• Title/Summary/Keyword: Synthetic media

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Comparative Study of Holmium (III) Selective Sensors Based on Thiacalixarene and Calixarene Derivatives as an Ionophore

  • Singh, Sanjay;Rani, Geeta
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2229-2237
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    • 2012
  • The two chelates based on calix[4]arene and thiacalix[4]arene have been synthesized and used as neutral ionophores for preparing PVC based membrane sensor selective to $Ho^{3+}$ ion. The addition of potassium tetrakis(4-chlorophenyl)borate (KTpClPB) and various plasticizers, viz., NDPE, o-NPOE, DOP, TEP and DOS have been found to improve significantly the performance of the sensors. The best performance was obtained with the sensor no. 6 having membrane of $L_2$ with composition (w/w) ionophore (2%): KTpClPB (4%): PVC (37%): NDPE (57%). This sensor exhibits Nernatian response with slope $21.10{\pm}0.3mV/decade$ of activity in the concentration range $3.0{\times}10^{-8}-1.0{\times}10^{-2}M\;Ho^{3+}\;ion$, with a detection limit of $1.0{\times}10^{-8}M$. The proposed sensor performs satisfactorily over a wide pH range of 2.8-10, with a fast response time (5 s). The sensor was also found to work successfully in partially non-aqueous media up to 25% (v/v) content of methanol, ethanol and acetonitrile, and can be used for a period of 4 months without any significant drift in potential. The electrode was also used for the determination of $Ho^{3+}$ ions in synthetic mixtures of different ions and the determination of the arsenate ion in different water samples.

A comparative study for adsorption of carbolic acid by synthetic resins

  • Uslu, Hasan;Bamufleh, Hisham S.
    • Membrane and Water Treatment
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    • v.6 no.6
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    • pp.439-449
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    • 2015
  • Carbolic Acid which is called phenol is one of the important starting and/or intermediate materials in various industrial processes. However, its excessive release into environment poses a threat to living organisms, as it is a highly carcinogens and hazardous pollutant even at the very low concentration. Thus removal of phenol from polluted environments is very crucial for sustainable remediation process. We developed a low cost adsorption method for separating phenol from a model aqueous solution. The phenol adsorption was studied using two adsorbents i.e., Amber lite XAD-16 and Amber lite XAD-7 HP with a constant amount of resin 0.1 g at varying aqueous phenol concentrations ($50-200mgL^{-1}$) at room temperature. We compared the efficacy of two phenol adsorbents for removing higher phenol concentrations from the media. We investigated equilibrium and kinetics studies of phenol adsorption employing Freundlich, Temkin and Langmuir isotherms. Amberlite XAD-16 performed better than Amberlite XAD-7 HP in terms of phenol removal efficiency that amounted to 95.52%. Pseudo second order model was highly fitted for both of the adsorption systems. The coefficient of determination ($R^2$) with Langmuir isotherm was found to be 0.98 for Amberlite XAD-7 HP. However, Freundlich isotherm showed $R^2$ value of 0.95 for Amberlite XAD-16, indicating that both isotherms could be described for the isotherms on XAD-7 HP and Amberlite XAD-16, respectively.

A New Report of Biscogniauxia petrensis Isolated from Mosquitoes in Korea

  • Das, Kallol;Kim, Joung-Ho;Choi, Kwang-Shik;Lee, Seung-Yeol;Jung, Hee-Young
    • The Korean Journal of Mycology
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    • v.48 no.2
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    • pp.87-93
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    • 2020
  • A fungal strain designated KNU-WDM2A2 was isolated from mosquitoes in Gimcheon, Korea. The pure culture was transferred to potato dextrose agar (PDA) and synthetic nutrient agar (SNA) media and attained a diameter of 90 mm after 10 days of incubation at 25℃. The colonies were whitish to light pink and cottony to wooly, with an abundant production of aerial mycelia. The strain produced hyaline to slightly yellowish conidiophores that were rough-walled and branched, with conidiogenous cells arising terminally or laterally. Conidia were unicellular, hyaline to light brown, smooth, and oval or ovoid to clavate, with a size of 4.1-6.9×2.5-3.3 ㎛ (n=65). A phylogenetic analysis was conducted using the internal transcribed spacer (ITS) regions and 28S rDNA of large subunit (LSU) sequences, to support the cultural and morphological characteristics. The KNU-WDM2A2 strain was identified here as Biscogniauxia petrensis, new to Korea.

