• Title/Summary/Keyword: Synthetic method

Search Result 2,123, Processing Time 0.029 seconds

Application and Improvement Plan of the Comprehensive Assessment for River Environments - Focusing on Tributary Streams of the Han River in Seoul - (하천환경종합평가의 적용 및 개선방안 - 서울시 한강 지류하천을 중심으로 -)

  • Ahn, Hong-Kyu;Lee, Sang-Hoon
    • Journal of Environmental Impact Assessment
    • /
    • v.29 no.6
    • /
    • pp.441-452
    • /
    • 2020
  • The assessment of the river environment is widely applied as a method to establish the purpose and direction of river rehabilitation projects. This includes surveying and assessing the current state of the river environment and determining whether a previous river project was properly executed. The city of Seoul executed ecological river rehabilitation activities for the tributaries of the Han River from the 2000s following a masterplan to recover the physical shape and ecological functionality of damaged rivers. After the rehabilitation activities, the river environment had been changed substantially. In this study, physical properties, water quality properties, and ecological properties were assessed for 28 tributaries underthe control of the city of Seoul, and then those 3 properties were synthetically reassessed. From the result of the study on the physical properties, it was found that mostrivers had II-III grades. As for water quality properties, rivers had III-IV grades. The damaged rivers showed low grades of D-E based on the Aquatic Ecosystem Health evaluation. Accordingly, we concluded that all rivers of Seoul City have an unhealthy environment in terms of water quality and Aquatic Ecosystem Health, therefore it is regarded that long-term and systematic improvements are required.

Early Estimation of Rice Cultivation in Gimje-si Using Sentinel-1 and UAV Imagery (Sentinel-1 및 UAV 영상을 활용한 김제시 벼 재배 조기 추정)

  • Lee, Kyung-do;Kim, Sook-gyeong;Ahn, Ho-yong;So, Kyu-ho;Na, Sang-il
    • Korean Journal of Remote Sensing
    • /
    • v.37 no.3
    • /
    • pp.503-514
    • /
    • 2021
  • Rice production with adequate level of area is important for decision making of rice supply and demand policy. It is essential to grasp rice cultivation areas in advance for estimating rice production of the year. This study was carried out to classify paddy rice cultivation in Gimje-si using sentinel-1 SAR (synthetic aperture radar) and UAV imagery in early July. Time-series Sentinel-1A and 1B images acquired from early May to early July were processed to convert into sigma naught (dB) images using SNAP (SeNtinel application platform, Version 8.0) toolbox provided by European Space Agency. Farm map and parcel map, which are spatial data of vector polygon, were used to stratify paddy field population for classifying rice paddy cultivation. To distinguish paddy rice from other crops grown in the paddy fields, we used the decision tree method using threshold levels and random forest model. Random forest model, trained by mainly rice cultivation area and rice and soybean cultivation area in UAV image area, showed the best performance as overall accuracy 89.9%, Kappa coefficient 0.774. Through this, we were able to confirm the possibility of early estimation of rice cultivation area in Gimje-si using UAV image.

Assessment of Soil Stabilization forthe Reduction of Environmental Risk of Lead-contaminated Soil Near a Smelter Site (제련소 주변 납 오염 현장토양의 위해성 저감을 위한 토양 안정화 평가)

  • Yeo, In-Hong;Chang, Yoon-Young
    • Journal of Environmental Impact Assessment
    • /
    • v.30 no.4
    • /
    • pp.215-224
    • /
    • 2021
  • In this study, to investigate the effect of stabilization of Pb-contaminated soil near a smelter site for the reduction of environmental risk of Pb leaching, commercial stabilizers were amended with the Pb-contaminated soil and evaluated leaching characteristics of Pb in soil by TCLP and SPLP leaching test. Also, performing sequential extraction procedure speciation of Pb in the amended soil was investigated. Limestone, AC-2 (Amron), Metafix (Peroxychem) that possess stabilization performance towards heavy metal in soil and mass production is available were selected as candidates. AC-2 contained a CaCO3 and MgO crystalline phase, while Metafix had a Fe7S8 crystalline phase, according to XRD studies. Pb content in SPLP extract was lower than the South Korean drinking water standard for Pb in groundwater at 4% AC-2 and Metafix treatment soil, and TCLP-based stabilization effectiveness was more than 90%. The findings of the sequential extraction method of soil treated with Metafix revealed that fractions 1 and 2 of Pb, which correspond to relatively high mobility and bioavailable fractions, were lowered, while the residual fraction (fraction 5) was raised. As a consequence, the order of performance for Pb stabilization in polluted soil was Metafix>AC-2>limestone.

