• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.30 no.1
• /
• pp.42-47
• /
• 2017

In this study, the physical and optical properties of $ZnS:Mn^{2+}$ Quantum Dot prepared by wet-process condition with Mn/Zn ratio was valuated. The powder characteristics and optical behavior were investigated through XRD, TEM and Photo spectrometer exicted by various UV light source. We found the main peak of ZnS (111) was shifted by 0.8 degree to low angle position with increasing stirring energy from 200 RPM to 600 RPM, which is thought to be the increase of lattice defects during wet process. The photo luminescence at 600 RPM shows also higher blue intensity which is well correlated with XRD results. With increasing Mn/Zn ratio, the PL intensity become higher and shifed by 8.5nm to right side, by the increment of substitutional $Mn^{2+}$ ions.

• Journal of Advanced Marine Engineering and Technology
• /
• v.22 no.6
• /
• pp.792-799
• /
• 1998

Further improvement of existing $H_{2}O/LiBr$ absorption refrigeration machine is absolutely neces-sary to promote the utilization of gas-cooling system Among various methods to improve the per-formance of the absorption refrigeration machine this research has focused on the use of a new working fluid that has better properties than the existing $H_{2}O/LiBr$ working fluid. In the series of the research, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ system was selected as the most promisable candidate. The absorption refrigeration machine is water-cooled double-effect, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ sys-tem with series flow type. In this study we found out the characteristic of new working solution through the cycle simulation and compared the result with that of LiBr solution to evaluate. Theoptimum designs and operating conditions were determined based on the operating constraints and the coefficient of performance. Results demonstrate that new working fluid subsrantially increases COP by as much as 10% and has a wider working range with 8% higher crystallization limits compared to the conventional $H_{2}O/LiBr$.

• Journal of Advanced Marine Engineering and Technology
• /
• v.23 no.3
• /
• pp.284-291
• /
• 1999

Recently the ductile cast iron is being used successfully to the parts for processing machinery vessels and gear etc. This study is mainly concerned with the heat treatment for the specimens of crank shaft which are made of ductile cast iron. The results obtained are summarized as follows. Comparing the mechanical properties of the specimens for the normalized ductile cast irons the specimen heat treated at $550^{\circ}C$ was the best for crank shaft of air-compressor. After austenizing at $910^{\circ}C$ it was observed that the higher the reheating temperature is the less tensile strength and the hardness became which was supposedly attributed to the fact that the amount of pearlite. Austenite matrix was reduced by reheating after normalizing and that as the reheating tem-perature went up the pearlite generated was less and the distance between the pearlites were widened at last made pearlite globular. In the comparsison of crank shaft for air compressor made of ductile cast iron with that made by forged steel the crank shaft made of ductile cast iron was superior in economical terms. And ductile cast iron could be practically enough if only the elonga-tion which was inferior mechanical property to forged steel could be reinforced by increasing the diameter of crank pin when designing the crank shaft.

• Journal of Korea Foundry Society
• /
• v.10 no.5
• /
• pp.417-425
• /
• 1990

The purpose of this study is to investigate the effect of Be addition on the microstructure and mechanical properties of as-cast and homogenization treated Al-Li-(Be)alloys. The ductility of as-cast Al-Li alloy was increased by the addition of Be and the fracture morphology was changed from brittle to ductile mode. Also, hardness and strength have been decreased by homogenization treatment. The morphology of eutectic structure which consists of ${\alpha}(Al)$ and ${\alpha}(Be)$ was changed from lammellae to spherical type by homogenization treatment. The shape of ${\alpha}(Be)$ phase has been revealed as hollow type by TEM observation. It consists of outer surfaces with well defined crystal facets and the core filled with ${\alpha}(Al)$. The microstructure of as-cast Al-Li-Be alloys showed coarse ${\delta}'$, fine ${\delta}'$, and coarse ${\delta}$ phases. The coarse and fine ${\delta}'$ phases were formed at Be-rich phase /matrix interfaces and in matrix, respectively. By homogenization treatment, the ${\delta}$ phase in Al-Li and Al-Li-Be alloys dissolved and the size of ${\delta}$ phase in Al-Li-Be alloys was finer than that of Al-Li alloy.

• Journal of the Korean Society of Costume
• /
• v.22
• /
• pp.345-356
• /
• 1994

The Shirts Blouse was produced through the process of shirts Blouse pattern making by utilizing CAD System developed by PAD Sys-tem Techologies Co. Ltd that is suitable to educational use or industrial use. The purpose of this study was to provide the basic data for the development of efficient and various design patterns by applying this pro-cess to the actual business of apparel making. The results were as follows: 1. The applicable range of CAD system 1) The repeated work can be avoided by thansforming and developing the basic pattern stored and the storage and remodification were easy. 2) The deletion duplication movement and copy of all points and lines in the pattern can be made freely and measurement of all lengths and angles the attachment of two patterns were possible. 3) The grading Library of the basic pattern was applied as it was and the time was curtailed by adding only several grading points with the change of design. 2. The problem in the use of the CAD System 1) Through the input of basic pattern by the digitizer the minute size difference was generated as each point on the curve came to be designated. 3) In grading the line of neck girth there was inconveniences to go to the plan view in order find out deviation.

