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Nanostructured PVdF-HFP/TiO2 Composite as Protective Layer on Lithium Metal Battery Anode with Enhanced Electrochemical Performance (PVdF-HFP/TiO2 나노복합체 보호층을 통한 리튬금속전지 음극의 전기화학적 성능 향상)

  • Lee, Sanghyun;Choi, Sang-Seok;Kim, Dong-Eun;Hyun, Jun-Heock;Park, Young-Wook;Yu, Jin-Seong;Jeon, So-Yoon;Park, Joongwon;Shin, Weon Ho;Sohn, Hiesang
    • Membrane Journal
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    • v.31 no.6
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    • pp.417-425
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    • 2021
  • As the demand for high-capacity batteries increases, there has been growing researches on the lithium metal anode with a capacity (3,860 mAh/g) of higher than that of conventional one and a low electrochemical potential (-3.040 V). In this study, using the anatase phased TiO2 nanoparticles synthesized by hydrothermal synthesis, a PVdF-HFP/TiO2 organic/inorganic composite material was designed and used as an interfacial protective layer for a Li metal anode. As-formed organic/inorganic-lithium composite thin film was confirmed through the crystalline structure and morphological analyses. In addition, the electrochemical test (cycle stability and voltage profile) confirmed that the protective layer of PVdF-HFP/TiO2 composite (10 wt% TiO2 and 1.1 ㎛ film thickness) contributed to the enhanced electrochemical performance of the lithium metal anode (Colombic efficiency retention: 90% for 77 cycles). Based on comparative test with the untreated lithium electrode, it was confirmed that our protective layer plays an important role to stabilize/improve the EC performance of the lithium metal negative electrode.

Design and Fabrication of Dual Linear Polarization Antenna for 28 GHz Band (28 GHz 대역에서 동작하는 이중 선형편파 안테나의 설계 및 제작)

  • Yoon, Joong-Han
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.1
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    • pp.13-22
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    • 2022
  • In this paper, we propose single and array antenna with dual linear polarization characteristics for 28 GHz band. The proposed antenna is designed two microstirp feeding structure and Taconic TLY-5 substrate, which is thickness 0.5 mm, and the dielectric constant is 2.2. The size of single patch antenna is 3.4 mm×3.4 mm, and total size of single antenna is 15.11 mm×15.11 mm. Also, the size of array antenna is 3.15 mm×3.15 mm, and total size of array antenna is 21.5 mm×13.97 mm. From the fabrication and measurement results, for 1×2 array antenna, in case of vertical polarization, cross polarization ratios are obtained from 14.23 dB to 20.79 dB and in case of horizontal polarization, cross polarization ratios are obtained from 14.31 dB to 22.74 dB for input port 1. in case of vertical polarization, cross polarization ratios are obtained from 15.75 dB to 25.88 dB and in case of horizontal polarization, cross polarization ratios are obtained from 14.70 dB to 22.82 dB for input port 2.

Design and Fabrication of Dual Linear Polarization Antenna for mmWave Application using FR-4 Substrate

  • Choi, Tea-Il;Yoon, Joong-Han
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.3
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    • pp.71-77
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    • 2022
  • In this paper, we propose 1×2 array antenna with dual linear polarization characteristics for mmWave band operation. The proposed antenna is designed two microstirp feeding structure and FR-4 substrate, which is thickness 0.4 mm, and the dielectric constant is 4.3. The size of 1×2 array antenna is 2.33 mm×2.33 mm, and total size of array antenna is 13.0 mm×6.90 mm. From the fabrication and measurement results, bandwidths of 1.13 GHz (28.52~29.65 GHz) for port 1 and 1.08 GHz (28.45~29.53 GHz) for port 2 were obtained based on the impedance bandwidth. Cross polarization ratios are obtained from 7.68 dBi to 16.90 dBi in case of vertical polarization, and from 7.46 dBi to 15.97 dBi in case of horizontal polarization for input port 1, respectively. Also, cross polarization ratios are obtained from 8.59 dBi to 13.72 dBi in case of vertical polarization and from 9.03 dB to 14.0 dB in case of horizontal polarization for input port 2, respectively.