A Review on Development of PPO-based Anion Exchange Membranes (PPO 기반 음이온 교환막 소재 개발 동향)

  • An, Seong Jin;Kim, Ki Jung;Yu, Somi;Ryu, Gun Young;Chi, Won Seok
    • Membrane Journal
    • /
    • v.31 no.6
    • /
    • pp.371-383
    • /
    • 2021
  • Anion exchange membranes have been used for water electrolysis, which can produce hydrogen, and fuel cells, which can generate electrical energy using hydrogen fuel. Anion exchange membranes operate based on hydroxide ion (OH-) conduction under alkaline conditions. However, since the anion exchange membrane shows relatively low ion conductivity and alkaline stability, there is still a limit to its commercialization in water electrolysis and fuel cells. To address these issues, it is important to develop novel anion exchange membrane materials by rationally designing a polymer structure. In particular, the polymer structure and synthetic method need to be controlled. By doing so, for polymers, the physical properties, ionic conductivity, and alkaline stability can be maintained. Among many anion exchange membranes, poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) is commercially available and easily accessible. In addition, the PPO has relatively high mechanical and chemical stability compared to other polymers. In this review, we introduce the recent development strategy and characteristics of PPO-based polymer materials used in anion exchange membranes.

Exploratory Study on the Specification of Content Knowledge Formation - Based on Analysis of University Writing Textbooks - (글쓰기 내용지식 구성의 세분화에 관한 탐색적 연구 - 대학 글쓰기교재 분석을 중심으로 -)

  • Lee, Ran
    • The Journal of the Korea Contents Association
    • /
    • v.22 no.7
    • /
    • pp.486-497
    • /
    • 2022
  • The aim of this study was to subdivide and present the units and the standards of knowledge integration in creating the students' integrated knowledge from content knowledge in college writing classes. For these, it analyzed three typical writing textbooks being used in colleges and examined the ways of presentation on forming integrated knowledge by text qualitative analysis methods. The analysis procedure and the presentation followed Creswell's spiral analysis model It is a method model which repeats the procedure from material collection and analysis to presentation circularly. This examination illustrates three dimensions of the units in forming content knowledge. Also, it suggested those should be all treated for the more systematic education: the units of the whole text, the paragraphs, and the sentences. In the next chapter, the standards and contents of knowledge integration were suggested in each process. For the process of knowledge selection, the suitability and the contradictoriness between the text materials and author's thesis were proposed as the standards and contents. For the process of organization and integration, the corresponsive integration, contradictive integration, background integration, synthetic integration were suggested. Finally the procedure knowledge such as correct expression and spelling, source indication were shown for the process of expression and citation. Furthermore, it showed, in terms of expression, the process of paraphrasing frequently practiced in writing textbooks needs to be exercised in the three dimensions including summarization, connection, and interpretation(or transformation). This result, however, calls for the further study about the subdividing processes to enhance the adequateness to writing textbooks in the level of universities and for a more refined syllabus on the systematic knowledge integration. Accordingly, it suggested the tasks mentioned above for further study.

