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Growth Behavior of Aluminum Borate Whisker under 2.45 GHz Electromagnetic Irradiation (2.45 GHz 전자기파 조사하에서 Aluminum Borate Whisker의 성장 거동)

  • 김성완;이상근;김지경;이창희;안진모;신준식;박성수;박희찬
    • Journal of the Korean Ceramic Society
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    • v.40 no.10
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    • pp.998-1004
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    • 2003
  • With starting materials of two different powder mixtures, $Al_2$(S $O_4$)$_3$+xNa$_2$B$_4$ $O_{7}$$.$10$H_2O$(㏖ ratio; x=0.1, 0.7) and ${\gamma}$-Al$_2$ $O_3$+xNa$_2$B$_4$ $O_{7}$$.$10$H_2O$(㏖ ratio; x=0.1, 0.7), whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were synthesized by using conventional and microwave heat-treatment. The effects of microwave, amount of flux and temperature on the growth of whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were investigated by using X-Ray Diffractometry (XRD) and Scanning Electron Microscopy (SEM). With increase of heat-treatment temperature and amount of flux, the size of whisker-type $Al_{18}$B$_4$ $O_{33}$ particles increased in both conventional and microwave heat-treated samples. However, compared to the conventional heat-treated samples, whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were well grown for the microwave heat-treated samples.ted samples.

Two Anhydrous Zeolite X Crystal Structures, $Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}\;and\;Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}$ (제올라이트 X의 두 개의 무수물 $Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}$$Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}$의 결정구조)

  • Choi, Eun Young;Kim, Yang
    • Journal of the Korean Chemical Society
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    • v.43 no.4
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    • pp.384-385
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    • 1999
  • Two anhydrous crystal structures of fully dehydrated, $Ca^{2+}$- and $Tl^+$-exchanged zeolite X, TEX>$Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}($Ca_{18}Tl_{56}$-X;\alpha=24.883(4)\AA)$ and TEX>$Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}($Ca_{32}Tl_{28}$-X;\alpha=24.973(4)\AA)$ per unit cell, have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at $21(1)^{\circ}C.$ $Ca_{18}Tl_{56}-X$ was prepared by ion exchange in a flowing stream of 0.045 M aqueous $Ca(NO_3)_2$ and 0.005 M $TlNO_3$. $Ca_{32}Tl_{28}-X$ was prepared similarly using a mixed solution of 0.0495 M $Ca(NO_3)_2$ and 0.0005M $TlNO_3$. Each crystal was then dehydrated at 360 $^{\circ}C$ and $2{\times}10^{-6}$ Torr for 2 days. Their structures were refined to the final error indices, $R_1=0.039\;and\;R_2=0.036$ with 382 reflections for $Ca_{18}Tl_{56}-X$ , and $R_1=0.046\;and\;R_2=0.045$ with 472 reflections for $Ca_{32}Tl_{28}$-X for which $/>3\sigma(I).$ In the structures of dehydrated $Ca_{18}Tl_{56^-}X\;and\;Ca_{32}Tl_{28}$-X, $Ca^{2+}\;and\;Tl^+$ ions are located at six crystallographic sites. Sixteen $Ca^{2+}$ ions fill the octahedral sites I at the centers of double six rings ($Ca_{18}Tl_{56}$-X:Ca-O=2.42(1) and O-Ca-O=93.06(4)$^{\circ}$; $Ca_{32}Tl_{28}$-X Ca-O=2.40(1) $\AA$ and O-Ca-O=93.08(3)$^{\circ}$). In the structure of $Ca_{18}Tl_{56}$-X, another two $Ca^{2+}$ ions occupy site II (Ca-O=2.35(2) $\AA$ and O-Ca-O=111.69(2)$^{\circ}$) and twenty six $Tl^+$ ions occupy site II opposite single six-rings in the supercage; each is 1.493 $\AA$ from the plane of three oxygens $(Tl-O=2.70(8)\AA$ and O-Tl-O=92.33(4)$^{\circ}$). About four $Tl^+$ ions are found at site II',1.695 $\AA$ into sodalite cavity from their three oxygen plane (Tl-O=2.81 (1) and O-Tl-O=87.48(3)). The remaining twenty six $Tl^+$ ions are distributed over site III'(Tl-O=2.82 (1) $\AA$ and Tl-O=2.88(3)$^{\circ}$). In the structure of $Ca_{32}Tl_{28}$-X, sixteen $Ca^{2+}$ ions and fifteen $Tl^+$ ions occupy site III' (Ca-O=2.26(1) $\AA$ and O-Ca-O=119.14(4)$^{\circ}$; Tl-O=2.70(1) $\AA$ and O-Tl-O=92.38$^{\circ}$) and one $Tl^+$ ion occupies site II'. The remaining twelve $Tl^+$ ions are distributed over site III'. It appears that $Ca^{2+}$ ions prefer sites I and II in that order and $Tl^+$ ions occupy the remaining sites.

