In dental resin cement studies, viscosity is also an important factor in the adhesion of tooth defects and implants. This study used BisGMA and HPMA as the main ingredients, triethylene glycol dimethacrylate (TEGDMA) as a diluent, and benzoyl peroxide (BPO) as a photoinitiator. The physical properties of graphene oxide used as an additive for functionality were evaluated, and its use as a dental resin cement material was investigated.The rupture strength has the tendency to increase along with the increase of the ratio of graphene oxide that was added, which seemed to reflect the effect of the high strength property of graphene oxide. The flexural strength also has the tendency to increase when about 0.5% of graphene oxide was added the same as the increase of rupture strength.When graphene oxide was added, according to viscosity use, the utilization as high-quality dental resin cements will increase.
Seo, Young-Ju;Kook, Joong-Ki;Yoon, Jung-Hoon;Kim, Su-Gwan;Lee, Nan-Young;Lee, Sang-Ho
Journal of the korean academy of Pediatric Dentistry
/
v.31
no.2
/
pp.247-255
/
2004
The purpose of this study was to examine the effects of resin composite monomers (Bis-GMA, TEGDMA, EGDMA, UDMA, HEMA, Camphorquinone) on the growth of the two cariogenic bacteria, Streptococcus mutans and Streptococcus sobrinus. We obtained the following results : 1. The growth rate of S. mutans and S. sobrinus was decreased significantly in the group of all composite resin monomer at a concentration of 0.03mmo1/L(P<0.01). 2. The growth rate of S. mutars in the group of UDMA at a concentration of 0.01 mmol/L and the group of CQ at a concentration of 0.005 mmol/L, 0.01 mmol/L was decreased significantly compared to the control group(P<0.01). 3. The growth rate of S. sobrinus in the group of HEMA, UDMA at a concentration of 0.01 mmol/L and the group of CQ at a concentration of 0.005mmol/L. 0.01mmo1/L was decreased significantly compared to the control group (P<0.01). 4. The growth rate of S. sobrinus in the group of EGDMA at a concentration of 0.001, 0.01, 0.03mmo1/L was decreased significantly compared to the control group(P<0.01) and were showed to be statistically significant difference between experimental groups(P<0.01).
Journal of the korean academy of Pediatric Dentistry
/
v.33
no.1
/
pp.70-76
/
2006
The aim of this study was comparison of effectiveness of surface treatment methods in reducing the oxygen-inhibited layer of a commercially available freshly polymerized, light cured dental sealant($concise^{TM}$, 3M, St Paul, USA). Surface treatment groups were consisted of no treatment(negative control group) and 3 experimental groups according to surface treatment of light-cured sealant. Experimental group I was 10 seconds' exposure to distilled water syringe, group II was 10 seconds' manual application using a cotton pellet wetted with 75% alcohol and group III was 10 seconds' prophylaxis with pumice/water slurry using rubber cup on a slow-speed handpiece. All specimens were immersed in 5ml distilled water and stored at 37c water bath for 10 minutes. All eluates were analyzed by HLPC for identification and quantitive analysis of monomers. The results of this study can be summarized as follows. 1. None of the chromatograms of the tested sealant displayed peaks with the same retention time as that of the standard solution, except for TEGDMA. 2. All surface treatment group had a statistically significant decrease of monomer release in comparison with no treatment group. 3. Removal effects of unreacted monomer in group III was statistically significant in comparison with group I and group II. These results revealed that mechanical method using pumice and rubber cup is the most effective in removing residual monomer and may be valuable to be used effectively in clinic.