Potential of Organic Solvent Tolerant Bacillus sp. BCNU 5006 (유기용매내성세균 Bacillus sp. BCNU 5006의 유용성)

  • Choi, Hye-Jung;Hwang, Min-Jung;Kim, Bong-Su;Jeong, Yong-Kee;Joo, Woo-Hong
    • KSBB Journal
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    • v.27 no.1
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    • pp.61-66
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    • 2012
  • In the screening process of organic solvent tolerant bacteria showing good growth in media containing several kinds of organic solvents, one strain was isolated and identified as Bacillus sp. BCNU 5006. The strain was able to tolerate many organic solvents including benzene, toluene, xylene, octane, dodecane, butanol and ethylbenzene. Likewise, it could also utilize these solvents as the sole source of carbon with significant enzyme production. The lipolytic enzyme stability of Bacillus sp. BCNU 5006 was studied in the presence of several kinds of solvents at a 25% (v/v) concentration. The highest enzyme stability was observed in the presence of octane (107%), followed by ethylbenzene (88%), decane (86%), and chloroform (85%). Especially, BCNU 5006 lipase was determined to be more stable than immobilized enzyme (Novozyme 435) in the presence of octane, chloroform and xylene. This organic solvent tolerant Bacillus sp. BCNU 5006 could be expected as a potential bioremediation agent and biocatalyst for biodegradation and provide on organic-solvent-based enzymatic synthetic method in industrial chemical processes.

Removal of $NH_4-N$ from Synthetic Wastewater Using Soil Column (토양컬럼을 이용한 합성폐수중의 암모니아성질소 제거)

  • Park San Ill;Cheong Kyung Hoon;Kim Hai Yeon;Paik Ke Jin
    • Journal of Environmental Health Sciences
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    • v.31 no.4 s.85
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    • pp.280-286
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    • 2005
  • The purpose of this investigation was to evaluate removal efficiency of $NH_4-N$ using the soil column. Soil, oyster shell and natural zeolite were used as a supporting media of soil column. Removal efficiencies of $NH_4-N$ were $35.9\%,\;41\%\;and\;93.4\%$ for the soil column packed with soil, natural $zeolite(20\%)$ and oyster $shell(20\%)$ at HRT of 72 hours, respectively. The addition of $20\%$ oyster shell to the soil accelerated nitrification in soil column. The influent ammonia nitrogen was mostly converted to nitrate nitrogen in the soil column and little ammonia nitrogen was found in the effluent. When the influent $NH_4-N$ concentration was 200 mg/l, the NIL-N removal was decreased at HRT of 48 hours, while nitrification was significantly increased after mechanical aeration. It was suggested that nitrification from higher $NH_4-N$ concentration was more affected by aeration in soil column process. The number of nitrifiers was approximately in a level of about $10^6\;MPN/g{\cdot}soil$ in the soil column mixed with oyster shell ($20\%$).

Treatment of Ethylene Glycol in Polyester Weight Loss Wastewater(I) - Reaction Characteristics - (Polyester감량폐수 중에 존재하는 Ethylene Glycol의 처리(I) - 반응 특성 -)

  • Kim, Jeong-Mog;Huh, Man-Woo;Han, Myung-Ho
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.84-89
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    • 1996
  • This study carried out batch and continuous experiments using calcium hydroxide as neutralization agent and immobilization media for removing the ethylene glycol in the pretreated polyester weight loss wastewater. The $TCOD_{Mn}$ concentration in the treated wastewater using culture of iramobilization and suspension for the synthetic wastewater were found as 650mg/l and 1,250mg/l after 48hours, respectively. SVI(Sludge Volume Index) and $TCOD_{Mn}$ concentration were 74 and 73mg/l at optimum F/M ratio, 1.32kg-TCO $D_{Mn}$ /day. kg-MLVSS. The $TCOD_{Mn}$ concentration and removal efficiency were 213mg/l and 93.5% by continuous experiments in the air-lift bioreactor, respectively. The $TCOD_{Mn}$ concentration was 82mg/l, and also the MLVSS concentration was 2,550mg/l, when the volumetric loading rate was 3.04kg-$TCOD_{Mn}/m^{2}$ day for real polyester weight loss wastewater.