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Crystal Structures of Full Dehydrated $Ca_{35}Cs_{22}Si_{100}Al_{92}O_{384}$and $Ca_{29}Cs_{34}Si_{100}Al_{92}O_{384}$ ($Ca^{2+}$ 이온과 $Cs^+$ 이온으로 치환되고 탈수된 두개의 제올라이트 X $Ca_{35}Cs_{22}Si_{100}Al_{92}O_{384}$$Ca_{29}Cs_{34}Si_{100}Al_{92}O_{384}$의 결정구조)

  • Jang, Se Bok;Song, Seung Hwan;Kim, Yang
    • Journal of the Korean Chemical Society
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    • v.40 no.6
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    • pp.427-435
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    • 1996
  • The structures of fully dehydrated $Ca^{2+}$- and $Cs^+$-exchanged zeolite X, $Ca_{35}Cs_{22}Si_{100}Al_{92}O_{384}$($Ca_{35}Cs_{22}$-X; a=25.071(1) $\AA)$ and $Ca_{29}Cs_{34}Si_{100}Al_{92}O_{384}$($Ca_{29}Cs_{34}$-X; a=24.949(1) $\AA)$, have been determined by single-crystal X-ray diffraction methods in the cubic space group Fd3 at $21(1)^{\circ}C.$ Their structures were refined to the final error indices $R_1$=0.051 and $R_2$=0.044 with 322 reflections for $Ca_{35}Cs_{22}$-X, and $R_1$=0.058 and $R_2$=0.055 with 260 reflections for $Ca_{29}Cs_{34}$-X; $I>3\sigma(I).$ In both structures, $Ca^{2+}$ and $Cs^+$ ions are located at five different crystallographic sites. In dehydrated $Ca_{35}Cs_{22}$-X, sixteen $Ca^{2+}$ ions fill site I, at the centers of the double 6-rings(Ca-O=2.41(1) $\AA$ and $O-Ca-O=93.4(3)^{\circ}).$ Another nineteen $Ca^{2+}$ ions occupy site II (Ca-O=2.29(1) $\AA$, O-Ca-O=118.7(4)') and ten $Cs^+$ ions occupy site II opposite single six-rings in the supercage; each is $1.95\AA$ from the plane of three oxygens (Cs-O=2.99(1) and $O-Cs-O=82.3(3)^{\circ}).$ About three $Cs^+$ ions are found at site II', 2.27 $\AA$ into sodalite cavity from their three-oxygen plane (Cs-O=3.23(1) $\AA$ and $O-Cs-O=75.2(3)^{\circ}).$ The remaining nine $Cs^+$ ions are statistically distributed over site Ⅲ, a 48-fold equipoint in the supercages on twofold axes (Cs-O=3.25(1) $\AA$ and Cs-O=3.49(1) $\AA).$ In dehydrated $Ca_{29}Cs_{34}$-X, sixteen $Ca^{2+}$ ions fill site I(Ca-O=2.38(1) $\AA$ and $O-Ca-O=94.1(4)^{\circ})$ and thirteen $Ca^{2+}$ ions occupy site II (Ca-O=2.32(2) $\AA$, $O-Ca-O=119.7(6)^{\circ}).$ Another twelve $Cs^+$ ions occupy site II; each is $1.93\AA$ from the plane of three oxygens (Cs-O=3.02(1) and $O-Cs-O=83.1(4)^{\circ})$ and seven $Cs^+$ ions occupy site II'; each is $2.22\AA$ into sodalite cavity from their three-oxygen plane (Cs-O=3.21(2) and $O-Cs-O=77.2(4)^{\circ}).$ The remaining sixteen $Cs^+$ ions are found at III site in the supercage (Cs-O=3.11(1) $\AA$ and Cs-O=3.46(2) $\AA).$ It appears that $Ca^{2+}$ ions prefer sites I and II in that order, and that $Cs^+$ ions occupy the remaining sites, except that they are too large to be stable at site I.

