• 제목/요약/키워드: Synthetic Fiber

검색결과 355건 처리시간 0.025초

Living cationic polymerization of poly (isobutyl vinyl ether) and PVA derived therefrom

  • Mah, Soukil
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.1-2
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    • 2003
  • Some new synthetic routes for the preparation of poly (isobutyl vinyl ether) (P(IBVE)) having a controllable molar mass with narrow distribution via catalytic or photoinduced living cationic polymerization and their conversion to corresponding PVA have been developed. It was found that the combination of iodomethyl methyl ether (IMME)-zinc iodide is effective in the initiation of the catalytic and the various combinations of diphenyliodonium halides, well known photocationic initiators (DPIX) with zinc halides (ZnX$_2$) are also useful in photoinduced living cationic polymerization of isobutyl vinyl ether (IBVE). Polymerization both in the catalytic and photoinduced systems precede until the full consumption of the monomer and the rate of polymerization increases as the concentration of the catalyst or photoinitiator. The number average molar mass of the resulting polymer is proportional with % conversion, which is determined by the ratio of monomer consumed and the initial values of the catalyst or initiator. The living nature was also confirmed by subsequent monomer addition technique.

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열분해-GC에 의한 면/폴리에스터 혼방 직물의 분석 (Analysis of Cotton/Polyester Fabrics using Pyrolysis Gas Chromatograpy)

  • 조미숙;김명덕;박성우;윤기준;남재도;이종훈;이영관
    • 폴리머
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    • 제27권3호
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    • pp.271-274
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    • 2003
  • 열분해 기체 크로마토그래피 (Py-GC)를 이용하여 섬유의 동일성과 함량을 조사하였다. 면사, 폴리에스터, 면과 폴리에스터 혼방사를 Py-GC를 이용하여 그 성분과 함량을 조사하였다. 면과 폴리에스터 성분은 각각의 특성 피이크를 나타내었으며, 특성 피이크의 면적은 각 성분의 함량이 증가함에 따라 비례적으로 증가함을 알 수 있었다. 또한 폴리에스터의 경우에 열분해로부터 생성되는 화합물의 성분을 질량 분광법을 이용하여 테레프탈산, 벤조산, 비닐 벤조산임을 확인할 수 있었으며, 이를 바탕으로 미지의 시료에 포함되어 있는 면과 폴리에스터의 함량을 정량 분석할 수 있었다.

키토산 전처리(前處理)가 면(綿), 견(絹), 나일론, 폴리에스테르의 코치닐염색(染色)에 미치는 효과(效果) (The Effect of Chitosan-Pretreatment on the Cochineal Dyeing of Cotton, Silk, Nylon, and Polyester Fabrics)

  • 전동원;김종준;김선화
    • 패션비즈니스
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    • 제7권4호
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    • pp.57-66
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    • 2003
  • Cochineal dyeing was applied to natural fiber fabrics, cotton and silk fabrics, and synthetic fiber fabrics, nylon and polyester fabrics. Chitosan-pretreatment was applied to the fabrics in order to investigate the effect of chitosan treatment on the dyeing behavior. The effect of chitosan treatment on the mordanting was also investigated by incorporating Cu-mordant on the chitosan-treated or chitosan-untreated fabrics during the dyeing process.

항균성을 부여하기 위한 세탁과정에서의 은콜로이드 용액 처리 (Colloidal Silver Treatment of Cotton Fabrics after Washing to Impart Antimicorbial Activity)

  • 정혜원;김현숙
    • 한국의류학회지
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    • 제28권9_10호
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    • pp.1312-1319
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    • 2004
  • Underwear is laundered frequently and most of them is made of cotton, but a cotton fiber is more difficult to modify than a synthetic fiber. We have attempted to determine the optimum conditions necessary whereby the lowest concentration of silver solution is needed to produce the greatest antimicrobial properties of cotton fabrics. For this study, colloidal silver was made by electrolysis. The concentration of colloidal silver was increased by increasing the area of the silver plates submerged in the water, the water temperature, the water hardness and the flow time of the water per 1l. However, the colloidal silver concentration was decreased by extending a space between the silver plates and increasing the water velocity. Cotton fabrics treated in the washing machine with 1.3 ppm colloidal silver solution for 10 minutes had effective microbial properties and an unperceivable reduction of reflectance.

