• Title/Summary/Keyword: TDS

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Treatment and Reuse of Acrylic Wastewater using Membrane Separation System

  • Lee, Kwanghyun
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.117-120
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    • 2004
  • The separation characteristics were investigated with the variations of pressure and temperature using ultrafiltration and reverse osmosis membrane module sets composed of different membrane types and materials. TDS, T-N and COD removal efficiencies were not affected and low with the change of temperature and pressure in case of using UF modules contained in module set 1, 2, 3. TDS, T-N and COD removal efficiencies were very high in RO modules. The final water quality of acrylic wastewater was satisfied within the discharge limit value of plant wastewater. It was known that membrane module sets could be used for the reuse of wastewater.

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The removal characteristics of dissolved solid in wastewater during a capacitive deionization process (축전식 탈염공정을 이용한 하수중의 용존염 제거특성 연구)

  • Shin, Kyong-Suk;Yi, Tae-Woo;Cha, Jae-Hwan;Lim, Yoon-Dae;Park, Seung-Kook;Kang, Kyoung-Suk;Song, Eui-Yeol
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.2
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    • pp.151-160
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    • 2014
  • Capacitive deionization(CDI) has many advantages over other desalination technologies due to its low energy consumption, less environmental pollution and relative low fouling potential. The objectives of this study are evaluate the performance of CDI which can be used for dissolved salts removal from sewage. To identify ion selectivity of nitrate and phosphate in multiionic solutions and adsorption/desorption performance related to applied potential, a series of laboratory scale experiments were conducted using a CDI unit cell with activated carbon electrodes. The CDI process was able to achieve more than 75 % TDS and $NO_3{^-}$, $NH_4{^+}$ removals, while phosphate removal was 60.8 % and is inversely related in initial TDS and $HCO_3{^-}$ concentration. In continuous operation, increasing the inner cell pressure and reduction of TDS removal ability were investigated which are caused by inorganic scaling and biofouling. However a relative mild cleaning solution(5 % of citric acid for calcium scaling and 500 mg/L of NaOCl for organic fouling) restored the electrochemical adsorption capacity of the CDI unit to its initial level.

Nitrogen adsorption on the stepped planes of tungsten: II. W(210) and W(310) plane (계단형 텅스텐 결정면의 질소 흡착에 관한 연구: II. W(210) 및 W(310)면)

  • 최대선;한종훈;백선목;박노길;김용욱;황정남
    • Journal of the Korean Vacuum Society
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    • v.5 no.4
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    • pp.301-308
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    • 1996
  • The heat of desorption and the work function change induced by nitrogen adsorption on the slepped tungstein surface plants, W(210) and W(310), are measured using the Field Electron Emission Microscope(FEM). The adsoption sites are predicted from the Thermal Desortion Spectra(TDS). The wirk function change of both W(210) and W(310) planes increase as increasing the nitrogen dose and saturates at the nitrogen dose about 5 Langmuir to 0.29 eV and 0.20 eV respectively. We find three adsorption site on each plane for the low dose range. The TDS result shows that the intensity of $\alpha_1$ state on W(310) is much stronger than that of $\alpha_1$ state on W(210), and the direction of nitrogen dipole moment adsorbed on the sites correspond to $\alpha_1$ and $\beta_2$ state on W(210) and W(310) planes are in the opposite direction to that of the equivalent states on W(100) plane. From this observation we can predict the relative atomic position in the z-direction (perpendicular direction to the surface) of nitrogen molecules/atoms adsorbed on these sites.

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A Study on Jammer Suppression Algorithm for Non-stationary Jamming Environment (재머의 크기가 변하는 환경에서의 억제 알고리즘 연구)

  • Yoon, Ho-Jun;Lee, Kang-In;Chung, Young-Seek
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.2
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    • pp.239-247
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    • 2018
  • Adaptive Beamforming (ABF) algorithm, which is a typical jammer suppression algorithm, guarantees the performance on the assumption that the jamming characteristics of the TDS (Training Data Sample) are stationary, which are obtained immediately before and after transmitting the pulse signal. Therefore, effective jammer suppression can not be expected when the jamming characteristics are non-stationary. In this paper, we propose a new jammer suppression algorithm, of which power spectrum fluctuates fast. In this case, we assume that the location of the jammer station is fixed during the processing time. By applying the MPM (Matrix Pencil Method) to the jamming signal in TDS, we can estimate jammer parameters such as power and incident angle, of which the power will vary fast in time or range bins after TDS. Though we assume that the jammer station is fixed, the estimated jammer's incident angle has an error due to the noise, which degrades the performance of the jammer suppression as the jammer power increases fast. Therefore, the jammer's incident angle should be re-estimated at each range bin after TDS. By using the re-estimated jammer's incident angle, we can construct new covariance matrix under the non-stationary jamming environment. Then, the optimum weight for the jammer suppression is obtained by inversing matrix estimation method based on the matrix projection with the estimated jammer parameters as variables. To verify the performance of the proposed algorithm, the SINR (signal-to-interference plus noise ratio) loss of the proposed algorithm is compared with that of the conventional ABF algorithm.

