Zinc, cadmium, lead and copper were simultaneously determined by depositing metals at - 1.200 V vs. a Ag/AgCl(sat. KCl) reference electrode for 150 seconds on a hanging mercury drop electrode(HMDE) or a thin mercury film electrode(TMFE), followed by scanning towards anodic direction using differential pulse voltammetric(DPASV) and square wave voltammetric(SWASV) techniques. The linear calibration curves were obtained for four metal ions simultaneously determined by DPASV with a HMDE in the concentration range between 20 and 100 ppb. However, the linear calibration plots were obtained only for $Cd^{2+}$ and $Pb^{2+}$ in the simultaneous determinations with a TMFE in the concentration range up to 100 ppb using DPASV and up to 10 ppb using SWASV. DPASV with a TMFE was about 15 times more sensitive than DPASV with a HMDE for simultaneous determinations of $Cd^{2+}$ and $Pb^{2+}$. SWASV was about 5 times more sensitive than DPASV at a TMFE. Concentrations of zinc in seven different sediment samples determined by DPASV with a HMDE and inductively coupled plasma-mass spectrometry were compared, resulting with an excellent correlation coefficient of 0.9993 and with no significant difference between two methods after t-test.
Park, Eun Ju;Kim, In Seok;Park, Sang Seok;Lee, Ho Sang;Lee, Moo Sung
Polymer(Korea)
/
v.37
no.6
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pp.744-752
/
2013
The miscibility between poly(L-lactide) (PLLA) and poly(methyl methacrylate) (PMMA) was investigated using thermal analyses for the purpose of developing birefringence-free material at oriented state. The effect of methyl acrylate (MA) units as comonomer of PMMA on the miscibility was also studied. All the blends prepared in this study show composition-dependent single $T_g$'s between those of blend components and high transparency over the visible region, indicating the miscibility at molecular level and no discernible effect of MA units on it. No phase separation was observed at elevated temperature of $280^{\circ}C$, higher than the degradation of PLLA and PMMA. The interaction energy density in PLLA/PMMA blends with 17 mol% of MA was measured to be $-0.74J/cm^3$ from the equilibrium melting temperature depression based on the Hoffman-Weeks method. The blends show zero-${\Delta}$n behavior at a specific mixing ratio and the drawing ratio of 3 due to compensation of intrinsic orientation birefringence. Birefringence dispersion of PLLA/PMMA5 blends was also measured to examine the possibility for quarter-wave plates or polarizer protective films.
Pool boiling of dilute aqueous solutions of polyethylene oxide polymer has been experimentally investigated for the purpose of understanding the physical mechanisms of the suppression of vapor explosions in this polymer solution. Tn solid spheres of 22.2mm and 9.5mm-diameter ore heat-ed and quenched in the polymer solutions of various concentrations at 3$0^{\circ}C$. The results showed that minimum film boiling temperature($\Delta$$T_{MFB}$) in this highly-subcooled liquid rapidly decreased from over $700^{\circ}C$ for pure water to about 15$0^{\circ}C$ as the polymer concentration was increased up to 300ppm for 22.2mm sphere, and it decreased to 35$0^{\circ}C$ for 9.5mm sphere. This large decrease of minimum film boiling temperature in this aqueous polymer solution may explain its ability to suppress spontaneous vapor explosions. Also, tests with applying a pressure wave showed that the vapor film behaved more stable against an external disturbance at higher polymer concentrations. These observations together with the experimental evidences of vapor explosion suppression in dilute polymer solutions suggest that the application of polymeric additives such as polyethylene oxide as low as 300ppm to reactor emergency coolant be considered to prevent or mitigate energetic fuel-coolant interactions during severe reactor accidents.s.
Background: In the patients with thoracic injury, we suspect simultaneous cardiac contusion or concussion. We analyzed the patients with possible cardiac injury by electrocardiography, serum creatine kinase (CK), creatine kinase isoenzyme fraction (CK-MB) screening, followed by two dimentional echocardiogram (2-DE) to access the severity of injury. Material and Method: From January 1997 to April 1998, 15-month retrospective study of suspicious myocardial injury was undertaken in including 24 patients admitted for suspected cardiac injury. All patients with history or signs of blunt chest injury were checked serially and the serial CK, CK-MB fraction, electrocardiography (EKG) analysis screening were followed by 2-DE. Result: The age range was between 20-40 years and were predominant male patients in(M:F=3:1). Most common causes of injury were traffic accidents, 15 patients(62.5%). Associated injuries involved multiple rib fractures, sternal fracture and such. EKG findings on the cardiac concussion were within normal limits, EKG findings on the cardiac contusion were nonspecific ST and T wave abnormality. In cardiac contusion patients, CK-MB fraction did not increase significantly on admission but on 2nd, 3rd, 4th hospital days, it increased significantly (p=0.0080, 0.0130, 0.0130). The average admission days were 9.22 in concussion and 26.18 in contusion patients(p=0.0075). Most common complication was the adult respiratory distress syndrome(7 cases), 5 out of the patients with ARDS were mechanically ventilated. There were no deaths. Conclusion: We believe the serial checks of CK-MB, EKG and subsquent two-dementional echocardiographic sector scanning are presently the most sensitive indicators available for structural and functional cardiac injury.
