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A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.199-207
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    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

Soft computing based mathematical models for improved prediction of rock brittleness index

  • Abiodun I. Lawal;Minju Kim;Sangki Kwon
    • Geomechanics and Engineering
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    • v.33 no.3
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    • pp.279-289
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    • 2023
  • Brittleness index (BI) is an important property of rocks because it is a good index to predict rockburst. Due to its importance, several empirical and soft computing (SC) models have been proposed in the literature based on the punch penetration test (PPT) results. These models are very important as there is no clear-cut experimental means for measuring BI asides the PPT which is very costly and time consuming to perform. This study used a novel Multivariate Adaptive regression spline (MARS), M5P, and white-box ANN to predict the BI of rocks using the available data in the literature for an improved BI prediction. The rock density, uniaxial compressive strength (σc) and tensile strength (σt) were used as the input parameters into the models while the BI was the targeted output. The models were implemented in the MATLAB software. The results of the proposed models were compared with those from existing multilinear regression, linear and nonlinear particle swarm optimization (PSO) and genetic algorithm (GA) based models using similar datasets. The coefficient of determination (R2), adjusted R2 (Adj R2), root-mean squared error (RMSE) and mean absolute percentage error (MAPE) were the indices used for the comparison. The outcomes of the comparison revealed that the proposed ANN and MARS models performed better than the other models with R2 and Adj R2 values above 0.9 and least error values while the M5P gave similar performance to those of the existing models. Weight partitioning method was also used to examine the percentage contribution of model predictors to the predicted BI and tensile strength was found to have the highest influence on the predicted BI.

A Study on Analyzing Sentiments on Movie Reviews by Multi-Level Sentiment Classifier (영화 리뷰 감성분석을 위한 텍스트 마이닝 기반 감성 분류기 구축)

  • Kim, Yuyoung;Song, Min
    • Journal of Intelligence and Information Systems
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    • v.22 no.3
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    • pp.71-89
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    • 2016
  • Sentiment analysis is used for identifying emotions or sentiments embedded in the user generated data such as customer reviews from blogs, social network services, and so on. Various research fields such as computer science and business management can take advantage of this feature to analyze customer-generated opinions. In previous studies, the star rating of a review is regarded as the same as sentiment embedded in the text. However, it does not always correspond to the sentiment polarity. Due to this supposition, previous studies have some limitations in their accuracy. To solve this issue, the present study uses a supervised sentiment classification model to measure a more accurate sentiment polarity. This study aims to propose an advanced sentiment classifier and to discover the correlation between movie reviews and box-office success. The advanced sentiment classifier is based on two supervised machine learning techniques, the Support Vector Machines (SVM) and Feedforward Neural Network (FNN). The sentiment scores of the movie reviews are measured by the sentiment classifier and are analyzed by statistical correlations between movie reviews and box-office success. Movie reviews are collected along with a star-rate. The dataset used in this study consists of 1,258,538 reviews from 175 films gathered from Naver Movie website (movie.naver.com). The results show that the proposed sentiment classifier outperforms Naive Bayes (NB) classifier as its accuracy is about 6% higher than NB. Furthermore, the results indicate that there are positive correlations between the star-rate and the number of audiences, which can be regarded as the box-office success of a movie. The study also shows that there is the mild, positive correlation between the sentiment scores estimated by the classifier and the number of audiences. To verify the applicability of the sentiment scores, an independent sample t-test was conducted. For this, the movies were divided into two groups using the average of sentiment scores. The two groups are significantly different in terms of the star-rated scores.

Model Experiment for Evaluating Internal Erosion Resistance Around Embankment Box-culvert Using Biopolymer T reated Soil (바이오폴리머 혼합토를 활용한 제방 통문 주위 내부침식 저항성 평가를 위한 모형실험)

  • Kim, Minjin;Moon, Junho;Kim, Chanhee;Kim, Younguk
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.12
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    • pp.65-70
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    • 2021
  • River-side Embankment collapse involves various causes. The embankment collapse due to internal erosion around embedded structures reaches up to more than 10% in Korea. Many studies are being attempted to prevent from the collapse of the embankment rooted from overtopping and instability as well as internal erosion. One of them is the study on the application of biopolymers. The application of biopolymers to soils are divided into enhancing strength, vegetation and erosion resistance. This study investigated the effect of biopolymer treated soil on erosion resistance. The main goal of the study is to obtain basic data for real-scale experiments to verify the effectiveness of biopolymer treated soil embankment including a review of the collapse pattern in the model embankment with various test conditions. The optimized experimental conditions were selected by examining the erosion patterns according to each induction path with three compaction degree of the model embankment. As a result of the experiment, the internal erosion rate in the embankment to which the biopolymer treated soil was applied is greatly reduced, and it could be concluded that it might be applied to the actual embankment. However, in this study, the conclusion was drawn only within the scaled-down model embankment. In order to practically apply the biopolymer treated soil to the embankment, the study considering the scale effect would be needed.