Kim Yong;Lee Juyeon;Park Kwangyong;Kim Chang Keun;Kim Ohyoung
Polymer(Korea)
/
v.28
no.5
/
pp.426-432
/
2004
To reduce volumetric shrinkage of the commercially available polymeric dental composite during curing reaction, (2,2-bis [4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (bis -GMA) derivatives, i.e., (2,2-bis[3-methyl, 4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propan) (DMBis-GMA) and (2,2-his [3,5-dimethyl ,4- (2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (TMBis-GMA) were synthesized and then new dental composite resin composed of Bis-GMA derivatives, diluent, spiro orthocarbonate (SOC), and inorganic filler was produced. Among the Bis-GMA derivative/Bis-GMA derivative/diluent mixtures, Bis-GMA/ TMBis-GMA/TEGDMA mixture exhibited the lowest volumetric shrinkage. Volumetric shrinkage of this mixture was further reduced by adding SOC. Volumtric shrinkage of dental composite prepared from commercially available resin monomer mixture was $2.5\%$, while that prepared from resin monomer mixture having minimum volumetric shrinkage was reduced to $0.7\%$. Mechanical strength of this dental composite was nearly the same with that of commercial products but the time required for the curing reaction was retarded.
Kim, Duck-Hyun;Jung, Hwi-Su;Kim, Sun-Hun;Sung, A-Young
Journal of the Korean Chemical Society
/
v.62
no.2
/
pp.93-98
/
2018
Bis-GMA, TEGDMA, and camphorquinone were used as the main material, cross-linking agent, and photoinitiator, respectively. In addition, 2-isocyanatoethyl methacrylate was used as an additive for high strength, while the 3-hydroxypyridine was used as an additive for antibacterial activity. Photopolymerization was also carried out at a 440-480 nm wavelength and at about $1000mW/cm^2$ intensity for about 40 seconds. The breaking strength measurement of the samples showed that the breaking strength increased along with increasing the addition ratio of IEM, while it took less time until the polymerization was complete, thereby suggesting that the degree of polymerization has the tendency to increase. And also, compared to the size of the clear zone formed by ampicillin, the 3-hydroxypyridine group exhibited antimicrobial activity induced by ampicillin. The results of this study suggest that the use of 2-isocyanatoethyl methacrylate as an additive for high strength and 3-hydroxypyridine as an additive for improved antibacterial activity would improve the usability of the fabricated polymer as a dental resin cement material with high functionality.
Journal of the korean academy of Pediatric Dentistry
/
v.31
no.3
/
pp.516-526
/
2004
Polymerization shrinkage of photoinitiation type composite resin cause several clinical problems. The purpose of this study was to evaluate the shrinkage strain stress, linear polymerization shrinkage, compressive strength and microhardness of recently developed composite resins. The composite resins were divided into four groups according to the contents of matrix and filler type. Group I : $Denfil^{TM}$(Vericom, Korea) with conventional matrix, Group II : $Charmfil^{(R)}$(Dentkist, Korea) with microfiller and nanofller mixture, Group III : $Filtek^{TM}$ Z250(3M-ESPE, USA) TEGDMA replaced by UDMA and Bis-EMA(6) in the matrix, and Group IV : $Filtek^{TM}$ Supreme(3M-ESPE, USA) using pure nanofiller. Preparation of acrylic molds were followed by filling and curing with light gun. Strain gauges were attached to each sample and the leads were connected to a strainmeter. With strainmeter shrinkage strain stress and linear polymerization shrinkage was measured for 10 minutes. The data detected at 1 minute and 10 minutes were analysed statistically with ONE-way ANOVA test. To evaluate the mechanical properties of tested materials, compressive hardness test and microhardness test were also rendered. The results can be summarized as follows : 1. Filling materials in acrylic molds showed initial temporary expansion in the early phase of polymerization. This was followed by contraction with the rapid increase in strain stress during the first 1 minute and gradually decreased during post-gel shrinkage phase. After 1 minute, there's no statistical differences of strain stress between groups. The highest strain stress was found in group IV and followed by group III, I, II at 10 minutes-measurement(p>.05). In regression analysis of strain stress, group III showed minimal inclination and followed by group II, I, IV during 1 minute. 2. In linear polymerization shrinkage test, the composite resins in every group showed initial increase of shrinkage velocity during the first 1 minute, followed by gradually decrease of shrinkage velocity. After 1 minute, group IV and group III showed statistical difference(p<.05). After 10 minutes, there were statistical differences between group IV and group I, III(p<.05) and between group II and group III(p<.05). In regression analysis of linear polymerization shrinkage, group II showed minimal inclination and followed by group IV, III, I during 1 minute. 3. In compressive strength test, group III showed the highest strength and followed by group II, IV, I. There were statistical differences between group III and group IV, I(p<.05). 4. In microhardness test, upper surfaces showed higher value than lower surfaces in every group(p<.05).