Total Diet Study: For a Closer-to-real Estimate of Dietary Exposure to Chemical Substances

  • Kim, Cho-il;Lee, Jeeyeon;Kwon, Sungok;Yoon, Hae-Jung
    • Toxicological Research
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    • v.31 no.3
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    • pp.227-240
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    • 2015
  • Recent amendment on the Food Sanitation Act in Korea mandated the Minister of Food & Drug Safety to secure the scientific basis for management and reevaluation of standards and specifications of foods. Especially because the current food safety control is limited within the scope of 'Farm to Market' covering from production to retail in Korea, safety control at the plane of true 'Farm to Fork' scope is urgently needed and should include 'total diet' of population instead of individual food items. Therefore, 'Total Diet Study (TDS)' which provides 'closer-to-real' estimates of exposure to hazardous materials through analysis on table-ready (cooked) samples of foods would be the solution to more comprehensive food safety management, as suggested by World Health Organization and Food and Agriculture Organization of the United Nations. Although the protection of diets from hazards must be considered as one of the most essential public health functions of any country, we may need to revisit the value of foods which has been too much underrated by the meaningless amount of some hazardous materials in Korea. Considering the primary value of foods lies on sustaining life, growth, development, and health promotion of human being, food safety control should be handled not only by the presence or absence of hazardous materials but also by maximizing the value of foods via balancing with the preservation of beneficial components in foods embracing total diet. In this regard, this article aims to provide an overview on TDS by describing procedures involved except chemical analysis which is beyond our scope. Also, details on the ongoing TDS in Korea are provided as an example. Although TDS itself might not be of keen interest for most readers, it is the main user of the safety reference values resulted from toxicological research in the public health perspective.

Estimation of Seawater Intrusion Range in the Daechang Area Using 3D-FEMWATER Model (3D-FEMWATER 모델을 이용한 대창지역의 해수침투 범위추정)

  • Kim Kyoung-Ho;Park Jae-Sung;Lee Ho-Jin;Youn Ju-Heum
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.5
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    • pp.3-13
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    • 2005
  • The present study examined the 3 dimensional space distribution characteristics of sea water intrusion using data available from previous observations. For this study, we used 3D FEMWATER, which is a 3 dimensional finite element model. The target area was around Daechang-ri, Gimje-si, Jeollabuk-do. The area is relatively easy to formulate a conceptual model and has observation wells in operation for surveying sea water intrusion. Considering the uncertainty of numerical simulation, we analyzed sensitivity to hydraulic conductivity, which has a relatively higher effect. According to the result of the analysis, the variation of TDS concentration had an error range of $-1,336{\~}+107 mg/{\iota}$. Taking note that the survey data from observation wells were collected when the boundary between fresh water and sea water in the aquifer was in equilibrium, we set the range of time for numerical simulation and estimated the spatial distribution of TDS concentration as the range of sea water intrusion. According to the result of estimation, the spatial distribution of TDS concentration calculated when 1,440 days were simulated was taken as the range of sea water intrusion. Using the result of calculation, we can draw not only vertical views for a certain section but also horizontal views of different depth. These views will be greatly helpful in understanding the spatial distribution of the range of sea water intrusion. In addition, the result of this study can be used rationally in proposing an optimal quantity of water pumping through investigating the moving route of sea water intrusion over time in order to prevent excessive water pumping and to maintain an optimal number of water pumping wells per interval.

Correlation analysis between Engineering properties and mineralogy of clay sediments in New Busan Port area of the estuary of the Nakdong River (낙동강 유역 신항만부지 지역 점토 퇴적물의 광물조성과 토질특성의 상관성)

  • Lee, Son-Kap;Hwang, Jin-Yun;Chung, Seong-Gyo;Kim, Sung-Wook
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.483-490
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    • 2004
  • Nakdong River Plain and its adjoining sea arc unusually covered by very thick soft clay sediments which were caned Pusan clays, sometimes reaching 40-70m. Since early 1990s a large number of geotechnical investigations have been carried out for land reclamation works in the area, including Busan city and its neighboring cities. Nevertheless, geotechnical engineers have paid little attention to studying geological characteristics on the clays, except some researches related to mineralogy, geo-chemistry, benthic foraminiferal fauna etc. The purpose of reserach is the knowledge of the correlation between engineering properties and mineralogy of clay sediments. The correlation analysis carry out multiple regression that have independent variables (Engineering properties) and dependent variables (mineralogy, geochemistry). Engineering properties of clay are correlated with the mineral compositions and geochemical characteristics. The result of the analysis is Wn = -0,6Feldspar + 1.1pH + 0.01TDS + 27.5, Ip = 0.36Clay + 1.44Vermiculite + 0.94clay mineral - 22.118, PI. = 0.005TDS - 0.31Feldspar + 22.43, eo = 0.02Vermiculite - 0.01Quartz + TDS + 0.93, ${\nu}$t = 0.009Quartz - 0.06Conductivity + 1.67, E50 = 1.94Vermicuhte - 0.96Kaohnite -0.53silt + 49.64, SR = -0.25Kaolinite + 1.5pH -2.3Conductivity, Cc = 0.03pH + TDS -0.2, LL = 0.5Clay + 1.3Vermiculite + 5.5Conductivity + 0.8Caly mineral -20.48

