• Journal of the Korean Applied Science and Technology
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• v.27 no.4
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• pp.522-530
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• 2010

We developed functional synthetic lubricant for internal combustion engine oil, which would improve engine oil performance for internal combustion engine and extend engine life. We made base oil by synthesizing nonanoic acid, 1.1.1-trimethylol propane (which has good bio-degradability) and pentaerythrytol ester. We synthesized catalyst using p-toluene sulfonic acid 0.15 wt% and coloring-prevention agent hypo-phosphorus acid 0.18 wt% at 180-$190^{\circ}C$. Reaction temperature was increased at the rate of $10^{\circ}C$ for every 1 hour. When acid value reached below 3, reaction was completed. After cooling and deoxidization, we washed it by distilled water two times. After dehydration and filtering, we obtained trimethylol propane tripelargonate (TMTP) and pentaerythrytol tetrapelargonate (PETP) at yields of 96 % and 98 % respectively.

• Journal of the Korean Chemical Society
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• v.59 no.3
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• pp.225-232
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• 2015

A liquid chromatography-electrospray ionization-tandem mass spectrometry method (LC-ESI-MS/MS) was used for determining seven pesticides (2,4-dichlorophenoxyacetic acid, methomyl, aldicarb, 2-methyl- 4-chlorophenoxy- acetic acid, molinate, carbaryl and carbofuran) and two synthetic materials (quinoline and bisphenol-A) in surface water. The analytes were extracted using solid-phase extraction (SPE). The eluate was concentrated by nitrogen gas. 100 microliters of 30% (v/v) methanol aqueous solution were used to dissolve the residue and an aliquot of the reconstituted solution was directly injected into LC-ESI-MS/MS after the filtration using 0.2 μm polytetrafluoroethylene (PTFE) syringe filter. Under the established condition, the calibration curves of the analytes were linear with correlation coefficients of above 0.997. The quantification limit was 0.002~0.011 μg/L and the relative standard deviations were less than 16.4%. In addition, accuracy was in the range of 84~107% and the recoveries were values between 56.2 and 98.6%. In this study, the developed method was applied to the analysis of real surface water samples.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.13 no.1
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• pp.57-68
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• 2010

The purpose of this study is to analyze the characteristics of environment-friendliness of waterproof materials based on comprehensive experiments on waterproofness in terms of coefficients of permeability, harmfulness of waterproof materials and fish toxicity of Oryzias latipes mortality to verify eco-toxicity of each method of construction and waterproof material, which are to be applied by taking eco-toxicity into account when building ecological flows in upper areas on natural and artificial grounds. As a result, the following conclusions have been reached in this study: 1. In regard of the harmfulness analyzed, each material showed a different result of analytical value in each lab tank. Compared to input water, pH, COD, SS, T-P, and T-N values increased a little, but DO value decreased. The value of turbidity analyzed independent of the water quality standard of aquatic ecosystem set forth by the Ministry of Environment increased a little compared to the value in input water. 2. In the experiment of fish toxicity, compacted quicklime, cement fluid waterproof material, cement mortar waterproof material and bentonite powder were found to have 100% of fish mortality, respectively, and membrane waterproof material showed 83.3% of mortality, indicating strong fish toxicity. Improved asphalt sheet (63.3%) and synthetic rubber sheet (53.3%) were analyzed to have medium fish toxicity, while bentonite sheet (6.7%), Hwang-toh (6.7%) and clay (3.3%) showed relatively lower mortality and fish toxicity. 3. Regarding the analysis on waterproofness in terms of the coefficient of permeability of each waterproof material, improved asphalt sheet, synthetic rubber sheet, membrane waterproof material, cement fluid and mortar waterproof material and bentonite sheet were found impervious in case no leakage takes place in construction. Bentonite powder was found practically impervious based on the analytical results from the experiment done in compliance with weight ratios. So were the clay and Hwang-toh from the experimental results. To sum up such results as found in the experiment mentioned so far, the values of harmfulness and waterproofness analyzed were different in each lab tank, but there was absolutely little correlation with the mortality gained from the experiment on fish toxicity. In the experiment of fish toxicity, environment-friendly waterproof materials were analyzed, and it was found that clay, Hwang-toh and bentonite sheet are highly environment-friendly. In contrast, synthetic rubber and improved asphalt sheets were found to have medium-level environment-friendliness. Also, membrane water-proof materials, compacted quicklime, cement fluid and mortar waterproof material and bentonite powder were analyzed to have low environment-friendliness.

• Journal of Korea Water Resources Association
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• v.51 no.12
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• pp.1181-1194
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• 2018

This study suggests a novel approach of estimating stream flow discharge using the Synthetic Aperture Radar (SAR) images taken from 2015 to 2017 by European Space Agency Sentinel-1 satellite. Fifteen small to medium sized rivers in the Han River basin were selected as study area, and the SAR satellite images and flow data from water level and flow observation system operated by the Korea Institute of Hydrological Survey were used for model construction. First, we apply the histogram matching technique to 12 SAR images that have undergone various preprocessing processes for error correction to make the brightness distribution of the images the same. Then, the flow estimation model was constructed by deriving the relationship between the area of the stream water body extracted using the threshold classification method and the in-situ flow data. As a result, we could construct a power function type flow estimation model at the fourteen study areas except for one station. The minimum, the mean, and the maximum coefficient of determination ($R^2$) of the models of at fourteen study areas were 0.30, 0.80, and 0.99, respectively.