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Single Cell Oil Production from Undetoxified Arundo donax L. hydrolysate by Cutaneotrichosporon curvatus

  • Di Fidio, Nicola;Liuzzi, Federico;Mastrolitti, Silvio;Albergo, Roberto;De Bari, Isabella
    • Journal of Microbiology and Biotechnology
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    • v.29 no.2
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    • pp.256-267
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    • 2019
  • The use of low-cost substrates represents one key issue to make single cell oil production sustainable. Among low-input crops, Arundo donax L. is a perennial herbaceous rhizomatous grass containing both C5 and C6 carbohydrates. The scope of the present work was to investigate and optimize the production of lipids by the oleaginous yeast Cutaneotrichosporon curvatus from undetoxified lignocellulosic hydrolysates of steam-pretreated A. donax. The growth of C. curvatus was first optimized in synthetic media, similar in terms of sugar concentration to hydrolysates, by applying the response surface methodology (RSM) analysis. Then the bioconversion of undetoxified hydrolysates was investigated. A fed-batch process for the fermentation of A. donax hydrolysates was finally implemented in a 2-L bioreactor. Under optimized conditions, the total lipid content was 64% of the dry cell weight and the lipid yield was 63% of the theoretical. The fatty acid profile of C. curvatus triglycerides contained 27% palmitic acid, 33% oleic acid and 32% linoleic acid. These results proved the potential of lipid production from A. donax, which is particularly important for their consideration as substitutes for vegetable oils in many applications such as biodiesel or bioplastics.

The current status, functionalities, and developmental strategies of the vinegar industry (식초산업의 현황과 기능성 그리고 발전 전략)

  • Won, Yeong-Seon;Min, Hye-Ji;Seo, Kwon-Il
    • Food Science and Industry
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    • v.53 no.2
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    • pp.215-224
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    • 2020
  • The vinegar can be used not only as functional foods but as the new high-quality materials. Lifestyles have changed a lot because of single-person households, women's economic activities, the aging society, the diversification of mass media, and the traveling abroad. Lifestyle diseases have increased with the life extension. The preference for the fermented vinegar, which is safer and healthier than the synthetic vinegar, has increased since the 1990s. The market of the functional fermented vinegars rapidly grew as researches and product developments on biological activities. In particular, the fermented vinegar, which can be enhanced in functionality depending on the characteristic of materials, is useful not only in the food industry but in various industries such as medical, defense, and construction. For the steady growth of the vinegar industry in the future, it is necessary to research and develop the function of the vinegar that can be utilized in various industries.

Conditional Variational Autoencoder-based Generative Model for Gene Expression Data Augmentation (유전자 발현량 데이터 증대를 위한 Conditional VAE 기반 생성 모델)

  • Hyunsu Bong;Minsik Oh
    • Journal of Broadcast Engineering
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    • v.28 no.3
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    • pp.275-284
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    • 2023
  • Gene expression data can be utilized in various studies, including the prediction of disease prognosis. However, there are challenges associated with collecting enough data due to cost constraints. In this paper, we propose a gene expression data generation model based on Conditional Variational Autoencoder. Our results demonstrate that the proposed model generates synthetic data with superior quality compared to two other state-of-the-art models for gene expression data generation, namely the Wasserstein Generative Adversarial Network with Gradient Penalty based model and the structured data generation models CTGAN and TVAE.

An Enhanced Text Mining Approach using Ensemble Algorithm for Detecting Cyber Bullying

  • Z.Sunitha Bai;Sreelatha Malempati
    • International Journal of Computer Science & Network Security
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    • v.23 no.5
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    • pp.1-6
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    • 2023
  • Text mining (TM) is most widely used to process the various unstructured text documents and process the data present in the various domains. The other name for text mining is text classification. This domain is most popular in many domains such as movie reviews, product reviews on various E-commerce websites, sentiment analysis, topic modeling and cyber bullying on social media messages. Cyber-bullying is the type of abusing someone with the insulting language. Personal abusing, sexual harassment, other types of abusing come under cyber-bullying. Several existing systems are developed to detect the bullying words based on their situation in the social networking sites (SNS). SNS becomes platform for bully someone. In this paper, An Enhanced text mining approach is developed by using Ensemble Algorithm (ETMA) to solve several problems in traditional algorithms and improve the accuracy, processing time and quality of the result. ETMA is the algorithm used to analyze the bullying text within the social networking sites (SNS) such as facebook, twitter etc. The ETMA is applied on synthetic dataset collected from various data a source which consists of 5k messages belongs to bullying and non-bullying. The performance is analyzed by showing Precision, Recall, F1-Score and Accuracy.