Synthesis of akermanite bioceramics by solid-state reaction and evaluation of its bioactivity (고상반응법에 의한 아커마나이트 분말의 합성 및 생체활성도 평가)

  • Go, Jaeeun;Lee, Jong Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.32 no.5
    • /
    • pp.191-198
    • /
    • 2022
  • Zirconia and titanium alloys, which are mainly used for dental implant materials, have poor osseointegration and osteogenesis abilities due to their bioinertness with low bioactivity on surface. In order to improve their surface bioinertness, surface modification with a bioactive material is an easy and simple method. In this study, akermanite (Ca2MgSi2O7), a silicate-based bioceramic material with excellent bone bonding ability, was synthesized by a solid-state reaction and investigated its bioactivity from the analysis of surface dissolution and precipitation of hydroxyapatite particles in SBF solution. Calcium carbonate (CaCO3), magnesium carbonate (MgCO3), and silicon dioxide (SiO2) were used as starting materials. After homogeneous mixing of starting materials by ball milling and the drying of at oven, uniaxial pressing was performed to form a compacted disk, and then heat-treated at high temperature to induce the solid-state reaction to akermanite. Bioactivity of synthesized akermanite disk was evaluated with the reaction temperature from the immersion test in SBF solution. The higher the reaction temperature, the more pronounced the akermanite phase and the less the surface dissolution at particle surface. It resulted that synthesized akermanite particles had high bioactivity on particle surface, but it depended on reacted temperature and phase composition. Moderate dissolution occurred at particle surfaces and observed the new precipitated hydroxyapatite particles in synthetic akermanite with solid-state reaction at 1100℃.

Applicability Analysis on Estimation of Spectral Induced Polarization Parameters Based on Multi-objective Optimization (다중목적함수 최적화에 기초한 광대역 유도분극 변수 예측 적용성 분석)

  • Kim, Bitnarae;Jeong, Ju Yeon;Min, Baehyun;Nam, Myung Jin
    • Geophysics and Geophysical Exploration
    • /
    • v.25 no.3
    • /
    • pp.99-108
    • /
    • 2022
  • Among induced polarization (IP) methods, spectral IP (SIP) uses alternating current as a transmission source to measure amplitudes and phase of complex electrical resistivity at each source frequency, which disperse with respect to source frequencies. The frequency dependence, which can be explained by a relaxation model such as Cole-Cole model or equivalent models, is analyzed to estimate SIP parameters from dispersion curves of complex resistivity employing multi-objective optimization (MOO). The estimation uses a generic algorithm to optimize two objective functions minimizing data misfits of amplitude and phase based on Cole-Cole model, which is most widely used to explain IP relaxation effects. The MOO-based estimation properly recovered Cole-Cole model parameters for synthetic examples but hardly fitted for the real laboratory measures ones, which have relatively smaller values of phases (less than about 10 mrad). Discrepancies between scales for data misfits of amplitude and phase, used as parameters of MOO method, and it is in necessity to employ other methods such as machine learning, which can deal with the discrepancies, to estimate SIP parameters from dispersion curves of complex resistivity.

Stochastic investigation on three-dimensional diffusion of chloride ions in concrete

  • Ye Tian;Yifei Zhu;Guoyi Zhang;Zhonggou Chen;Huiping Feng;Nanguo Jin;Xianyu Jin;Hongxiao Wu;Yinzhe Shao;Yu Liu;Dongming Yan;Zheng Zhou;Shenshan Wang;Zhiqiang Zhang
    • Computers and Concrete
    • /
    • v.32 no.3
    • /
    • pp.247-261
    • /
    • 2023
  • Due to the non-uniform distribution of meso-structure, the diffusion of chloride ions in concrete show the characteristics of characteristics of randomness and fuzziness, which leads to the non-uniform distribution of chloride ions and the non-uniform corrosion of steel rebar in concrete. This phenomenon is supposed as the main reason causing the uncertainty of the bearing capacity deterioration of reinforced concrete structures. In order to analyze and predict the durability of reinforced concrete structures under chloride environment, the random features of chloride ions transport in concrete were studied in this research from in situ meso-structure of concrete. Based on X-ray CT technology, the spatial distribution of coarse aggregates and pores were recognized and extracted from a cylinder concrete specimen. In considering the influence of ITZ, the in situ mesostructure of concrete specimen was reconstructed to conduct a numerical simulation on the diffusion of chloride ions in concrete, which was verified through electronic microprobe technology. Then a stochastic study was performed to investigate the distribution of chloride ions concentration in space and time. The research indicates that the influence of coarse aggregate on chloride ions diffusion is the synthetic action of tortuosity and ITZ effect. The spatial distribution of coarse aggregates and pores is the main reason leading to the non-uniform distribution of chloride ions both in spatial and time scale. The chloride ions concentration under a certain time and the time under a certain concentration both satisfy the Lognormal distribution, which are accepted by Kolmogorov-Smirnov test and Chi-square test. This research provides an efficient method for obtain mass stochastic data from limited but representative samples, which lays a solid foundation for the investigation on the service properties of reinforced concrete structures.