Rubber-toughened particles which are used in the field of chemical engineering are used to increase the fracture toughness of thermoset resin. The application of Core-Shell particles, one of rubber-toughened particles, as a filler for dental composite or restoration have not been examined. The purpose of this study was to evaluate possible use of Core-Shell particles for dental composite, and the hypothesis was that additional toughening mechanisms are activated by the addition of Core-Shell particles. After blending 50vol% quartz with Bis-GMA/TEGDMA resin matrix, the experimental resins were made by the addition of Core-Shell particles with varied content level as 0, 2.5, 5, 7.5, 10, 12.5, 15, and 20wt%. Fracture toughness was determined on three-point bending specimen with single-edge notch according to ASTM-E 399. Also, flexural properties, that is, strength and modulus were measured by three-point bending testing. Fractogragh of fracture toughness specimen was observed using SEM (JEOL 6400 SEM, MA). The following results from this study were obtained ; 1. Fracture toughness of composite resin added 2.5wt% Core-Shell particles was significantly higher than control group ($p{\leq}0.05$). 2. Flexural properties were decreased with increasing Core-Shell particle content, which showed a correlation statistically ($p{\leq}0.05$). 3. A toughening mechanism such as lamination and microcrack was observed in specimen determined high fracture toughness. 4. The dispersion of Core-Shell itself and quartz filler particles was limited present high content of Core-Shell particles, which decreased a resulting mechanical properties of composites. These results suggest that adequate Core-Shell particles can be used to enhance mechanical properties included toughening for dental composites.
The purpose of this study was to search the optimal silane concentrations for filler- silanization of seven experimental composites. Silica filer was a 25micron crushed type. 0.0%, 0.5%, 1.0%, 1.5%, 2.0%, 2.5%, and 3.0% silane($\gamma$-methacrylooxypropyltrimethoxysilane)were added into silica-filler with weight percentage (wt%). Mixtures(silica filler/silane)were reacted at 6$0^{\circ}C$ for 72hours, and crushed into fine particles those were used as fillers for 7 experimental composites. Monomer was a 3 : 1 mixture of Bis-GMA and TEGDMA containing 0.2% tertiary amine and 0.4% camphoroquinone for light curability. A ratio for mixing the monomer and filler was 75% and 25% respectively. Seven experimental composites was classified with the concentration of silane treated, and the specimen number for each test was 10. Specimens with 6mm diameter and 3mm height dimension for measuring the diametral tensile strength were destroyed with 1mm/min cross-head speed on Instron universal testing machine (No. 4467, USA). Shear bond strength was measured on the specimens bonded to bovine enamel etched with 37% phosphoric acid solution for 1 minute Fractured surfaces were observed by SEM (Hitachi S-3200, Japan) among that of the highest values measured from each groups. Following results were obtained: 1. Experimental composites containing silanized filter showed the significantly higher diametral tensile strength and shear bond strength than the composites containing un-silanized fillers(Group1) (p<0.05). 2. In silanized filler composite resins(Group 2~7), Diametral tensile strength of Group 3 showed the significantly higher than that of Group 2 and Group 6(p<0.05). 3. Shear bond strength was higher in Group 3 than that of Group 7 (p<0.05)in silanized fillers composite resins. 4. Fracture surface was formed in resin matrixes on the specimens from composites containing the fillers treated with 0.5% 1.0%, and 1.5% silane. These results mean that the optimal silane concentrations are exist for each fillet with its size and surface area, and that 1.0% is a optimal value for concentration to coat the 25$\mu\textrm{m}$ filler with silane.
