• Title/Summary/Keyword: TCAT

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Study of Aging and Durability on Plasma Polymerized Tire Cords (플라즈마 중합 코팅된 타이어 코드의 노화에 따른 접착력 변화 연구)

  • Kang, H.M.;Yoon, T.H.
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.28-34
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    • 2003
  • Steel tire cords were subjected to plasma polymerization coating of acetylene in order to enhance the adhesion to rubber compounds. Plasma polymerization coating was varied to plasma polymerization coating of acetylene, argon plasma etching+plasma polymerization, or argon plasma. etching+plasma polymerization with Ar carrier gas. Adhesion was evaluated via TCAT samples and compared to those with brass coated tire cord. For durability study, plasma polymer cooled tire cords were aged in lab atmosphere for 1, 3, 5, 10 or 15 days, while TCAT specimens prepared with plasma polymer coated tire cords were aged in distilled water, 10% NaCl solution or $100^{\circ}C$ oven for 1, 2, 3 or 4 weeks. After testing, failure surfaces were analyzed with SEM/EDX. Among the treatments, the highest adhesion was obtained by Ar etching+acetylene plasma. polymerization coating with Ar carrier gas, providing almost same pull-out force as the brass coated tire cords. Upon the aging of the tire cords in the lab atmosphere, brass coated tire cords provided better adhesion than plasma polymer coated tire cords, while the TCAT samples with plasma polymer coated tire cords exhibited similar or slightly superior durability to those with brass coated tire cords.

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Adhesion Properties of Rubber Composite with Direct Blending Technique and Adhesive Composition (직접블렌딩 기술과 접착제 조성이 고무복합체 물성에 미치는 영향)

  • Lee, Seong-Jae;Chang, Young-Wook;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.253-261
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    • 1999
  • The cure properties of rubber compounds containing different adhesive compositions were examined. As the amounts of tannin were increased in the adhesive composition, the scorch time was increased and cure rate was decreased due to the size and shape of tannin molecules. Also, the effect of adhesive composition on the adhesion between rubber and fiber was examined by TCAT(Tire Cord Adhesion Test), The reinforcing cords used in this study were mon ofilaments of nylon 610 and nylon 66. According to the results, the optimum adhesion strength between rubber and fiber could be obtained with adhesives whose molar ratios of formaldehyde/resorcinol were above 5/1 in the recipes. Although the level of dip pick-up(DPU) on the reinforcing cord affects the adhesion strength, the DPU of nylon 610 monofilament did not affect the adhesion strength because the level of DPU was constant regardless of the adhesive compositions. In this case, the adhesion strength with the adhesive composition could be explained with the behavior of tannin in the adhesive.

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Surface Modification of Steel Tire Cords via Plasma Etching and Plasma Polymerization Coating : Part II. Characterization (플라즈마 고분자 코팅에 의한 강철 타이어 코드의 표면 개질 : 제2부. 타이어 코드의 분석)

  • Kang, H.M.;Chung, K.H.;Kaang, S.;Yoon, T.H.
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.63-70
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    • 2000
  • Zinc plated steel tire cords were subjected to RF plasma etching of argon, followed by plasma polymerization coating of acetylene or butadiene in order to enhance adhesion to rubber compounds. Plasma polymerization was carried out under optimized conditions of 10 W, 30 sec, 30 mTorr for acetylene and butadiene gas, while plasma etching was performed at 90W, 10min and 30mTorr. The adhesion of tire cords was evaluated via Tire Cords Adhesion Test (TCAT) and the failure surfaces of the tested samples were analyzed by SEM. Polymer coating by plasma polymerization was also characterized by FT-IR, Alpha-Step and dynamic contact angle analyzer in order to elucidate the adhesion mechanism.

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Surface Modification of Steel Tire Cords via Plasma Etching and Plasma Polymer Coating : Part I. Adhesive properties (플라즈마 고분자 코팅에 의한 강철 타이어 코드의 표면 개질 : 제1부. 타이어 코드의 접착성)

  • Kang, H.M.;Chung, K.H.;Kaang, S.;Yoon, T.H.
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.53-62
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    • 2000
  • Zinc plated steel tire cords were treated with RF plasma polymerization coating of acetylene or butadiene in order to enhance adhesion to rubber compounds. Plasma polymerization was carried out as a function of plasma power, treatment tune and gas pressure. In order to maximize adhesion, argon plasma etching was performed, with carrier gas such as argon, nitrogen and oxygen, while the adhesion of tire cords was evaluated via TCAT. Best results were obtained from a combination treatment of argon etching (90 W. 10 min, 30 mTorr) and acetylene plasma polymerization coating (10 W, 30 sec, 30 mTorr) with argon carrier gas (25/5:acetylene/argon). These samples exhibited a pull out force of 285N which is comparable to that obtained from the brass plated tire cords (290N).

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Enhanced Adhesion of Tire Cords via Plasma Polymerizations (플라즈마 중합에 의한 타이어 코드의 접착성 향상연구)

  • Kim, R.K.;Sohn, B.Y.;Han, M.H.;Kang, H.M.;Yoon, T.H.
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.128-134
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    • 1999
  • Steel tire cords were coated via RF plasma polymerization of acetylene and butadiene gas in order to enhance adhesion to rubber compounds. Adhesion of tire cords was measured by TCAT and T-test as a function of type of gas, plasma powder, treatment time, gas pressure and Ar gas etching. Some samples were subjected to aging study in distilled water at $80^{\circ}C$ for a period of 7 days. After testing, tire cords were analysed by SEM to elucidate the adhesion mechanism. The highest adhesion values were obtained at 20W, 2min and 25mtorr for acetylene plasma polymerization, and l0W, 4min, 25mtorr for butadiene plasma polymerization. However, Ar plasma etching did not affect adhesion, while the adhesion of tire cords increased rather than decreased, contrary to expectations. It was not possible to elucidate failure mode by SEM, owing to the rough surface of the tire and the thin plasma polymer coating layer.

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Existential Psychological approaches about risk and safety (위험과 안전에 대한 실존심리학적 고찰)

  • Soon yeol Lee
    • Korean Journal of Culture and Social Issue
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    • v.22 no.3
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    • pp.387-410
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    • 2016
  • This study conducted a review of the existential and psychological perspective about the risks and safe. The risk was identified as existential task through the existential philosophy and psychology discussed were the safety regulations as existential need. As existential anxiety that is caused by unmet and insufficiency of the existential needs and the existential task that was presented to identify the subjective risk. Subjective risk as existential anxiety, and suggested that serves as a compass to advance to the completion and the facing the existential. In addition, existential anxiety as a subjective function as a signal that can identify the problem conditions that expressed phenomena. Problematic aspect of a subjective risk was suggested that it can be adjusted through a method for supplying information that can be recognized by an experienced and symmetrical state with the direction of the expressed symptoms. The attempt to determine the existence of and psychological point of view, it gave provided the underlying psychological spokesman for the analysis of human society, including the Sewol ferry of Korea-type disaster. There are also presented some implications that can be applied effectively to give more psychological approach to future risk reduction and safety enhancement. In addition, this study through the various views presented by a comprehensive existential subject of several ways to adjust the status Theme conditioning method (Theme Condition Adjustment Theory: TCAT) to establish a theoretical basis for expecting it to be that.

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