Phase Transition of Zeolite X under High Pressure and Temperature (고온 고압 환경에서 합성 제올라이트 X의 상전이 비교연구)

  • Hyunseung Lee;Soojin Lee;Yongmoon Lee
    • Economic and Environmental Geology
    • /
    • v.56 no.1
    • /
    • pp.13-21
    • /
    • 2023
  • X-ray powder diffraction study was conducted on the bulk modulus and phase transition behavior of synthetic zeolite X under high temperature and high pressure. Water and HCO3- solution were used as a PTM. Sample was heated and pressurized up to 250 ℃ and 5.18 GPa. The change of unit cell volume and phase transition were observed by X-ray diffraction. The lattice constants and unit cell volume of zeolite X, gmelinite, natrolite, and smectite were calculated using the GSAS2 program to which Le Bail's whole powder pattern decomposition (WPPD) method was applied. The bulk modulus of each zeolite X and smectite were calculated using the EosFit program to which the Birch-Murnaghan equation was applied. The bulk modulus of zeolite X is 89(3) GPa in water run, and zeolite X is 92(3) GPa in HCO3- solution run. In both run, pressure induced hydration (PIH) occurred due to the inflow of PTM into the zeolite X framework at initial pressure. Zeolite X transited to gmelinite, natrolite, and smectite in water run. Zeolite X, however, transited to smectite in HCO3- solution run. Interzeolite transformation occurred in water run, and did not occur in HCO3- solution run, which is assumed that conflict between the environment to form zeolite and the pH of the HCO3- solution.

Application and conservation of 3D technology for the restoration of the original shape of military boots excavated in the DMZ (비무장지대 출토 군화의 형태 복원을 위한 3차원 디지털 기술의 적용 및 보존처리)

  • OH Seungjun;WI Koangchul
    • Korean Journal of Heritage: History & Science
    • /
    • v.56 no.2
    • /
    • pp.124-133
    • /
    • 2023
  • Preservation processing for two combat boots was executed through application of 3-dimensional digital technology and with use of preservation materials providing outstanding reversibility and stability. The aim of this was to establish a method to preserve the relics of fallen Korean War soldiers that had been excavated by the soldiers remains excavation corps of the Ministry of National Defense. It was possible to estimate the foot size of the soldiers who would have worn the combat boots via 3-dimensional digital scanning and modeling of the boots. In this process, the original form of the combat boots was restored through the use of 3D-printed structures. The original form was restored through a process of removing contaminants from the excavated relics and performing a conditioning treatment, and through use of an antique-color treatment after bonding and filling in the sections that had been ripped or deteriorated. Following the aforementioned preservation processes, it was possible to confirm that both of the combat boots had soles and top sections made of rubber, and portions of the top section and ankle section of the boots were made of synthetic rubber. As such, it was confirmed that these were similar to the Shoe Pac(M-1944, 12-inch) winter boots that had been manufactured for the purposes of waterproofing and/or protection against cold, and introduced in 1944. Such results confirmed that it is possible to discover the manufacturing techniques, materials, and uses of relics excavated through application of preservation processing, thereby illustrating the importance of the convergent research of scientific preservation processing and 3-dimensional digital technology.