• The Journal of the Petrological Society of Korea
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• v.15 no.1 s.43
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• pp.10-24
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• 2006

Staurolite grains in staurolite, kyanite and sillimanite zones occurred in the Littleton Formation, Northcentral Massachusetts have interpreted to form by Barrovian-type metamorphism during Acadian orogeny. However, various occurrence of staurolite in the three zones, (a) porphyroblast, (b) randomly oriented and coarse-grained muscovite pseudomorph after staurolite, (c) recrystallized staurolite at the margin of garnet porphyroblast and within the pseudomorph, indicates that they have resulted from polymetamorphism. Staurolite in these three metamorphic zones can be formed by demise of chlorite or chloritoid that depends on difference of bulk-rock compositions and changes of P-T conditions. Staurolite modal proportion calculated in MnNCKFHASH system using THERMOCALC program reveals that staurolite could have grown with garnet with increasing pressure and temperature, if it coexist with chlorite. After demise of chlorite and appearance of biotite, staurolite mode decrease with increasing pressure and temperature. Therefore, based on the previous P-T paths for the Acadian metamorhism, staurolite porphyroblast grew with garnet during 400-370 Ma. Randomly oriented and coarse-grained muscovite pseudomorphs after staurolite probably have grown due to heating with appearance of kyanite and sillimanite. Consequently, pseudomorphisrn of staurolite occurred by heating derived from locally intense Alleghanian shearing (ca. 320-300 Ma) overprinted the Acadian metamorphism. Recrystallized fine-grained staurolite in sillimanite zone observed between the grain boundaries of muscovite in the pseudomorphs and at the edge of garnet porphyrobasts has formed during decreasing temperature and pressure (ca. 300-280 Ma) after peak temperature (ca. $700^{\circ}C$) of the Allegllanian metamorphism.

• Journal of the Mineralogical Society of Korea
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• v.17 no.4
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• pp.309-325
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• 2004

The Cannington Ag-Pb-Zn deposit, northwest Queensland, Australia developed around the host rocks composing banded and migmatitic gneisses, sillimanite-garnet schist and amphibolite. Three crystal habits of sillimanite, gahnite (Zn-spinel) and garnet porphyroblasts occurred on the host rocks of the Cannington deposit could be used to delineate metamorphism that closely associated with Zn-mineralization in the deposit. Linkages the metamorphism to Zinc-mineralization is determined in four chemical systems, KFMASH (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$), KFMASHTO (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$-TiO$_2$-Fe$_2$O$_3$), NCKFMASH (Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$) and MnNCK-FMASH (MnO-Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$), using THERMOCALC program (version 3.1; Powell and Holland 1988). Partial melting in MnNCKFMASH and NCKFMASH systems occurs at lower temperature than in the KFMASH and KFMASHTO systems. The partial melting temperature decreases with increasing of Na/(Na+Ca+K) of the bulk rock compositions in the MnNCKFMASH system. The host rocks have melted ca 15 vol.% in the MnNCKFMASH system at peak metamorphic conditions (634$\pm$62$^{\circ}C$ and 4.8$\pm$1.3 kbar), but partial melting have not occurred in KFMASHTO system. Based on calculations of sillimanite isograd in different systems and sillimanite modal pro-portion, prismatic and rhombic sillimanite and gahnite porphyroblasts including prismatic sillimanite inclusion probably have resulted from pressure and temperature increasing through partial melting (from 550～$600^{\circ}C$, 2.0～3.0 kbar to 700～75$0^{\circ}C$, 5.0～7.0 kbar), furthermore have experienced N-S then W-E crustal shortening during D$_1$ and D$_2$ deformation. Consequently, Zinc mineralization related to gahnite growth occurred during D$_2$ and was redistributed and upgraded by partial melting and retrograde metamorphism into structural and rheological sites during shearing in D$_3$.