• Title/Summary/Keyword: THM 생성

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A Study on Characterization of THMs Formation in Tap Water in Daegu (대구수돗물의 THMs 생성특성)

  • Bae, Gi-Soo;Baek, Yoon-Kyung;Ryu, Ki-Sung;Shin, Sang-Hee;Lee, Chan-Hyung
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.12
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    • pp.893-899
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    • 2011
  • The occurrence of THMs, the characteristics of THMs formation and removal of THMs were investigated. The treatment train of M plant consists of prechlorination, flocculation, sedimentation, filtration, ozonation, activated carbon and postchlorination. The study of THM formation indicated that about 92% of the THMs were formed in the flocculation/sedimentation/filtration process which affected by prechlorination. The formation of THMs was highly correlated to $KMnO_4$ consumption and water temperature in raw water. The regression model had showed 0.72~0.80 of determination coefficient so it could be used to predict the amount of THMs formation in finished water. Compared to the prechlorination process, the THMs formation was reduced in interchlorination process. With the addition of PAC, fewer THMs were formed in PAC-chlorination process than in chlorination-PAC process. Our results showed that air stripping could be used to remove the existing THMs.

Modeling Residual Chlorine and THMs in Water Distribution System (배급수계통에서 잔류염소 및 THMs 분포 예측에 관한 연구)

  • Ahn, Jae-Chan;Lee, Su-Won;Rho, Bang-Sik;Choi, Young-Jun;Choi, Jae-Ho;Kim, Hyo-Il;Park, Tae-Jun;Park, Chang-Min;Park, Hyeon;Koo, Ja-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.706-714
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    • 2007
  • This study suggested a method for prediction of residual chlorine and THMs in water distribution system by measurement of residual chlorine, THMs, and other parameters, estimation of chlorine decay coefficients and THM formation coefficients, and simulation of water qualities using pipe network analysis. Bulk decay coefficients of parallel first-order were obtained by bottle tests, and pipe wall decay coefficients of first-order were estimated through evaluation of 5 models, which showed the lowest values of 0.03 for MAE(mean absolute error) and 0.037 MAE in comparison with the observed in field. And bottle tests were conducted to model first-order reaction of THM formation by nonlinear least square regression and the resultant coefficients were compared with the observed in field. As a result, the coefficients of determination$(R^2)$ for the observed and the predicted values were 0.98 in September and 0.82 in November, and the formation of THMs was predicted by modeling.

Factors Affecting the Formation of Iodo-Trihalomethanes during Chlorination in Drinking Water Treatment (정수처리에서 염소 처리시 요오드계 트리할로메탄류 생성에 영향을 미치는 인자들)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Kim, Kyung-A;Song, Mi-Jeong;Choi, Jin-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.542-548
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    • 2014
  • Effects of bromide ($Br^-$) and iodide ($I^-$) concentrations, chlorine ($Cl_2$) doses, pH, temperature, ammonia nitrogen concentrations, reaction times and water characteristics on formation of iodinated trihalomethanes (I-THMs) during oxidation of iodide containing water with chlorine were investigated in this study. Results showed that the yields of I-THMs increased with the high bromide and iodide level during chlorination. The elevated pH significantly increased the yields of I-THMs during chlorination. The formation of I-THMs was higher at $20^{\circ}C$ than $4^{\circ}C$, $10^{\circ}C$ and $30^{\circ}C$. In chloramination study, addition of ammonium chloride ($NH_4Cl$) markedly increased the formation of I-THMs. Among the water samples collected from seven water sources including wastewater treatment plant (WWTP) effluent water (EfOM water), prepared humic containing water (HA water) and algal organic matter (AOM) containing water (AOM water), EfOM water generated the highest yields of I-THMs ($12.31{\mu}g/mg$ DOC), followed by HA water ($4.96{\mu}g/mg$ DOC), while AOM water produced the lowest yields of I-THMs ($0.99{\mu}g/mg$ DOC). $SUVA_{254}$ values of EfOM water, HA water and AOM water were $1.38L/mg{\cdot}m$, $4.96L/mg{\cdot}m$ and $0.97L/mg{\cdot}m$, respectively. The I-THMs yields had a low correlation with $SUVA_{254}$ values ($r^2$ = 0.002).