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Antibacterial Activity of $Scutellaria$ $baicalensis$ Extract against Antibiotic Resistant Bacteria (항생제 내성균에 대한 황금 추출물의 항균효과)

  • Jang, Jae-Seon;Kim, Jung-Hee;Kwon, Mun-Ju
    • The Korean Journal of Food And Nutrition
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    • v.24 no.4
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    • pp.708-712
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    • 2011
  • This study was focused on the determination of antibacterial activity of $Scutellaria$ $baicalensis$ extract against antibiotic resistant bacteria($Salmonella$ Enteritidis, $Staphylococcus$ $aureus$ and enteroaggregative $E.$ $coli$). Extract of $Scutellaria$ $baicalensis$ were tested for antibacterial activity by paper disc methods. The $Scutellaria$ $baicalensis$ extract in 0.1 g/$m{\ell}$ and 0.2 g/$m{\ell}$ showed a significant antibacterial activity against antibiotic resistant bacteria. Minimum inhibitory concentration (MIC) of $Scutellaria$ $baicalensis$ extract were appeared to 2,048 ${\mu}g/m{\ell}$ at $S.$ Enteritidis, $S.$ $aureus$ and enteroaggregative $E.$ $coli$. Finally, the growth incubation curve was determined using $Scutellaria$ $baicalensis$ extract against $S.$ Enteritidis, $S.$ $aureus$ and enteroaggregative $E.$ $coli$. The growth of $S.$ Enteritidis was significantly inhibited within 10 hours by the addition of at least 10,000 ppm of $Scutellaria$ $baicalensis$ extract. The 10,000 ppm of $Scutellaria$ $baicalensis$ extract retarded the growth of $S.$ $aureus$ and enteroaggregative $E.$ $coli$ more than 10 hours. In conclusion, $Scutellaria$ $baicalensis$ extract might be useful to control antibiotic resistant bacteria $in$ $vitro$.

The Electrical Properties and Stability of $Pr_6$$O_{11}$-Based ZnO Varistors Doped with $Dy_2$$O_3$ ($Dy_2$$O_3$가 첨가된 $Pr_6$$O_{11}$계 ZnO 바리스터의 전기적 성질 및 안정성)

  • 남춘우;윤한수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.402-410
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    • 2000
  • The electrical properties and stability of Pr$_{6}$/O$_{11}$-based ZnO wvaristors consisting of ZnO-Pr$_{6}$/O$_{11}$-CoO-Dy$_{2}$/O$_{3}$ based ceramics were investigated in the Dy$_{2}$/O$_{3}$ additive content range o 0.0 to 2.0 mol%. The density was nearly constant 5.62 g/cm$^3$corresponding to 97% of theoretical density as Dy$_{2}$/O$_{3}$ additive content increases up to 0.5 mol%. However the density decreased as Dy$_{2}$/O sub 3/ additive content is further additive content. Pr$_{6}$/O$_{11}$-based ZnO varistors doped with 0.5mol% Dy$_{2}$/O$_{3}$ exhibited a good nonlinearity, which is 37.76 in the nonlinear exponent and 5.36 $mutextrm{A}$ in the leakage current. And they exhibited very stress (0.80 V$_{1mA}$/9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$/115$^{\circ}C$/12h)+(0.95 V$_{1mA}$/1$25^{\circ}C$/12h). Consequently it was estimated that ZnO-0.5 mol% Pr$_{6}$/O$_{11}$-1.0 mol% CoO-0.5 mol% Dy$_{2}$/O$_{3}$ based ceramics will be sufficiently used as a basic composition to develop the advanced Pr$_{6}$/O$_{11}$-based ZnO varistors in the future.he future.uture.he future.