In KORDI (Korea Ocean Research and Development Institute), the KOSC (Korea Ocean Satellite Center) construction project is being prepared for acquisition, processing and distribution of sensor data via L-band from GOCI (Geostationary Ocean Color Imager) instrument which is loaded on COMS (Communication, Ocean and Meteorological Satellite); it will be launched in 2008. Ansan (the headquarter of KORDI) has been selected for the location of KOSC between 5 proposed sites, because it has the best condition to receive radio wave. The data acquisition system is classified into antenna and RF. Antenna is designed to be $\phi$ 9m cassegrain antenna which has 19.35 G/T$(dB/^{\circ}K)$ at 1.67GHz. RF module is divided into LNA (low noise amplifier) and down converter, those are designed to send only horizontal polarization to modem. The existing building is re-designed and arranged for the KOSC operation concept; computing room, board of electricity, data processing room, operation room. Hardware and network facilities have been designed to adapt for efficiency of each functions. The distribution system which is one of the most important systems will be constructed mainly on the internet. and it is also being considered constructing outer data distribution system as a web hosting service for offering received data to user less than an hour.
The purpose of this research is to identify the longitudinal reciprocal relationship between family social capital and self-esteem of adolescents. Five waves of panel data from the Korea Youth Panel Survey were employed for this research. Korean Adolescents Policy Research Institute collected the first wave data in 2004 from elementary school children in 4th grade. Autoregressive cross-lagged modeling was performed to analysis the longitudinal reciprocal relationship between family social capital and self-esteem. The major findings were as follows. First, stability coefficient of family social capital and self-esteem showed that both variables were significantly stable over time. Secondly family social capital(t) had statistically significant effect on self-esteem(t+1), whereas self-esteem did not predict family social capital at a statistically significant level. These findings suggest that family social capital and self-esteem is stable overtime, and that obtaining family social capital and establishing positive self-esteem is important during this period in childhood. In addition, the results show that family social capital affects self-esteem, which highlights the importance of family social capital accumulation on the development of adolescent self-esteem.
Journal of the Korean Society of Hazard Mitigation
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v.11
no.3
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pp.219-228
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2011
In this paper, the design procedure of substructure of the steel-type breakwater was described and the actual foundation design was performed for the test bed. The site investigation was executed at the Osan-port area, in Uljin, Gyeongbuk, where the steeltype detached breakwater is constructed. The foundation mainly depends on the lateral load and uplift force due to the wave force. Since the superstructure is stuck out about 9.0m from the ocean bed, the foundation must resist on the lateral force and bending moment. After considering various factors, the foundation type of this structure was determined by the steel pipe pile(${\varphi}711{\times}t12mm$). On the stability of pile foundation, the safety factors of the pile on the compressive, lateral and uplift forces were grater than the minimum factor of safety. The displacements of pile under the working load were evaluated as the values below the permissible ones. Based on the subgrade reaction method, we evaluated the relationship of subgrade reaction and displacement for the lateral and the vertical directions in the layers. The structural analyses along with the foundation were perfomed and the effect of pile foundations were compared quantitatively.
Journal of the Korean Society of Marine Environment & Safety
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v.25
no.4
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pp.433-440
/
2019
Offshore working environments such as ships, offshore oil and gas plants, and offshore wind turbines are isolated and directly exposed to rough seas, which pose high risks of safety accidents. Therefore, all workers in offshore plants should be able to cope with emergency situations and must be qualified according to relevant laws and regulations such as the International Convention on Standards of Training, Certification and Watchkeeping for Seafarers (STCW Convention) and Offshore Petroleum Industry Training Organization (OPITO) standards. In particular, marine workers should be able to perform cardiopulmonary resuscitation (CPR) in isolated locations or enclosed and confined spaces such as those in life-boats, life-rafts, rescue-boats, etc. Because the floor material is made of rubber, it may be difficult to perform chest compressions in life-rafts used to escape from emergency situations in ships or offshore plants. Chest compressions performed on life-rafts may reduce the accuracy of CPR and increase fatigue for those providing aid. To measure the accuracy and fatigue of those performing CPR in life-rafts, 15 experimenters with more than five years of experience as first aid instructors were exposed to different CPR environments in a marine safety training center equipped with an artificial wave generator. The results showed that the accuracy of CPR in the classroom was 99.6 %, but that in various life-raft environments was only 84 %. T-verification of the two sites confirmed the reduced accuracy of CPR performed on life-rafts. CPR on life-rafts should be performed in groups of two and with the use of automated chest compression devices.