Concentration distributions and formation characteristics of trihalomethanes in drinking water supplies to rural communities (농촌지역 마을상수 중 trihalomethanes의 농도 분포 및 생성 특성)

  • Kim, Hekap;Kim, Seyoung
    • Analytical Science and Technology
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    • v.28 no.1
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    • pp.58-64
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    • 2015
  • This study aimed to investigate the concentration distributions and formation characteristics of trihalomethanes (THMs) in drinking water supplies to rural communities. Water samples were collected twice from 40 rural households located on the outskirts of Chuncheon city of Gangwon Province in the summers of 2010 and 2011, and urban drinking water samples were collected from 20 faucets during the same period in 2011 for comparison purpose. Water temperature, pH, and residual chlorine (total and free) concentrations were measured in the field, and samples were analyzed for dissolved organic carbon (DOC) and THM concentrations in the laboratory. The average DOC concentrations in rural water samples were not greatly different between groundwater (n = 20) and surface water (n = 20) which were used as sources for drinking water (1.81 vs. 1.91 mg/L). However, the average concentrations of total THMs (TTHMs) in groundwater ($9.77{\mu}g/L$) were much higher than those in surface water ($2.85{\mu}g/L$) and similar to those in urban drinking water samples ($10.8{\mu}g/L$). Unlike urban water supply, rural water (particularly groundwater) contained more brominated THM species such as dibromochloromethane (DBCM), suggesting its relatively high content of bromide ion (Br-). This study showed that rural water supplies have different THM formation characteristics from urban water supplies, probably due to their differences in source water quality properties.

Quantitative Evaluation of Super-resolution Drone Images Generated Using Deep Learning (딥러닝을 이용하여 생성한 초해상화 드론 영상의 정량적 평가)

  • Seo, Hong-Deok;So, Hyeong-Yoon;Kim, Eui-Myoung
    • Journal of Cadastre & Land InformatiX
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    • v.53 no.2
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    • pp.5-18
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    • 2023
  • As the development of drones and sensors accelerates, new services and values are created by fusing data acquired from various sensors mounted on drone. However, the construction of spatial information through data fusion is mainly constructed depending on the image, and the quality of data is determined according to the specification and performance of the hardware. In addition, it is difficult to utilize it in the actual field because expensive equipment is required to construct spatial information of high-quality. In this study, super-resolution was performed by applying deep learning to low-resolution images acquired through RGB and THM cameras mounted on a drone, and quantitative evaluation and feature point extraction were performed on the generated high-resolution images. As a result of the experiment, the high-resolution image generated by super-resolution was maintained the characteristics of the original image, and as the resolution was improved, more features could be extracted compared to the original image. Therefore, when generating a high-resolution image by applying a low-resolution image to an super-resolution deep learning model, it is judged to be a new method to construct spatial information of high-quality without being restricted by hardware.

Water Treatment Method for Removal of Trihalomethanes, Pesticides, Heavy Metals and Detergent in Drinking Water (1). -Effective Removal Method of Trihalomethanes in Drinking Water- (상수중 Trihalomethanes, 농약, 중금속 및 합성세제의 효율적인 제거를 위한 수처리 방법 제 1보. -상수중 Trihalomethanes의 효율적인 제거방법-)

  • Park, Jong-Woo;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.37 no.6
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    • pp.472-479
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    • 1994
  • This study was conducted to determine the effective removal method of THMs and humic material in drinking water when the doses of oxidants, coagulants, and activated carbon, and the points of oxidants treatment were changed in the drinking water treatment process. The inhibition of THMs formation and the removal of humic matter were more effectively achieved by $ClO_2$ than by other oxidants, $Cl_2,\;NH_2Cl,\;KMnO_4\;and\;O_3$. By changing the point of oxidant treatment, the formation of THMs was reduced by about 36.7 to 8.2% on treatment after coagulation, but the content of humic matter was not affected. The coagulation efficiency of alum and ferric sulfate to coagulate organic materials in water was affected by the molecular weight of humic matter in drinking water. The treatment of activated carbon after filtration was found to be more effective than that before oxidation in inhibiting THMs formation and removing THMs.