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Application in Ultrafiltration and Reverse Osmosis Module Set with Acrylic Wastewater Pretreated by Coagulation-Filtration-Neutralization Process (응집-여과-중화 공정에 의해 전처리된 아크릴 폐수의 한외여과와 역삼투 모듈 조합 공정에의 적용)

  • Lee, Kwang-Hyun;Kang, Byung-Chul;Lee, Jong-Baek
    • Membrane Journal
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    • v.18 no.1
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    • pp.1-6
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    • 2008
  • After membrane fouling factors in acrylic wastewater were minimized by pretreatment process accompanied with coagulation-filtration-neutralization, it was utilized in UF/RO process. After composing of ultrafiltration and reverse osmosis module set according to types and kinds of membrane, the separation characteristics were examined with the variation temperature and pressure using pretreated acrylic wastewater by membrane module sets. It was found that permeate flux of UF module in module set 4 was about two${\sim}$three times larger than that of UF module in module set 1. Final quantity of permeate from the module set 2 and module set 3 combined with tubular module was shown very good result. It was shown that the removal efficiency of TDS, T-N and COD was very low and was not dependent on the variation of temperature and pressure in all UF modules. The removal efficiency of TDS, T-N and COD was very excellent in RO module. Final water quality of acrylic wastewater was satisfied with effluent allowances limit and membrane module sets were ascertained to reuse wastewater.

A Study on the Photo-Degradation Properties of the Spiropyran Using THz-TDS (테라헤르츠 시간 영역 분광법을 이용한 스피로파이란의 광 퇴화 특성 연구)

  • Bang, Jin-Hyuk;Park, Myoung-Hwan;Ryu, Han-Cheol
    • Journal of the Korean Chemical Society
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    • v.60 no.1
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    • pp.28-33
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    • 2016
  • The spiropyran is a typical material having photodegradation properties in the process of photochromism. The spiropyran has been utilized in various applications such as optical switch, optical memories, and biosensor because of its remarkable stability, fast responsive time, stronger color change, and photo-induced controllability. However, the spriropyran is photodegraded by the repetitive optical irradiation. The photodegradation of spiropyran have been investigated by using UV-Visible spectroscopy, nuclear magnetic resonance (NMR), and Raman spectroscopy. Herein, the properties of spiropyran were characterized by using terahertz time-domain spectroscopy (THz-TDS) in the terahertz frequency region. In terahertz region, the measured absorbance of spiropyran was increased due to the photodegradation induced by the repetitive UV irradiation. The absorbance tendency of spiropyran in the terahertz frequency region was compared with that in the visible region, and they were completely opposite to each other.

Comprehensive Structural Characterization of Commercial Blue Light Emitting Diode by Using High-Angle Annular Dark Filed Scanning Transmission Electron Microscopy and Transmission Electron Microscopy (고각 환형 암시야 주사투과전자현미경기법과 투과전자현미경기법을 이용한 상용 청색 발광다이오드의 종합적인 구조분석)

  • Kim, Dong-Yeob;Hong, Soon-Ku;Chung, Tae-Hoon;Lee, Sang Hern;Baek, Jong Hyeob
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.1-8
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    • 2015
  • This study suggested comprehensive structural characterization methods for the commercial blue light emitting diodes(LEDs). By using the Z-contrast intensity profile of Cs-corrected high-angle annular dark field scanning transmission electron microscope(HAADF-STEM) images from a commercial lateral GaN-based blue light emitting diode, we obtained important structural information on the epilayer structure of the LED, which would have been difficult to obtain by conventional analysis. This method was simple but very powerful to obtain structural and chemical information on epi-structures in a nanometer-scale resolution. One of the examples was that we could determine whether the barrier in the multi-quantum well(MQW) was GaN or InGaN. Plan-view TEM observations were performed from the commercial blue LED to characterize the threading dislocations(TDs) and the related V-pit defects. Each TD observed in the region with the total LED epilayer structure including the MQW showed V-pit defects for almost of TDs independent of the TD types: edge-, screw-, mixed TDs. The total TD density from the region with the total LED epilayer structure including the MQW was about $3.6{\times}10^8cm^{-2}$ with a relative ratio of Edge- : Screw- :Mixed-TD portion as 80%: 7%: 13%. However, in the mesa-etched region without the MQW total TD density was about $2.5{\times}10^8cm^{-2}$ with a relative ratio of Edge- : Screw- :Mixed-TD portion of 86%: 5%: 9 %. The higher TD density in the total LED epilayer structure implied new generation of TDs mostly from the MQW region.