• Title/Summary/Keyword: TOF method

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Drift Velocities for Electrons in $SF_6$-Ar Mixtures Gas by MCS-Beq Algorithm (MCS-BEq에 의한 $SF_6-Ar$혼합기체(混合氣體)의 전자(電子) 이동속도(移動速度))

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.54 no.1
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    • pp.29-33
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    • 2005
  • Energy distribution function for electrons in $SF_6$-Ar mixtures gas by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300$[Td] by a two term Boltana equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other, authors, experimentally the electron swarm parameters for 0.2[%} and 0.5[%] $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method. The result show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The results obtained from Booltemann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

Analysis of electron transport properties of $CF_4+Ar$ mixtures gas by the TOF method (TOF법에 의한 $CF_4+Ar$ 혼합기체의 전자수송특성 해석)

  • 서상현;하성철;유회영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.279-283
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    • 1998
  • The electron swarm parameters in the$CF_4$(O.l%, 5%)+Ar mixtures are measured by time of flight method over the E/N(Td) range from 10 to 300LTdl. A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, NDL, NDT, $\alpha$ and the limiting breakdown electric field to gas mixtures ratio in pure $CF_4$ gas and$CF_4+Ar$ mixtures. The measured results and the calculated results have been compared each other paper.

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Establishment of a library of fragments for the rapid and reliable determination of anabolic steroids by liquid chromatography-quadrupole time of flight-mass spectrometry

  • Do, Jung-Ah;Noh, Eunyoung;Yoon, Soon-Byung;Choi, Hojune;Baek, Sun-Young;Park, Sung-Kwan;Lee, Sang-Gyeong
    • Analytical Science and Technology
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    • v.30 no.1
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    • pp.10-19
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    • 2017
  • Anabolic steroids have similar structures to testosterone, both of which promote the growth of muscle mass and increase strength. However, the side effects of anabolic steroid use may lead to heart attacks or strokes. Additionally, the excessive use of steroids inhibits the production of the sex hormones in the body via a negative feedback loop, which results in testicular atrophy in males and amenorrhea in females. Currently, the method of choice used to test for the presence of anabolic steroids is GC-MS. However, GC-MS methods require chemical derivatization of the steroid sample to ensure compatibility with the analytical method; therefore, analysis of many different samples is difficult and time consuming. Unlike GC-MS, the liquid chromatography-quadrupole-time of flight mass spectrometry (LC-Q-TOF-MS) method is suitable for many samples. Twenty-two different anabolic steroids were analyzed by LC-Q-TOF-MS with various collision energies (CE). Accurate mass spectral data were obtained using a Q-TOF-MS equipped with an electro-spray ionization source and operated in the positive MS/MS mode for several classes of steroids that are often the targets of testing. Based on the collected data, fragmentation pathways were carefully elucidated. The high selectivity and sensitivity of the LC-Q-TOF-MS instrument combined with these fragmentation pathways offers a new approach for the rapid and accurate screening of anabolic steroids. The obtained data from the 22 different anabolic steroids will be shared with the scientific community in order to establish a library to aid in the screening of illegal anabolic steroids.

Resonance Integral of Neptunium(237Np) from Energy Dependent Differential Neutron Capture Cross-Section by Using the Linac TOF Method and C6D6 Scintillation Spectrometer

  • Lee, Sam-Yol
    • Journal of the Korean Society of Radiology
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    • v.5 no.4
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    • pp.217-221
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    • 2011
  • $^{237}Np$ is very important material in the fission products of nuclear reactors. Resonance integral(RI) tests of this material is necessary to check between the experiments and the evaluated data. Such feedback to the evaluated data is very important to correct data and improve of codes. The RI for the $^{237}Np(n,{\gamma})^{238}Np$ reaction were measured by using the 46-MeV electron linear accelerator (linac) at the Research Reactor Institute, Kyoto University (KURRI). The measurement was performed in the energy region from 0.005 eV and 10 keV. RI obtained as 804.7 barns, compared with those of the evaluated data in JENDL-4.0 and Mughabghab.