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Characterization of Disinfection By-Products by Chlamydomonas pulsatilla (녹조류(Chlamydomonas pulsatilla)에 의한 염소소독부산물 생성과 그 특성)

  • Kum, Heejung;Kim, Junsung;Chung, Yong
    • Journal of Korean Society on Water Environment
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    • v.21 no.5
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    • pp.535-540
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    • 2005
  • This study was conducted to evaluate the chlorinated disinfection by-products formation potential (DBPFP) produced from the cell and extracellular product (ECP) of Chlamydomonas pulsatilla after chlorination. Reaction yields of DBPs produced by C. pulsatilla of ECP and the cell were $0.007{\mu}mol/mg{\cdot}C$ and $0.808{\mu}mol/mg{\cdot}C$ respectively, Also, SUVA values of ECP and the cell were measured as $0.313L/mg{\cdot}m$ and $1.052L/mg{\cdot}m$ respectively, The DOC of cell was found to be lower than that of ECP, while the SUVA value and reaction yields for the cell were higher than those of ECP. For ECP, most of the DBPFP was composed of trihalomethanes (THM; 47.3%) and haloacetonitriles (HAN; 38,83%). THM and HAN were the major DBPFP produced by the cell. Chloroform was found to be the major THM compound; 98.3% for ECP and 99.98% for the cell. Dichloroacetic acid (DCAA) and dichloroacetonitrile (DCAN) were identified as the major haloacetic acid (HAA) and HAN compounds formed by ECP and the cell as a precursor, respectively. As the chlorine dose was increased, concentrations of DOC, THMs, and HANs were increased. However, the chlorine dose decreased the concentration of chlorophyll-a.

A research on the generation of future rainfall scenarios using stochastic rainfall generation model (추계 강우 생성 모형을 통한 미래 강우 시나리오 생성 방법 연구)

  • Park, Jeong Ha;Park, Hyun Jin;Kim, Dong Kyun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.336-336
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    • 2019
  • 기후변화는 미래 수문 순환 및 수자원에 악영향을 미칠 수 있는 가장 잠재력이 큰 요인이다. 특히 강우량의 변동은 가뭄 홍수를 더욱 양극화 할 수 있으며, 지역별 수문 순환에 막대한 영향을 주기 때문에 수자원 관리 계획 수립 시 기후변화 요소를 필히 고려해야 한다. 추계 강우 생성 모형은 상대적으로 적은 매개변수를 이용하여 긴 강우 시나리오를 생성할 수 있는 장점을 바탕으로 기후 변화와 결합하여 기후 변화 영향 평가에 활발하게 활용되고 있다. 본 연구에서는 General Circulation Model(GCM)으로 모의한 미래 월강우 자료에서 기후변화에 따른 강우량의 변화를 변동 인자(Change factor)로 정량화하고, 강우생성모형인 THM(The hybrid model)에 적용하여 미래 강우 시나리오를 모의하고자 한다. 먼저 기상청 28개 종관기상관측소를 대상으로 강우생성모형의 성능을 평가 하였고, 그 결과 집성기간 1시간-1일에 해당하는 강우의 통계치를 성공적으로 재현함을 확인하였다. 본 연구에서 생성된 미래 강우 시나리오는 1) 기후변화를 고려하였으며, 2) 시 단위의 고해상도 강우자료이며, 3) 수문 모의에 필요한 만큼 충분히 길게 생성할 수 있기 때문에 미래 수자원 관리 계획 및 수문 분석에 효과적으로 활용될 것이다.

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고무상 고분자막을 통한 물에 용해된 미량의 유기 염소계 탄화수소화합물의 분리

  • 오부근;하성룡;하상태;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.54-55
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    • 1993
  • 유기염소계 화합물들은 저렴한 가격과 우수한 세정력으로 기계, 금속, 섬유산업에서 뿐만아니라 일반적인 용제로도 널리 사용되고 있다. 그러나, 현재 산업현장에서사용 후 처리에 있어 유기염소계 화합물들을 완전히 제거하지 못하고 방출하는 실정이다. 또한, 음용수제조시 행해지는 염소소득으로 미량의 트리할로메탄(THM)인 클로로포름이 생성된다. 이러한 유기염소계 화합물들은 음용수 중에 포함되어 체내로 흡수되면 암을 유발시킨다. 따라서 물중에 용해된 미량의 유기염소계 화합물들을 제거하는 것이 필수불가결한 실정이다.

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