Utilization of Demographic Analysis with IMDB User Ratings on the Recommendation of Movies (IMDB 사용자평점에 대한 인구통계학적 분석의 활용)

  • Bae, Sung Moon;Lee, Sang Chun;Park, Jong Hun
    • The Journal of Society for e-Business Studies
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    • v.19 no.3
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    • pp.125-141
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    • 2014
  • Nowadays, overflowing data produced every second from the internet make people to be difficult to search for the useful information. That's why people have invented and developed unique tools that they get some relevant information. In this paper, the recommender system, one of the effective tools, is used and it helps us to get the useful information that we want by using demographic information to predict new items of interest. The demographic recommender system in this paper computes users' similarity using demographic information, age and gender. So we performed demographic analysis on movie ratings on Internet Movie Database (IMDB) web site that movies are rated by thousands of people, where users submitted a movie rating after they watched a recent popular film. Meanwhile, we can understand that user's ratings, among various determinants of box office, is very essential factor in the study on recommendation of movie. This paper is aimed at analyzing movie average ratings directly given by film viewers, categorizing them into groups by sex and age, investigating the entire group and finding the representative group by examining it with F-test and T-test. This result is used to promote and recommend for the target group only. Therefore, this study is considerably significant as presenting utilization for movie business as well as showing how to analyze demographic information on movie ratings on the web.

A Study on the Development of Remotely CP Potential Measuring Method by using Vehicle (차량을 이용한 원격전위 측정방법 개발에 관한 연구)

  • Ryou, Young-Don;Jo, Young-Do;Kim, Jin-Jun;Seo, Min-Sung
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.64-71
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    • 2016
  • According to the urban gas business law, electrical corrosion prevention measures shall be installed to the buried gas pipelines and the pipe-to-soil potentials should be measured at the test box at least once a year. Most of the test boxes installed in urban area are usually located on the road where the vehicle travels, therefore, it is difficult to measure the CP potentials at the test boxes. That is, we need traffic control when carrying out the measurement of the CP potentials on daytime when the traffic is heavy, or we have to measure the potentials in the late night when the traffic is light. To solve these difficulties, we have studied remotely CP potential measuring method by using the patrol car. We have installed solid reference electrodes and data loggers under the test boxes on the site and received the CP potentials from the data loggers when the vehicle moves. It was difficult to send and receive the data because the data logger was located under the ground. We have applied 3 different method including 2 antenna systems to achieve best effective way in receiving the data. We have found the remote CP measuring method by using a car can save more 20 times of measuring time than conventional measuring methods.

The Biomechanical Properties of the Shock Absorption Phase during Drop Landing According to Landing Types (드롭랜딩 시 착지형태에 따른 충격흡수구간의 운동역학적 특성)

  • Park, Gu-Tae;Yoo, Kyoung-Seok
    • Korean Journal of Applied Biomechanics
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    • v.25 no.1
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    • pp.29-37
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    • 2015
  • Objective : The purpose of this study was to investigate the biomechanical properties of shock absorption strategy and postural stability during the drop landing for each types. Methods : The motions were captured with Vicon Motion Capture System, with the fourteen infra-red cameras (100Hz) and synchronized with GRF(ground reaction force) data(1000Hz). Ten male soccer players performed a drop landing with single-leg and bi-legs on the 30cm height box. Dependent variables were the CoM trajectory and the Joint Moment. Statistical computations were performed using the paired t-test and ANOVA with Turkey HSD as post-hoc. Results : The dominant leg was confirmed to show a significant difference between the left leg and right leg as the inverted pendulum model during Drop Landing(Phase 1 & Phase 2). One-leg drop landing type had the higher CoM displacement, the peak of joint moment with the shock absorption than Bi-leg landing type. As a lower extremity joint kinetics analysis, the knee joint showed a function of shock absorption in the anterior-posterior, and the hip joint showed a function of the stability and shock absorption in the medial-lateral directions. Conclusion : These findings indicate that the instant equilibrium of posture balance(phase 1) was assessed by the passive phase as Class 1 leverage on the effect of the stability of shock absorption(phase 2) assessed by the active phase on the effect of Class 2 leverage. Application : This study shows that the cause of musculo-skeletal injuries estimated to be focused on the passive phase of landing and this findings could help the prevention of lower damage from loads involving landing related to the game of sports.