A Simulation of the Mean energy of electrons in $SF_6$-Ar Mixtures Gas (시뮬레이션을 이용한 $SF_6$-Ar혼합기체의 전자 평균에너지)

  • Kim, Sang-Nam
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.578-580
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    • 2005
  • Energy distribution function for electrons in SF6-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range 30~300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by TOF method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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Study on the Chemical Polymerization of Pyrrole in the Presence of Cyclic Poly(oxyethylene)s (환형 폴리옥시에틸렌 존재하의 피롤의 화학적 중합에 관한 연구)

  • 차국찬;김진환;배진영
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.568-574
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    • 2002
  • Inclusion compounds using cyclic poly(oxyethylene)s as host molecules have been used to polymerize pyrrole chemically in aqueous medium. This general synthetic strategy makes it possible to grow rigid aromatic polymers in aqueous medium by chemical oxidation method. It is an easy method to obtain rigid polymers in a very mild manner. Some threaded and water-soluble polypyrroles are obtained, and their characterization is performed by NMR, IR, UV, and MALDI-TOF MS measurements.

MALDI-TOF Analysis of Polyhexamethylene Guanidine (PHMG) Oligomers Used as a Commercial Antibacterial Humidifier Disinfectant

  • Hwang, Hyo Jin;Nam, Jungjoo;Yang, Sung Ik;Kwon, Jung-Hwan;Oh, Han Bin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1708-1714
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    • 2013
  • Polyhexamethylene guanidine (PHMG) polymers used as an active ingredient in an antibacterial humidifier disinfectant were reported to cause harm to the human health when inhaled, although physical contact with this material was known to present low toxicity to humans. It is therefore necessary to develop an optimal analysis method which enables detection and analysis of PHMG polymers. MALDI-TOF investigations of PHMG are performed with a variety of matrices, and it is found that CHCA and 2,5-DHB are excellent matrices which well reflects the polymer population even at high mass. For the provided PHMG sample, the number-average ($M_n$) and weight-average ($M_w$) molecular masses were determined to be 744.8 and 810.7, respectively, when the CHCA was used as a matrix. The rank of the matrices in terms of averaged molecular weight was CHCA ~2,5-DHB > 5-NSA > DHAP, THAP > ATT > IAA ~ super-DHB ~ HABA. In addition, PSD of the PHMG oligomer ions exhibited a few unique fragmenation characteristics. The formation of a- and c-type fragments was the major fragmentation pathway, and the 25-Da loss peaks generally accompanied a- and c-type fragments.

Evaluation of LC/MS and LC/UVD(EPA-631) Methods in Determination of Benomyl Concentration in Water Samples (LC/MS법 및 LC/UVD(EPA-631)를 이용한 수계 중 Benomyl의 분석법 평가)

  • Kim, Kee D.;Choi, Won Gyu;Seo, Yong Chan;Park, Byung Hwang;Choi, Hye Kyung
    • Journal of the Korean Chemical Society
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    • v.45 no.1
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    • pp.40-44
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    • 2001
  • Benomyl, one of the known endocrine disrupting chemicals, was analyzed to understand the its fate in water. Benomyl analysis process in water sample include the following sequential steps. Hydrolysis of benomyl into carbendazim, solvent extraction, concentration, and the concentration of final carbendazim solution was determined by LC/MS (TOF). Recoveries of the spiked samples were good with the range of 80.6 to 118.6% and the MDL was 1,600 times lower than that of LC/UVD method. The use of LC/MS (TOF) successfully eliminated the positive error incurred by interferencing materials in the matrix.

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Magnetic Resonance Angiography using 3D Time-Of-Flight Method (Time of Flight 원리를 이용한 삼차원 자기공명 혈관조영술의 구현)

  • Yi, Y.;Ryu, T.H.;Kim, S.S.;Ahn, S.H.;Lee, M.W.;Jung, K.J.
    • Proceedings of the KOSOMBE Conference
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    • v.1998 no.11
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    • pp.96-97
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    • 1998
  • 3D TOF MR Angiography is able to obtain thinner slice thickness, higher SNR, therefore higher spatial resolution than 2D TOF MR Angiography. Since it uses longer TR than 2D TOF MRA to allow stronger in-flow effect, the background tissue may not be fully saturated. Thus background tissue signal can be further suppressed by MTS(Magnetization Transfer Saturation). Flow-compensation was accomplished by GMN(Gradient Moment Nulling), and tracking saturation was used to suppress vein signal. The different flow signal at the entry of the slab and output of the slab can be compensated by TONE(Tilted Optimized Non-saturating Excitation) RF pulse.

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