A Study on Applicability of Smartphone Camera and Lens for Concrete Crack Measurement Using Image Processing Techniques (이미지 처리기법을 이용한 균열 측정시 스마트폰 카메라 및 렌즈 적용성에 대한 연구)

  • Seo, Seunghwan;Kim, Dong-Hyun;Chung, Moonkyung
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.4
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    • pp.63-71
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    • 2021
  • Recently, high-resolution cameras in smartphones enable measurement of minute objects such as cracks in concrete using image processing techniques. The technology to investigate the crack width using an application at an adjacent distance of the close shot range has already been implemented, but the use is limited, so it is necessary to verify the usability of the high-resolution smartphone camera to measure cracks at a longer distance. This study focuses on recognizing the size of subdivided crack widths at a thickness within 1.0 mm of crack width at a distance of 2 m. In recent Android-based smartphones, an experiment was conducted focusing on the relationship between the unit pixel size, which is a measurement component, and the shooting distance, depending on the camera resolution. As a result, it was possible to confirm the necessity of a smartphone lens for the classification and quantification of microcrack widths of 0.3 mm to 1mm. The universal telecentric lens for smartphones needed to be installed in an accurate position to minimize the effect of distortion. In addition, as a result of applying a 64 MP high-resolution smartphone camera and double magnification lens, the crack width could be calculated within 2 m in pixel units, and crack widths of 0.3, 0.5, and 1mm could be distinguished.

Assessment of Fluoride Release through Dentin Adhesive in the Alkasite Restorative Material and Giomer (알카자이트 수복재와 자이오머의 상아질 접착제를 투과하는 불소 유리 평가)

  • Kim, Haeni;Park, Howon;Lee, Juhyun;Seo, Hyunwoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.48 no.4
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    • pp.367-375
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    • 2021
  • This study evaluated the fluoride release of alkasite restorative material (ARM) and giomer penetrating the dentin adhesive layer. Twenty specimens were prepared for each restorative material, and dentin adhesive with uniform thickness was applied to half of them. The prepared specimens were placed in a polyethylene tube containing 2.0 mL of deionized water and deposited in a 37.0℃ water bath for the study duration. The amount of fluoride release was measured on the 1st, 3rd, 7th, 14th, 21st, and 28th days after deposition. The dentin adhesive applied to the ARM and giomer could not completely block the fluoride release; however, it significantly reduced its amount. The cumulative amount of fluoride release of the ARM after 28 days was higher than that of the giomer regardless of the application of dentin adhesive.

A Study on the Effect of the Orifice Shape on Oil Outflow from a Damaged Ship (사고 선박 손상부 형상이 기름 유출량에 미치는 영향 연구)

  • Park, Il-Ryong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.4
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    • pp.620-631
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    • 2022
  • This paper shows the numerical prediction of the change in oil outflow rate according to the orifice shape of a damaged ship by using the computational fluid dynamics (CFD) analysis method. It also provides discharge coefficients for various orifice shapes to be used in theoretical prediction approaches. The oil outflow from the model ship was analyzed using a multiphase flow method under the condition that the Froude and Reynolds number similitudes were satisfied. The present numerical results were verified by comparing them with the available experimental data. Along with the aspect ratio of the orifice and the wall thickness of the cargo tank, the effects of the orifice shapes defined by mathematical figures on the oil outflow were investigated. To consider more realistic situations, the investigation of the ef ect of the crushed iron plate around the damaged part was also included. The numerical results confirmed the change in oil outflow time for various shapes of the damaged part of the oil tank, and discharge coefficients that quantify the viscous effects of those orifice shapes were extracted. To verify the predicted discharge coefficients, they were applied to an oil spill estimation equation. As a result, a good agreement between the CFD and theoretical results was obtained.

Development and characterization of hyaluronic acid-based orally disintegrating film containing vitamin D (히알루론산 기반 비타민 D 함유 구강용해필름의 제조 및 특성평가)

  • Kang, Seo-Yeon;An, Da-Yeon;Han, Jung-Ah
    • Korean Journal of Food Science and Technology
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    • v.54 no.3
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    • pp.327-333
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    • 2022
  • An orally disintegrating film (ODF) based on hyaluronic acid (HA) containing vitamin D was developed. The vitamin D content in the ODF was set based on the adequate intake (AI) of vitamin D from 0 to 10 AI (0, 1, 4, 7, and 10AI). The control (0AI) had the highest thickness and showed the longest disintegration time among the samples. The moisture content of the ODFs was significantly lower in those with vitamin D compared to the control. As the amount of vitamin D increased, the water vapor permeability (WVP) of the ODFs decreased, and the opacity significantly increased. The tensile strength was higher in the films containing vitamin D compared to the control films. However, the elongation at the break showed no significant difference among the films. The vitamin D content in the film was reduced by 25.7-44.2% during processing compared to the amount that was originally added. Based on the above results, a new and convenient vitamin D delivery system, an ODF, could be successfully produced.

