• 제목/요약/키워드: Synthesis process

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메커니즘 합성을 통한 기계설계 (Mechanism Design Using a Mechanism Configuration Method)

  • 이장용
    • 대한기계학회논문집A
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    • 제35권12호
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    • pp.1613-1618
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    • 2011
  • 기구 메커니즘의 작동해석과 관련하여 해석기하적 방법과 도식적 방법에 대한 연구가 있어왔다. 반면에 주어진 목적에 맞게끔 메커니즘을 구성하는 것에 대한 연구는 그리 많이 이루어지지 않았는데 일반 산업체 현장에서는 주로 과거에 활용된 메커니즘을 응용하는 방식으로 메커니즘 설계를 수행하여 왔다. 이런 방식은 설계초기 단계에서 가능한 모든 기구구성에 대해 숙고할 필요가 있는 메커니즘 설계자의 기구 선택범위를 제한하는 측면이 있다. 본 논문에서는 개념설계 단계에서 활용될 수 있는 기구 메커니즘 구성에 관한 새로운 방법론을 제시한다. 이를 활용하여 설계자는 창의적인 기구구성을 보다 효율적으로 수행할 수 있게 된다.

플라즈마 아크 방전법에 의한 Zr계 나노분말 제조 (Synthesis of Zirconium-Based Nanopowder by the Plasma Arc Discharge Process)

  • 이길근;김경주;박제신
    • 한국분말재료학회지
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    • 제14권1호
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    • pp.63-69
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    • 2007
  • The present study was focused on the synthesis of a zirconium-based alloyed nanopowder by the plasma arc discharge process. The chemical composition, phase structure, particle size and hydrogen sorption property of the synthesized powders under various synthesis conditions were analyzed using XRF, XRD, SEM, XPS and the ASTM-F798 method. The chemical composition of the synthesized Zr-V-Fe-based powders approached that of the raw material with an increasing hydrogen fraction in the powder synthesis atmosphere. The synthesized $Zr_{55}V_{29}Fe_{16}$ powder consist of a mixed phase structure of the $Zr,\;ZrH_2,\;FeV\;and\;Zr(V_{1-x}Fe_{x})_2$ phases. This powder has an average particle size of about 20 nm. The synthesized $Zr_{55}V_{29}Fe_{16}$ nanopowder showed getter characteristics, even though it had a lower hydrogen sorption speed than the $Zr_{57}\;V{36}\;Fe_7$ getter powder. However, the synthesized Zr nanopowder with an average particle size of 20 nm showed higher hydrogen sorption speed than the $Zr_{57}\;V{36}\;Fe_7$ getter powder.

물유리를 이용한 나노실리카 제조 시 pH가 미치는 영향 (The Effect of pH on Synthesis of Nano-Silica Using Water Glass)

  • 최진석;안성진
    • 한국재료학회지
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    • 제25권4호
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    • pp.209-213
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    • 2015
  • Synthesis of nano-silica using water glass in a Sol-Gel process is one of several methods to manufacture nano-silica. In nano-silica synthesized from water glass, there are various metal impurities. However, synthesis of nano-silica using water glass in a Sol-Gel process is an interesting method because it is relatively simple and cheap. In this study, nano-silica was synthesized from water glass; we investigated the effect of pH on the synthesis of nano-silica. The morphology of the nanosilica with pH 2 was flat, but the surface of the nano-silica with pH 10 had holes similar to small craters. As a result of ICP-OES analysis, the amount of Na in the nano-silica with pH 2 was found to be 170 mg/kg. On the other hand, the amount of Na in the nano-silica with pH 10 was found to be 56,930 mg/kg. After calcination, the crystal structure of the nano-silica with pH 2 was amorphous. The crystal structure of the nano-silica with pH 10 transformed from amorphous to tridymite. This is because elemental Na in the nano-silica had the effect of decreasing the phase transformation temperature.

수소화 연소합성법을 이용한 Mg-xNi 금속수소화물의 수소저장특성에 관한 연구 (Hydriding Behavior of an Mg-xNi Alloys Prepared in Hydriding Combustion Synthesis)

  • 김지호;최덕균;황광택;한정섭;김진호
    • 한국수소및신에너지학회논문집
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    • 제21권2호
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    • pp.123-128
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    • 2010
  • Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

수열합성법을 이용한 TiO2 나노 입자의 합성 (Synthesis of Nano-sized TiO2 Powder using a Hydrothermal Process)

  • 김강혁;이우진;김동규;이성근;이상화;김인수
    • 대한금속재료학회지
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    • 제48권6호
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    • pp.543-550
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    • 2010
  • This paper investigated the synthesis conditions of nano-sized $TiO_2$ powder in a hydrothermal process at a temperature range of $100{\sim}180^{\circ}C$ considering the precipitation agent, precipitation pH, reaction temperature and time. Titanium hydroxide formed by $NH_4OH$ exhibited a lower crystallization temperature than that by NaOH and formed less aggregated $TiO_2$ particles. As the precipitation pH increased above 8, the shape of the particles changed from spherical to needle form, which appeared to be caused by dissolution and re-precipitation of the titanium hydroxide in an alkali environment.