• Magazine of the Korean Society of Agricultural Engineers
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• v.31 no.4
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• pp.31-49
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• 1989

It is of the most urgent necessity to get hydrological time series of long duration for the establishment of rational design and operation criterion for the Agricultural hydraulic structures. This study was conducted to select best fitted frequency distribution for the monthly runoff and to simulate long series of generated flows by multi-season first order Markov model with comparison of statistical parameters which are derivated from observed and sy- nthetic flows in the five watersheds along Geum river basin. The results summarized through this study are as follows. 1. Both two parameter gamma and two parameter lognormal distribution were judged to be as good fitted distributions for monthly discharge by Kolmogorov-Smirnov method for goodness of fit test in all watersheds. 2. Statistical parameters were obtained from synthetic flows simulated by two parameter gamma distribution were closer to the results from observed flows than those of two para- meter lognormal distribution in all watersheds. 3. In general, fluctuation for the coefficient of variation based on two parameter gamma distribution was shown as more good agreement with the observed flow than that of two parameter lognormal distribution. Especially, coefficient of variation based on two parameter lognormal distribution was quite closer to that of observed flow during June and August in all years. 4. Monthly synthetic flows based on two parameter gamma distribution are considered to give more reasonably good results than those of two parameter lognormal distribution in the multi-season first order Markov model in all watersheds. 5. Synthetic monthly flows with 100 years for eack watershed were sjmulated by multi- season first order Markov model based on two parameter gamma distribution which is ack- nowledged to fit the actual distribution of monthly discharges of watersheds. Simulated sy- nthetic monthly flows may be considered to be contributed to the long series of discharges as an input data for the development of water resources. 6. It is to be desired that generation technique of synthetic flow in this study would be compared with other simulation techniques for the objective time series.

• Journal of the Korea Institute of Building Construction
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• v.10 no.2
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• pp.105-113
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• 2010

Method or work type improvement is needed in relation to reducing cost and increasing efficiency by ensuring construction quality and reducing labor in the form work process. This would have a great influence on the entire construction process, and make the process of adopting materials and methods more rational and economic. Hence, this study aimed to develop a Synthetic Resins Euroform that could improve durability, water-proofing, sophistication, and organizational unity through the use of injection modeling. Accordingly, this paper first investigated various performance requirements and necessary techniques, and then verified feasibility by evaluating the physical safety and technical validity when it is applied to construction field. In addition, this study evaluated the constructability, safety performance, environmental performance, and systemic excellence in terms of maintaining convenience of Synthetic Resins Euroform. Moreover, to verify feasibility in the construction field, this study analyzed and evaluated the maximum stress by measuring the load and deformation of the space of the horizontal furring, which is attached to Euroform as an armature.

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.564-568
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• 1993

By measuring the COD (chemical oxygen demend) of dish washing detergents being sold at market and pollutants connected with domestic sewage, we compared the amounts of water pollutants of one with other and carried out the experiments of ultimate biodegradation as against these samples. Also we combined our experimental results and circumstances of water pollution and wastewater treatments to the sewage system, compared the effects of synthetic detergent on water pollution with soap and the other pollutants and investigated results of our research.

• Journal of Korean Society on Water Environment
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• v.16 no.4
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• pp.533-539
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• 2000

A bench-scale reactor using SBR process was experimented with an synthetic wastewater. The main purpose of this investigation was to evaluate applicability in the field and process removal efficiencies in terms of BOD and T-P and its corresponding kinetic parameters. Removal rate of phosphorus was 77% in terms of total phosphorus. Effluent concentrations were $9.8mg/{\ell}$ BOD and $1.1mg/{\ell}$ T-P. Effluent quality was maintained consistently stable by controlling decant volume and operating cycles. The efficiency for phosphorus removal was increased due to decrease in BOD-SS loading value in the range of $0.25{\leq}$aeration time ratio${\leq}0.52$.

• Journal of the Korean institute of surface engineering
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• v.36 no.2
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• pp.194-199
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• 2003

Polarization measurements were peformed to investigate the electrochemical behavior of copper ions and limiting current density in waste rinse water from copper electroplating processes. A newly designed cyclone type electrolyzer was tested to recover the copper powder. Synthetic solutions were prepared using analytical grade $CuSO_4$ to the desired waste water concentration and pH was adjusted with $H_2$$SO_4$. Electrowinning was peformed at room temperature and the solution was cycled with a pump. Results showed that more than 99 percent of Cu was recovered and the size of the recovered Cu powder ranges from 0.1 - $0.5\mu\textrm{m}$. The chemical composition of the Cu powder mainly consists of $Cu_2$O and Cu and can be easily reduced to pure Cu powder.

• Journal of Korean Society of Water and Wastewater
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• v.9 no.3
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• pp.78-87
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• 1995

A study on the fouling control by periodical ozone-scrubbing was conducted in a membrane filtration process for drinking water treatment. Hydrophilic hollow fiber polyethylene membrane with pore size of $0.1{\mu}m$ and its surface area of $0.42m^2$ was used. Dead-End filtration method was selected to obtain high efficiency of energy. Laboratory prepared synthetic raw water with kaolin was used and the membranes were scrubbed by ozone once in an hour and once in two hours. When the duration of ozone scrubbing was increased from 10 seconds to 20 seconds, the rate of membrane fouling was significantly decreased. Although the frequency of ozone-scrubbing was reduced from once in an hour to once in two hours. the effect of fouling control was unchanged. However, ozone-scrubbing was not effective after a membrane was fouled and washed with detergent for reuse. Among several possible working effects of ozone, bactericidal effect was confirmed to be the primary reason of fouling control.