• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.87-125
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• 2000

A new paradigm of crystal growth was suggested in a charged cluster model, where charged clusters of nanometer size are suspended in the gas phase in most thin film processes and are a major flux for thin film growth. The existence of these hypothetical clusters was experimentally confirmed in the diamond and silicon CVD processes as well as in gold and tungsten evaporation. These results imply new insights as to the low pressure diamond synthesis without hydrogen, epitaxial growth, selective deposition and fabrication of quantum dots, nanometer-sized powders and nanowires or nanotubes. Based on this concept, we produced such quantum dot structures of carbon, silicon, gold and tungsten. Charged clusters land preferably on conducting substrates over on insulating substrates, resulting in selective deposition. if the behavior of selective deposition is properly controlled, charged clusters can make highly anisotropic growth, leading to nanowires or nanotubes.

• Journal of the Korean institute of surface engineering
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• v.26 no.6
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• pp.299-306
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• 1993

The characteristic of synthesized potassium hexatitanate and manufacturing of thin film type matrix for battery was studied. After ball milled the mixture with 1:4 of $K_2CO_3$ and TiO2, mixsture was sintered at 85$0^{\circ}C$ and its product was confirmed with XRD. Adding the PTFE to the obtained potassium hexatitanate according to there various ball-mill time to control its particle size, thin film type matrix was manufactured. The high-est wettability of 50% was found with 12 hour ball milled powder containing 10w/o of PTFE and also it shown good mechanical properties. The matrix with $K_2O$$\cdot$$6TiO_2$ whisker shown 170% of wettability. Thed char-acteristics of matrix made by whisker and powder mixture were compared with the investigation of bubbled pressure and pore size distribution to improve its mechanical properties.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.107-107
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• 2003

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.149-149
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• 1996

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.11a
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• pp.62-62
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• 1996

• Proceedings of the Materials Research Society of Korea Conference
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• 1997.05a
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• pp.113-113
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• 1997

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.88.1-88
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• 2003

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.3
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• pp.193-199
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• 2013

In this work, thin film type Cu/ZnO nanostructure catalysts were fabricated by several synthetic routes in order to maximize the performance of the micro reforming system. For this work, various Cu/ZnO nanostructure catalysts could be synthesized by means of four approaches which are chemical vapor method, wet solution method and their hybrid method. The reforming performance of these as-synthetic catalysts was evaluated as compared to the conventional catalysts. Among the as-synthetic nanostructures, sphere type catalysts with specific surface of $18.6m^2/g$ showed the best performance of hydrogen production rate of 30ml/min at the feed rate of 0.2ml/min. This work will give the first insight on thin film type Cu/ZnO nanostructure catalyst for micro reforming system for hydrogen production of portable electronic systems.

• Journal of Powder Materials
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• v.31 no.3
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• pp.255-262
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• 2024

Nano-oxide dispersion-strengthened (ODS) superalloys have attracted attention because of their outstanding mechanical reinforcement mechanism. Dispersed oxides increase the material's strength by preventing grain growth and recrystallization, as well as increasing creep resistance. In this research, atomic layer deposition (ALD) was applied to synthesize an ODS alloy. It is useful to coat conformal thin films even on complex matrix shapes, such as nanorods or powders. We coated an Nb-Si-based superalloy with TiO₂ thin film by using rotary-reactor type thermal ALD. TiO₂ was grown by controlling the deposition recipe, reactor temperature, N₂ flow rate, and rotor speed. We could confirm the formation of uniform TiO₂ film on the surface of the superalloy. This process was successfully applied to the synthesis of an ODS alloy, which could be a new field of ALD applications.

• Membrane and Water Treatment
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• v.9 no.5
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• pp.327-334
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• 2018

The nano/micro composites with highly porous surface area have attracted of great interest, particularly the synthesis of porous and thin film sheets of high performance. In this paper, an easy method of cost-effective synthesis of thin film ceramic fiber membranes based on Hydroxyapatite, and activated carbon by turned into studied to be applied within the service-facilitated the transport of radioactive waste such as $^{90}Sr$, $^{137}Cs$ and $^{60}Co$) as activated product of radioisotopes from ETRR-2 research reactor and dissolved in 3M $HNO_3$, across a thin flat-sheet supported liquid membrane (TFSSLM). Radionuclides are transported from alkaline pH values. The presence of sodium salts in the aqueous media improves in $HNO_3$, the lowering of permeability because the initial $HNO_3$ concentration is improved. The study some parameters on the thin sheet ceramic supported liquid membrane. EDTA as stripping phase concentration, time of extraction and temperature were studied. The study of maximum permeability of radioisotopes for all parameters. The pertraction of a radioactive waste solution from nitrate medium were examined at the optimized conditions. Under the optimum experimental 98.6-99.9% of $^{90}Sr$, 79.65-80.3% of $^{137}Cs$ and $^{60}Co$ 45.5-55.5% in 90-110 min with were extracted in 10-30 min, respectively. The process of diffusion in liquid membranes is governed by the chemical diffusion process.