Facile Regiocontrolled Three-Step Synthesis of Poly-Substituted Furans, Pyrroles, and Thiophenes: Consecutive Michael Addition of Methyl Cyanoacetate to α,β-Enone, CuI-Mediated Aerobic Oxidation, and Acid-Catalyzed Paal-Knorr Synthesis

  • Kim, Se-Hee;Lim, Jin-Woo;Lim, Cheol-Hee;Kim, Jae-Nyoung
    • Bulletin of the Korean Chemical Society
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    • 제33권2호
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    • pp.620-624
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    • 2012
  • An efficient synthesis of poly-substituted furans, pyrroles, and thiophenes was carried out in a regiocontrolled manner via a three-step process; (i) conjugate addition of methyl cyanoacetate derivatives to ${\alpha}$,${\beta}$-enones, (ii) CuI-mediated aerobic oxidation, and (iii) Paal-Knorr type synthesis of five-membered heterocycles.

'Hanmal' Korean Language Diphone Database for Speech Synthesis

  • Chung, Hyun-Song
    • 음성과학
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    • 제12권1호
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    • pp.55-63
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    • 2005
  • This paper introduces a 'Hanmal' Korean language diphone database for speech synthesis, which has been publicly available since 1999 in the MBROLA web site and never been properly published in a journal. The diphone database is compatible with the MBROLA programme of high-quality multilingual speech synthesis systems. The usefulness of the diphone database is introduced in the paper. The paper also describes the phonetic and phonological structure of the database, showing the process of creating a text corpus. A machine-readable Korean SAMPA convention for the control data input to the MBROLA application is also suggested. Diphone concatenation and prosody manipulation are performed using the MBR-PSOLA algorithm. A set of segment duration models can be applied to the diphone synthesis of Korean.

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대용량 운율 음성데이타를 이용한 자동합성방식 (Automatic Synthesis Method Using Prosody-Rich Database)

  • 김상훈
    • 한국음향학회:학술대회논문집
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    • 한국음향학회 1998년도 제15회 음성통신 및 신호처리 워크샵(KSCSP 98 15권1호)
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    • pp.87-92
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    • 1998
  • In general, the synthesis unit database was constructed by recording isolated word. In that case, each boundary of word has typical prosodic pattern like a falling intonation or preboundary lengthening. To get natural synthetic speech using these kinds of database, we must artificially distort original speech. However, that artificial process rather resulted in unnatural, unintelligible synthetic speech due to the excessive prosodic modification on speech signal. To overcome these problems, we gathered thousands of sentences for synthesis database. To make a phone level synthesis unit, we trained speech recognizer with the recorded speech, and then segmented phone boundaries automatically. In addition, we used laryngo graph for the epoch detection. From the automatically generated synthesis database, we chose the best phone and directly concatenated it without any prosody processing. To select the best phone among multiple phone candidates, we used prosodic information such as break strength of word boundaries, phonetic contexts, cepstrum, pitch, energy, and phone duration. From the pilot test, we obtained some positive results.

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평면 링크기구 자동 설계를 위한 스프링 연결 사이즈 가변 블록 모델 (Spring Connected Size-Variable Rigid Block Model for Automatic Synthesis of a Planar Linkage Mechanism)

  • 김범석;유홍희
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.822-826
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    • 2008
  • A linkage mechanism is a device to convert an input motion into a desired output motion. Traditional linkage mechanism designs are based on trial and error approaches so that size or shape changes of an original mechanism often result in improper results. In order to resolve these problems, an improved automatic mechanism synthesis method that determines the linkage type and dimensions by using an optimization method during the synthesis process has been proposed. For the synthesis, a planar linkage is modeled as a set of rigid blocks connected by zero-length translational springs with variable stiffness. In this study, the sizes of rigid blocks were also treated as design variables for more general linkage synthesis. The values of spring stiffness and the size of rigid block yielding a desired output motion at the end-effecter are found by using an optimization method.

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The μ-synthesis and analysis of water level control in steam generators

  • Salehi, Ahmad;Kazemi, Mohammad Hosein;Safarzadeh, Omid
    • Nuclear Engineering and Technology
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    • 제51권1호
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    • pp.163-169
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    • 2019
  • The robust controller synthesis and analysis of the water level process in the U-tube system generator (UTSG) is addressed in this paper. The parameter uncertainties of the steam generator (SG) are modeled as multiplicative perturbations which are normalized by designing suitable weighting functions. The relative errors of the nominal SG model with respect to the other operating power level models are employed to specify the weighting functions for normalizing the plant uncertainties. Then, a robust controller is designed based on ${\mu}$-synthesis and D-K iteration, and its stability robustness is verified over the whole range of power operations. A gain-scheduled controller with $H_{\infty}$-synthesis is also designed to compare its robustness with the proposed controller. The stability analysis is accomplished and compared with the previous QFT design. The ${\mu}$-analysis of the system shows that the proposed controller has a favorable stability robustness for the whole range of operating power conditions. The proposed controller response is simulated against the power level deviation in start-up and shutdown stages and compared with the other concerning controllers.