연료전지막을 위한 PPO/PS-b-PSSA 블랜드의 제조와 분석 (Preparation and Characterization of PPO/PS-b-PSSA Blend for Fuel Cell)

  • Woo, Jung-Kyu;Ahn, Sung-Guk;Cho, Chang-Gi
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 가을 학술발표회 논문집
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    • pp.175-176
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    • 2003
  • Generally, The protone exchange membrane (PEM) contains cationic exchange groups such as SO3$\^$-/ group. The poly(styrene sulfonic acid) (PSSA) and its copolymers are widely studied because of easily synthetic method and higher conductivities. However, PSSA is not used individually because of poor physical properties such as brittleness and relatively lower Tg. So some researchers are concerned engineering plastics (EP) such as polyimides, polysulfone, polyketones, and poly(2,6-dimethyl-1,4-phenylene oxide) (MPPO) etc. (omitted)

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전사인쇄에 있어서 색재현에 관한 연구 (A Study on the Color Reproduction in Decalcomania)

  • 정다현;조가람;구철회
    • 한국인쇄학회지
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    • 제24권2호
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    • pp.35-48
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    • 2006
  • Textile decalcomania printing is how after the disperse dye which is melting and vaporizing absorbs on the surface of the cloth, it colors by permeating into the cloth inside. So it has applied a lot to the synthetic fiber like polyester. However, because there is no showing right temperature and time in case of printing on the polyester fiber and the microfiber, this study aims at it. The experimental methods are like this : first measuring the density for the objective judgment, and measuring colors with the colorimeter, and then study for the color reproduction through a visual evaluation.

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다른 configuration을 가진 1,2-diaminocyclohexane이 폴리아크릴로니트릴(PAN)의 중합 거동과 입체규칙성에 미치는 영향 (Effect of the Addition of 1,2-Diaminocyclohexane with Different Configuration on the Polymerization Kinetics and Stereoregularity of Polyacrylonitrile(PAN))

  • Bae, Dong-Jin;Park, Chong-Rae
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.101-102
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    • 2001
  • The control of the stereochemistry during the radical polymerization of vinyl monomer has been a long standing concern and is still one of the most important topic in synthetic polymer chemistry.[1-5] The stereoregularity of vinyl polymers often has significant effect on the properties of polymer materials. Therefore, it is important to devise methods to control stereoregularity during the polymerization reactions. (omitted)

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Myocardial tissue engineering using electrospun nanofiber composites

  • Kim, Pyung-Hwan;Cho, Je-Yoel
    • BMB Reports
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    • 제49권1호
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    • pp.26-36
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    • 2016
  • Emerging trends for cardiac tissue engineering are focused on increasing the biocompatibility and tissue regeneration ability of artificial heart tissue by incorporating various cell sources and bioactive molecules. Although primary cardiomyocytes can be successfully implanted, clinical applications are restricted due to their low survival rates and poor proliferation. To develop successful cardiovascular tissue regeneration systems, new technologies must be introduced to improve myocardial regeneration. Electrospinning is a simple, versatile technique for fabricating nanofibers. Here, we discuss various biodegradable polymers (natural, synthetic, and combinatorial polymers) that can be used for fiber fabrication. We also describe a series of fiber modification methods that can increase cell survival, proliferation, and migration and provide supporting mechanical properties by mimicking micro-environment structures, such as the extracellular matrix (ECM). In addition, the applications and types of nanofiber-based scaffolds for myocardial regeneration are described. Finally, fusion research methods combined with stem cells and scaffolds to improve biocompatibility are discussed. [BMB Reports 2016; 49(1): 26-36]

자전연소합성 반응중 속빈 TiC 섬유의 형성 기구 (Forming Mechanism of TiC Hollow Fibers during Self-Propagating High Temperature Synthesis)

  • 윤존도;방환철
    • 한국세라믹학회지
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    • 제37권4호
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    • pp.332-337
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    • 2000
  • Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

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Experimental and analytical investigation of the shear behavior of strain hardening cementitious composites

  • Georgiou, Antroula V.;Pantazopoulou, Stavroula J.
    • Structural Engineering and Mechanics
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    • 제72권1호
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    • pp.19-30
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    • 2019
  • The mechanical behavior of Fiber Reinforced Cementitious Composites (FRCC) under direct shear is studied through experiment and analytical simulation. The cementitious composite considered contains 55% replacement of cement with fly ash and 2% (volume ratio) of short discontinuous synthetic fibers (in the form of mass reinforcement, comprising PVA - Polyvinyl Alcohol fibers). This class of cementitious materials exhibits ductility under tension with the formation of multiple fine cracks and significant delay of crack stabilization (i.e., localization of cracking at a single location). One of the behavioral parameters that concern structural design is the shear strength of this new type of fiber reinforced composites. This aspect was studied in the present work with the use of Push-off tests. The shear strength is then compared to the materials' tensile and splitting strength values.