Analysis of the Differences of the Shock Attenuation Strategy between Double-leg and Single-leg Landing on Sagittal Plane using Statistical Parametric Mapping (Statistical Parametric Mapping을 이용한 시상면에서의 양발 착지와 외발 착지의 전략 차이)

  • Ha, Sunghe;Park, Sang-Kyoon;Lee, Sae Yong
    • Korean Journal of Applied Biomechanics
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    • v.29 no.4
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    • pp.255-261
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    • 2019
  • Objective: The purpose of this study was to investigate differences of shock attenuation strategies between double-leg and single-leg landing on sagittal plane using statistical parametric mapping. Method: Nine healthy female professional soccer players (age: 24.0±2.5 yrs, height: 164.9±3.3 cm, weight: 55.7±6.6 kg, career: 11.2±1.4 yrs) were participated in this study. The subjects performed 10 times of double-leg and single-leg landing from the box of 30 cm height onto force plates respectively. The ground reaction force, angle, moment, angular velocity, and power of the ankle, knee, and hip joint on sagittal plane was calculated from initial contact to maximum knee flexion during landing phase. Statistical parametric mapping was used to compare the biomechanical variables of double-leg and single-leg landing of the dominant leg throughout the landing phase. Each mean difference of variables was analyzed using a paired t-test and alpha level was set to 0.05. Results: For the biomechanical variables, significantly increased vertical ground reaction force, plantarflexion moment of the ankle joint, negative ankle joint power and extension moment of the hip joint were found in single-leg landing compared to double-leg landing (p<.05). In addition, the flexion angle and angular velocity of the knee and hip joint in double-leg landing were observed significantly greater than single-leg landing, respectively (p<.05). Conclusion: These findings suggested that negative joint power and plantarflexion moment of the ankle joint can contribute to shock absorption during single-leg landing and may be the factors for preventing the musculoskeletal injuries of the lower extremity by an external force.

Polylactic Acid Coating Affects the Ring Crush Strength of Linerboards

  • Lee, Jun-Ho;Rhim, Jong-Whan
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.54-59
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    • 2006
  • Paperboards used for linerboard of corrugated fiberboard box were coated with different concentrations of polylactic acid (PLA) solution and the effects of harsh environmental conditions such as high humidity and temperature (96% RH at $30^{\circ}C$ for up to 5 days), and freeze-thaw ($-20^{\circ}C$ for a day and then thaw at room temperature for 30 min) conditions on the ring crush (RC) strength of the boards were investigated. One to five percent PLA solutions were coated onto SC manila linerboard ($20{\times}27cm$) using a No. 20 wire bar coater and the ring crush strength was measured using a computer-controlled Advanced Universal Testing System in accordance with TAPPI Test Method T 822 om-93. The RC strength increased significantly when the concentration of coating solution increased and appreciable changes were found when the concentration increased from 0 to 2% (P<0.05). Similar pattern of results was found after 5-day storage at $30^{\circ}C$ and 96% RH. Although such highly humid condition increased moisture content in the samples up to 3.95 from 0.97 times, the RC strength decreased in the range from 29.9 to 48.5%. The freeze-thaw treatment increased the moisture content only up to 1.27% and the reduction in the RC strength ranged from 21.1 to 28.1 %. The results were promising: the samples coated with 5% PLA solution showed 29.9% reduction in the RC strength while that of control was 48.5% during highly humid condition stated above.

The Study of Long-Term Performance Evaluation of Vacuum Insulation Panel(VIP) with Accelerated Aging Test (가속노화 시험을 통한 진공단열패널(VIP)의 장기성능 평가 연구)

  • Kim, Jin-Hee;Kim, Jun-Tae
    • Journal of the Korean Solar Energy Society
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    • v.37 no.4
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    • pp.35-47
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    • 2017
  • Energy efficiency solutions are being pursued as a sustainable approach to reducing energy consumption and related gas emissions across various sectors of the economy. Vacuum Insulation Panel (VIP) is an energy efficient advanced insulation system that facilitates slim but high-performance insulation, based on a porous core material evacuated and encapsulated in a barrier envelope. Although VIP has been applied in buildings for over a decade, it wasn't until recently that efforts have been initiated to propose and adopt a global standard on characterization and testing of VIP. One of the issues regarding VIP is its durability and aging due to pressure and moisture dependent increase of the initial low thermal conductivity with time; more so in building applications. In this paper, the aging of commercially available VIP was investigated experimentally; thermal conductivity was tested in accordance with ISO 8302 standard (guarded hot box method) and long-term durability was estimated based on a non-linear pressure-humidity dependent equation based on study of IEA/ECBCS Annex 39, with the aim of assessing durability of VIP for use in buildings. The center-of-panel thermal conductivity after 25 years based on initial 90% fractile with a confidence level of 90 % for the thermal conductivity (${\lambda}90/90$) ranged from 0.00726-0.00814 (W/m K) for silica core VIP. Significant differences between manufacturer-provided data and measurements of thermal conductivity and internal pressure were observed.