 84.4%, DTN 93.8%, DTP 98.3%의 제거효율을 보였다. 수온에 따른 정화효율은 수온이 약 $20^{\circ}C$로 유지되어 수질정화효율에 미치는 영향은 없는 것으로 나타났다. 수리학적 체류시간(HRT)은 SS 및 TP 처리효율과 유의한 상관성이 있는 것으로 나타났고, 체류시간을 5일로 했을 때 SS, TP 처리효율이 좋은 것으로 나타났다. 유입수의 COD/TN에 따른 처리효율은 TN, TP 모두 C/N비가 낮을수록 증가하였고, 유입수의 COD/TP에 따른 처리효율도 C/P비가 낮을수록 TN, TP 모두 처리효율이 증가하는 것으로 나타났다.

• 자원리싸이클링
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• 제17권5호
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• pp.60-65
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• 2008

고순도 동 제조를 위해 황산동 전해액중에 존재하는 은(Ag)을 제거하기 위한 기초연구를 실시하였다. 이온교환수지법, 활성탄 흡착법, 구리분말 및 세선을 이용한 치환법, CuS침전법 등을 이용하여 Ag제거에 대한 실험을 실시하였으며, 은(Ag)제거 반응에 영향을 미칠 수 있는 반응온도, 반응시간, 첨가량 등에 대해 고찰하였다. 이들 방법중 CuS 침전법과 Lewatit TP214를 이용한 이온교환수지 방법이 효과적이었는데 특히 Lewatit TP214를 사용한 경우 초기 동전해액중, Ag 농도가 10ppm서 0.1ppm 이하 수준까지 제거가 가능하였다.

• 한국환경복원기술학회지
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• 제8권1호
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• pp.45-51
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• 2005

Total phosphorus(TP) removal was examined in a surface-flow wetland constructed in April 2003 during its initial operating stage from June to November 2003. Its dimensions were 87mL by 14mW. It was a part of a four-wetland-cell treatment system constructed near the Kohung Estuarine Lake located in the southern part of Korea. Effluent from a night soil treatment plant was discharged into the wetland and purified effluent from the wetland was discharged into Sinyang Stream flowing into the Lake. Cattails(Typha angustifolia ) from natural wetlands were cut at about 40 cm height and transplanted into the wetland. An average of 25.0$m^3$/day of effluent flowed from the plant into the wetland. Water depth was maintained about 0.2m and hydraulic detention time was about 5.2 days. Average heights of the cattail stems in June and October 2003 were 47.2 and 164.6cm, respectively. The average number of stems was 10.2 stems/$m^2$ in June 2003 and 18.8 stems/$m^2$ in October 2003. Average temperature of influent and effluent ranged 23.4 and $24.2^{\circ}C$, respectively. The average TP concentrations of influent and effluent were about 1.31, 0.50mg/L, respectively. TP loading rate of influent into the wetland averaged 26.81mg/$m^2$, day and average TP loading rate of effluent was 10.04mg/$m^2$, day. Monthly average TP removal by the wetland during the warm growing season of cattails(June to September) ranged 16.28~19.57mg/$m^2$, day and during the cold senescent period (October to November) ranged 12.62~13.90mg/$m^2$, day. TP removal in the wetland continued during the cold winter months and was primarily done by sedimentation and precipitation of phosphorus rather than phosphorus absorption by cattails and microorganisms.

• 한국환경과학회지
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• 제25권9호
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• pp.1233-1239
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• 2016

This study aimed to evaluate changes in the TN and TP removal efficiencies, depending on whether or not a settling process is applied, in a sequencing batch reactor (SBR) process with a membrane bioreactor (MBR). Nutrient removal was considered in terms of developing an advanced water treatment system for ships in accordance with water quality standards set forth by 227(64). For these purposes, the TN and TP concentrations in the inflow and outflow water were measured to calculate the TN and TP removal efficiencies, depending on whether or not a settling process was used. Water discharged from a bathroom, which was constructed for the experiment, was used as the raw water. The experiment that included a settling process was conducted twice, and the operating conditions were: aeration for 90 min, settling for 30 min, agitation for 15 min, and settling for 15 min for one experiment; and aeration for 150 min, settling for 45 min, agitation for 15 min, and settling for 15 min in the other. Operating conditions for the experiment that did not include a settling process were: aeration for 180 min and agitation for 60 min. The concentration of the mixed liquor suspended solids (MLSS) in the reactor was 3,500 mg/L, while the aeration rate was 121 L/min and the water production rate was 1.5 L/min. For the two experiments where a settling process was applied, the average TN removal efficiencies were 44.39% and 41.05%, and the average TP removal efficiencies were 47.85% and 46.04%. For the experiment in which a settling process was not applied, the average TN removal efficiency was 65.51%, and the average TP removal efficiency was 52.51%. Although the final nutrient levels did not satisfy the water quality standards of MEPC 227(64), the TN and TP removal efficiencies were higher when a settling process was not applied.

• 대한환경공학회지
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• 제35권5호
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• pp.381-387
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• 2013

UASB-ABF (Up-flow anaerobic sludge blanket-aerated bio-filter) 시스템을 이용한 하수의 혐기성처리 방법에서 질소와 인을 제거하는 공법에 대하여 연구하였다. 160일간의 UASB-ABF 시스템을 운영한 결과 유출수 반송을 통하여 TCOD뿐만 아니라, TN과 TP를 효율적으로 제거할 수 있었다. 무반송의 경우 UASB 반응조에서 유기물 제거효율은 64%에 머물었으나, 반송률 120%, 180%, 240%로 증가한 결과 각각 92%, 95%, 96%로 향상되었다. 반송률 180% 이상에서는 유기물 제거효율 증가폭은 크지 않았다. ABF 유출수 반송으로 TN 제거효율이 크게 향상되었다. TN 제거효율은 무반송 조건일 때 18%에서 82%로 향상되었으며, UASB에서 지속적인 유기물질 제거로 인하여 ABF에서 질산화효율은 안정적으로 95% 이상으로 타나났다. ABF 유출수 반송으로 TP 및 $PO{_4}^{3-}$-P 제거효율이 모두 향상되었다. TP의 경우 무반송에서는 거의 제거되지 않았으나, 반송률이 120%, 180%, 240%에서는 각각 51%, 63%, 71%로 향상되었고, 주로 UASB에서 제거되었다.