Analysis of Development Characteristics of the Terra Nova Bay Polynya in East Antarctica by Using SAR and Optical Images (SAR와 광학 영상을 이용한 동남극 Terra Nova Bay 폴리냐의 발달 특성 분석)

  • Kim, Jinyeong;Kim, Sanghee;Han, Hyangsun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1245-1255
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    • 2022
  • Terra Nova Bay polynya (TNBP) is a representative coastal polynya in East Antarctica, which is formed by strong katabatic winds. As the TNBP is one of the major sea ice factory in East Antarctica and has a great impact on regional ocean circulation and surrounding marine ecosystem, it is very important to analyze its area change and development characteristics. In this study, we detected the TNBP from synthetic aperture radar (SAR) and optical images obtained from April 2007 to April 2022 by visually analyzing the stripes caused by the Langmuir circulation effect and the boundary between the polynya and surrounding sea ice. Then, we analyzed the area change and development characteristics of the TNBP. The TNBP occurred frequently but in a small size during the Antarctic winter (April-July) when strong katabatic winds blow, whereas it developed in a large size in March and November when sea ice thickness is thin. The 12-hour mean wind speed before the satellite observations showed a correlation coefficient of 0.577 with the TNBP area. This represents that wind has a significant effect on the formation of TNBP, and that other environmental factors might also affect its development process. The direction of TNBP expansion was predominantly determined by the wind direction and was partially influenced by the local ocean current. The results of this study suggest that the influences of environmental factors related to wind, sea ice, ocean, and atmosphere should be analyzed in combination to identify the development characteristics of TNBP.

Therapeutic Effects of LED Fusion of Two Wavelength Bands on Atopic Dermatitis of NC/Nga Mice (융합 LED 광선치료가 아토피 피부염에 미치는 영향)

  • Lee, Sangmin;Choi, Ji-Hye;Koo, Bon-Jun;Kwon, Jungkee
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.4
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    • pp.552-559
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    • 2022
  • Atopic dermatitis (AD) is a chronic inflammatory skin disease accompanied by severe itching, mainly before five. The aim of this study is to investigate the effects of 405 nm+850 nm LED light therapy on AD-like symptoms in NC/Nga mice. The mice were randomly placed in the normal (Vehicle), atopic dermatitis-induced (CON), and 405 nm + 850 nm LED light therapy (LED) groups. The LED experimental group conducted 405 nm+850 nm wavelength LED ray therapy for 10 minutes a day for seven days. LED light therapy research confirmed the improvement and improvement of Dermatics score and observed the reduction of epidermal tissue thickness caused by dermatitis. Based on the significant decrease of serum IL-1𝛽 and transdermal moisture loss and serum IgE concentration due to LED light therapy, LED light therapy can help restore normal skin conditions in mice that cause atopic dermatitis. This study showed the anti-atopic effect of infrared light and blue light. Light in mice with atopic dermatitis led to the simultaneous use of circular LEDs with two wavelengths.

Bioactivity enhancement of zirconia substrate by surface coating of diopside bioceramics using sol-gel method (솔젤법에 의한 다이옵사이드 생체 세라믹의 표면코팅 및 지르코니아 기판의 생체활성 증진)

  • Park, Hyunjung;Lee, Jong Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.5
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    • pp.183-190
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    • 2022
  • Diopside (CaMgSi2O6) is known to have high bioactivity as well as excellent mechanical properties. In this study, we tried to improve the bioactivity of zirconia ceramics by surface coating of diopside and its bioactivity was investigated through an in vitro test. Surface coating on zirconia substrate was prepared by sol-gel method using a diopside sol which was prepared by dissolving Ca(NO3)2·4H2O, MgCl2·6H2O and Si(OC2H5)4 in ethanol with a fixed molar ratio and then hydrolysis. To examine the bioactivity of diopside coating, we examined the surface dissolution and the precipitation of new hydroxyapatite particles through in vitro test in SBF (Simulated Body Fluid) solution. Dense and thick diopside coating layers could be fabricated on zirconia substrate by sol-gel method. Also, we confirmed that they contained high bioactivity from the in vitro test, indicated the precipitation of hydroxyapatite particles after the 14 days immersion in SBF solution. In addition, we checked that the bioactivity of diopside coated layers was dependent on the repeated coating cycle and coating thickness.