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The κ-Fermat's Integer Factorization Algorithm (κ-페르마 소인수분해 알고리즘)

  • Choi, Myeong-Bok;Lee, Sang-Un
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.11 no.4
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    • pp.157-164
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    • 2011
  • It is very difficult problem to factorize composite number. Integer factorization algorithms, for the most part, find ($a,b$) that is congruence of squares ($a^2{\equiv}b^2$(mode $n$)) with using factoring(factor base, B) and get the result, $p=GCD(a-b,n)$, $q=GCD(a+b,n)$ with taking the greatest common divisor of Euclid based on the formula $a^2-b^2=(a-b)(a+b)$. The efficiency of these algorithms hangs on finding ($a,b$). Fermat's algorithm that is base of congruence of squares finds $a^2-b^2=n$. This paper proposes the method to find $a^2-b^2=kn$, ($k=1,2,{\cdots}$). It is supposed $b_1$=0 or 5 to be surely, and b is a double number. First, the proposed method decides $k$ by getting kn that satisfies $b_1=0$ and $b_1=5$ about $n_2n_1$. Second, it decides $a_2a_1$ that satisfies $a^2-b^2=kn$. Third, it figures out ($a,b$) from $a^2-b^2=kn$ about $a_2a_1$ as deciding $\sqrt{kn}$ < $a$ < $\sqrt{(k+1)n}$ that is in $kn$ < $a^2$ < $(k+1)n$. The proposed algorithm is much more effective in comparison with the conventional Fermat algorithm.

91년 3/4분기 전국 지가변동률조사 결과

  • 한국주택협회
    • 주택과사람들
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    • no.2 s.19
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    • pp.83-88
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    • 1991
  • [ $\circ$ ]''91년 3/4분기 중 전국평균지가상승률은$ 2.71\%$(''91년 누계: $11.18\%$) $\circ$ 도시규모별: 6대도시-$2.73\%$, 중소도시-$3.21\%$, 녹지-$3.11\%$, 비도시-2.01$\%$ $\circ$ 용도지역별: 주거-2.71$\%$, 상업-2.78$\%$, 공업-$3.61\%$, 녹지-$3.11\%$, 비도시-$2.01\%$ $\circ$$\cdot$도별: 대전($7.14\%$), 인천($4.78\%$) 등이 많이 올랐고, 서울($1.93\%$), 전남($1.09\%$) 등의 상승률이 낮았음.

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NOTES ON A NON-ASSOCIATIVE ALGEBRAS WITH EXPONENTIAL FUNCTIONS I

  • CHOI, SEUL HEE
    • Honam Mathematical Journal
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    • v.28 no.2
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    • pp.197-204
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    • 2006
  • For the evaluation algebra $F[e^{{\pm}{\chi}}]_M$, if M={$\partial$}, the automorphism group $Aut_{non}$($F[e^{{\pm}{\chi}}]_M$) and $Der_{non}$($F[e^{{\pm}{\chi}}]_M$) of the evaluation algebra $F[e^{{\pm}{\chi}}]_M$ are found in the paper [12]. For M={${\partial}^n$}, we find $Aut_{non}$($F[e^{{\pm}{\chi}}]_M$) and $Der_{non}$($F[e^{{\pm}{\chi}}]_M$) of the evaluation algebra $F[e^{{\pm}{\chi}}]_M$ in this paper. We show that a derivation of some non-associative algebra is not inner.

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GENERALIZED((ξ, ζ)-) SOFT INTERIOR Γ-HYPERIDEALS OF Γ-SEMIHYPERGROUPS

  • Abbasi, M.Y.;Basar, A.;Talee, A.F.;Khan, S.A.
    • Honam Mathematical Journal
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    • v.40 no.1
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    • pp.93-108
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    • 2018
  • In this paper, we introduce the notion of ($\xi$, ${\zeta}$)-soft ${\Gamma}$-hyperideals and ($\xi$, ${\zeta}$)-soft interior ${\Gamma}$-hyperideals of ${\Gamma}$-semihypergroups by a new approach called soft intersection (briefly, S. I.). It is proved that in regular ${\Gamma}$-semihypergroups the ($\xi$, ${\zeta}$)-soft ${\Gamma}$-hyperideals and the ($\xi$, ${\zeta}$)-soft interior ${\Gamma}$-hyperideals coincide. Further, we introduce the concept of ($\xi$, ${\zeta}$)-soft simple ${\Gamma}$-semihypergroup and characterize the simple ${\Gamma}$-semihypergroups in terms of ($\xi$, ${\zeta}$)-soft ${\Gamma}$-hyperideals and ($\xi$, ${\zeta}$)-soft interior ${\Gamma}$-hyperideals.