Park, Eun-Sook;Bae, Ji-Hyun;Kim, Jong-Soon;Kim, Jae-Hoon;Lee, In-Bog;Kim, Chang-Keun;Son, Ho-Hyun;Cho, Byeong-Hoon
Restorative Dentistry and Endodontics
/
v.34
no.1
/
pp.42-50
/
2009
Deterioration of long-term dentin adhesion durability is thought to occur by hydrolytic degradation within hydrophilic domains of the adhesive and hybrid layers. This study investigated the hypothesis that priming the collagen network with an organic solvent displace water without collapse and thereby obtain good bond strength with an adhesive made of hydrophobic monomers and organic solvents. Three experimental adhesives were prepared by dissolving two hydrophobic monomers, bisphenol-A-glycidylmethacrylate (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA), into acetone, ethanol or methanol. After an etching and rinsing procedure, the adhesives were applied onto either wet dentin surfaces (wet bonding) or dentin surfaces primed with the same solvent (solvent-primed bonding). Microtensile bond strength (MTBS) was measured at 48 hrs, 1 month and after 10,000 times of thermocycles. The bonded interfaces were evaluated using a scanning electron microscope (SEM). Regardless of bonding protocols, well-developed hybrid layers were observed at the bonded interface in most specimens. The highest mean MTBS was observed in the adhesive containing ethanol at 48 hrs. With solvent-primed bonding, increased MTBS tendencies were seen with thermo cycling in the adhesives containing ethanol or methanol. However, in the case of wet bonding, no increase in MTBS was observed with aging.
The purpose of this study is to investigate a possible contribution of nonspecific esterases, which occur in the oral cavity, to the degradation of ester bonds in polymethacrylates. One of the problems connected with the use of composite resins for restorations is their inadequate resistance to wear. It has been shown that methacrylate hydrolysis can be catalyzed by enzymes and that a carboxylic hydrolase (porcine liver esterase) catalyzed the hydrolysis of several mono - and dimethacrylates. The softening effect on a BISGMA/TEGDMA polymer induced by hydrolase will accelerate the in vivo wear of the polymer. Porcine liver esterase (EC 3.1.1.1) 3.2 mol/L $(NH_4)_2$$SO_4$ was obtained from Sigma Chemical Company. The esterase activity of one unit is defined as the amount of enzyme capable of hydrolyzing $l{\mu}mol$ ethyl butyrate per min at pH 8.0 AT $25^{\circ}C$. Phosphate buffer, 10mmol/L, pH 7.0, was made by adjustment of a solution of $Na_2HPO_4$ with $H_3PO_4$. Composite resins used in this study are Silux Plus, Z-100, Durafil VS, and Prisma APH. Cylindrical specimens, 14mm in diameter and 3mm thick, of Silux Plus, Z-100, Durafil VS, Prisma APH were polymerized under the celluloid strip. 60 specimens were divided into 2 groups. One group was emersed only in buffer solution, the other group was emersed in buffer and enzyme solution. Silux Plus and Z-100 were divided into 2 subgroups, one subgroup was cured only Visilux 2. And the other subgroup was cured Visilux 2 and Triaid II. Thereafter, specimens were polished to its best achievable surface according to manufacture's directions. The Vickers hardness of the specimens was measured after 1, 2, 4, 7, 9, 15, 50 days. The solutions were changed after each measurement. Composite resin surfaces were evaluated for the surface roughness with profilometer (${\alpha}$-step 200, Tencor instruments, USA) after 1 and 50 days. And then surfaces of specimens were pictured with stereosopy after 1 and 50 days. The results were as follows. 1. The surface hardness of Silux plus, durafil VS, and Prisma APH were decreased with time. But, the surface hardness of Z-100 was not decreased. 2. The surface hardness of all composite resins was decreased by esterase. 3. Composite resins, which were light-cured by Visilux 2 and concomitantly baked by oven, showed more hardened surface than light-cured by Visilux 2 only. 4. Significant surface changes were occured in Silux plus after esterase treatment.
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