The study looked at the effect of body food on stress reduction and NK cell activity in improving natural healing for nurses, and examined whether it is effective in preventing and curing human health. The study was conducted for 30 days on 22 nurses who currently worked for more than a year at a general hospital in Gyeonggi Province. Stress measurements were conducted through pulse wave measuring instrument, and blood tests were conducted on the activity of NK cells. Treatment of collected data was performed by Paired t-testing through the Stat program SPSS 21 and providing body food suitable for the physical quality of participants after the classification of the body based on the internal diameter of the emperor and scholarship. Studies have shown that the effect on reducing the stress of body food has significant positive effects and that body food is effective for the activity of NK cells. This study has the following significance: First, the main health threat factor for modern people is the increased resistance of natural healing through body food to stress, which has the potential to prevent disease. Second, immunodeficiency in disease prevention and treatment is very important, which can increase the natural healing power of the human body by increasing the activity of NK cells through body food.
Journal of the Korean Institute of Landscape Architecture
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v.45
no.6
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pp.115-125
/
2017
This study was to investigate the user's thermal environments under the pergola($L\;7,200{\times}W\;4,200{\times}H\;2,700mn$) covered with Wisteria floribunda(Willd.) DC. according to the variation of leaf area index(LAI). We carried out detailed measurements with two human-biometeorological stations on a popular square Jinju, Korea($N35^{\circ}10^{\prime}59.8^{{\prime}{\prime}}$, $E\;128^{\circ}05^{\prime}32.0^{{\prime}{\prime}}$, elevation: 38m). One of the stations stood under a pergola, while the other in the sun. The measurement spots were instrumented with microclimate monitoring stations to continuously measure air temperature and relative humidity, wind speed, shortwave and longwave radiation from the six cardinal directions at the height of 0.6m so as to calculate the Universal Thermal Climate Index(UTCI) from $9^{th}$ April to $27^{th}$ September 2017. The LAI was measured using the LAI-2200C Plant Canopy Analyzer. The analysis results of 18 day's 1 minute term human-biometeorological data absorbed by a man in sitting position from 10am to 4pm showed the following. During the whole observation period, daily average air temperatures under the pergola were respectively $0.7{\sim}2.3^{\circ}C$ lower compared with those in the sun, daily average wind speed and relative humidity under the pergola were respectively 0.17~0.38m/s and 0.4~3.1% higher compared with those in the sun. There was significant relationship in LAI, Julian day number and were expressed in the equation $y=-0.0004x^2+0.1719x-11.765(R^2=0.9897)$. The average $T_{mrt}$ under the pergola were $11.9{\sim}25.4^{\circ}C$ lower and maximum ${\Delta}T_{mrt}$ under the pergola were $24.1{\sim}30.2^{\circ}C$ when compared with those in the sun. There was significant relationship in LAI, reduction ratio(%) of daily average $T_{mrt}$ compared with those in the sun and was expressed in the equation $y=0.0678{\ln}(x)+0.3036(R^2=0.9454)$. The average UTCI under the pergola were $4.1{\sim}8.3^{\circ}C$ lower and maximum ${\Delta}UTCI$ under the pergola were $7.8{\sim}10.2^{\circ}C$ when compared with those in the sun. There was significant relationship in LAI, reduction ratio(%) of daily average UTCI compared with those in the sun and were expressed in the equation $y=0.0322{\ln}(x)+0.1538(R^2=0.8946)$. The shading by the pergola covered with vines was very effective for reducing daytime UTCI absorbed by a man in sitting position at summer largely through a reduction in mean radiant temperature from sun protection, lowering thermal stress from very strong(UTCI >$38^{\circ}C$) and strong(UTCI >$32^{\circ}C$) down to strong(UTCI >$32^{\circ}C$) and moderate(UTCI >$26^{\circ}C$). Therefore the pergola covered with vines used for shading outdoor spaces is essential to mitigate heat stress and can create better human thermal comfort especially in cities during summer. But the thermal environments under the pergola covered with vines during the heat wave supposed to user "very strong heat stress(UTCI>$38^{\circ}C$)". Therefore users must restrain themselves from outdoor activities during the heat waves.
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