• Journal of Advanced Marine Engineering and Technology
• /
• v.21 no.4
• /
• pp.372-380
• /
• 1997

This paper describes experimental investigations of helium-air exchange flows through parti¬tioned opening and two-opening. Such exchange flows may occur following rupture accident of stand pipe in high temperature gas cooled reactor. A test vessel with the two types of small open¬ing on top of test cylinder is used for experiments. An estimation method of mass increment is developed and applied to measure the exchange flow rate. A technique of flow visualization by Mach-Zehnder interferometer is provided to recognize the exchange flows. In the case of exchange flow through the partitioned opening, flow passages of upward flow of the helium and downward flow of the air within the opening are separated by vertical partition, and the two flows interact out of entrance and exit of the opening. Therefore, an experiment of the exchange flow through two-opening is made to investigate effect of the fluids interaction of the partitioned opening sys¬tem. As a result of comparison of the exchange flow rates between the two types of the opening system, it is found that the exchange flow rate of the two-opening system is larger than that of the partitioned opening system due to absence of the effect of fluids interaction. Finally, the fluids interaction between the upward and downward flows through the partitioned opening is found to be an important factor on the helium-air exchange flow.

• Korean Journal of Materials Research
• /
• v.26 no.1
• /
• pp.13-16
• /
• 2016

Morphology and formation processes of lamellar grain boundaries in titanium rich binary TiAl intermetallics were studied. TiAl alloys containing aluminum content of 44 to 48 at.% were induction-heated to 1723 K followed by helium-gas-quenching at various temperatures. For the Ti-44%Al, few lamellae were observed in samples quenched from higher than 1473 K. Although small peaks of beta phase were detected using X-ray diffraction, only the ordered hexagonal phase (${\alpha}_2$) with clear APB contrast was observed in TEM observation. For the Ti-48 at.%Al alloy, almost no lamellar structure, and straight grain boundaries were observed in samples quenched from higher than 1623 K. The formation of lamellae along grain boundaries was observed in the sample quenched from 1573 K. The fully lamellar microstructures with serrated boundaries were observed in samples quenched from lower than 1473 K. It was found that the formation of ${\gamma}$ platelets took place at higher temperatures in Ti-48 at.%Al than in Ti-44 at.%Al. Although the size of the serration is different, serrated lamellar grain boundaries could be obtained for all alloy compositions employed. The serration appeared to be due to the grain boundary migration induced by precipitation and growth of ${\gamma}$. Differences in transformation characteristics with aluminum content are discussed.

• Korean Journal of Materials Research
• /
• v.27 no.5
• /
• pp.270-275
• /
• 2017

Inorganic phosphors based on $ZrO_2:Eu^{3+}$ nanoparticles were synthesized by a salt-assisted ultrasonic spray pyrolysis process that is suitable for industrially-scalable production because of its continuous nature and because it does not require expensive precursors, long reaction time, physical templates or surfactant. This facile process results in the formation of tiny, highly crystalline spherical nanoparticles without hard agglomeration. The powder X-ray diffraction patterns of the $ZrO_2:Eu^{3+}$ (1-20 mol%) confirmed the body centered tetragonal phase. The average particle size, estimated from the Scherrer equation and from TEM images, was found to be approximately 11 nm. Photoluminescence (PL) emission was recorded under 266 nm excitation and shows an intense emission peak at 607 nm, along with other emission peaks at 580, 592 and 632 nm which are indicated in red.

• Korean Journal of Materials Research
• /
• v.27 no.5
• /
• pp.255-262
• /
• 2017

Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substances in natural water environments and can completely destroy various organic pollutants in waste water. In this study, we used graphene oxide modified $Ag_2Se$ nanoparticles to enhance photochemically generated oxygen (PGO) species activity. Surface area and pore volumes of the $Ag_2Se-graphene$ ($Ag_2Se-G$) samples showed catastrophic decrease due to deposition of $Ag_2Se$. The generation of reactive oxygen species was detected through the oxidation reaction of DPCI to DPCO. The photocurrent density and the PGO effect increase in the case of the use of modified graphene. The PGO effect of the graphene modified with $Ag_2Se$ composites increased significantly due to a synergetic effect between graphene and the $Ag_2Se$ nanoparticles. The photocatalytic activity of sample was evaluated by measuring the degradation of organic pollutants such as methylene blue (MB) and industrial dyes such as Texbrite BA-L (TBA) under visible light.

• Korean Journal of Materials Research
• /
• v.8 no.9
• /
• pp.825-830
• /
• 1998

자화된 유도결합형 C4F8 플라즈마로 SiO2를 건식식각시 실리콘 표면에 발생하는 손상과 오염에 대하여 연구하였다. 오염의 분석을 위해서 XPS, SIMS, TEM을 사용하였으며, 손상정도를 측정하기 위해서 HRTEM과 Schottky-diode 구성을 통한 I-V특성 측정을 사용하였다. 유도 결합형 C4F8 플라스마에 0에서 18Gauss까지의 자장이 가해짐에 따라서 실리콘 표면에 생기는 잔류막의 두께가 SiO2식각속도와 선택비의 증가와 함께 증가하였으며, XPS를 통하여 그 조성이 fluorine-rich에서 carbon-rich 한 상태로 변화함을 알 수 있었다. 자장을 가하지 않는 상태에서는 표면에서 $40\AA$부근까지 고밀도의 손상층이 관찰되었으나, 자장을 가함에 따라서 노출된 손상층의 깊이는 깊어지나 그 밀도는 줄어들음을 HRTEM을 통하여 관찰 할 수 있었다. Schottky-diode를 통한 I-V특성곡선의 분석으로 자장이 증가함에 따라서 전기적인 손상이 감소함을 알 수 있었다.