• 제목/요약/키워드: Synthesis of thin film

검색결과 287건 처리시간 0.031초

(N-docosyl pyridinium)-TCNQ(1 : 1) 착체의 합성과 Langmur-Blodgett 초박막 제작 (Synthesis of (N-docosyl Pyridinium)-TCNQ (1:1) complex and Fabrication of Langmuir-Blodgett Ultra Thin Films)

  • 손병청;정순욱
    • 한국응용과학기술학회지
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    • 제6권2호
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    • pp.39-44
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    • 1989
  • (N-docosyl pyridinium)-TCNQ(1:1) complex was synthesized by reacting N-docosyl pyridinium bromide and LiTCNQ. This complex was investigated and confirmed by elemental analysis. U.V, I.R spectra. A stability to the dispersion solvent, which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene (1:1, V/V) of (N-docosyl pyridinium)-TCNQ(1:1) complex was investigated by U. V spectrophotometer and was confirmed stabilized on acetonitrile, benzene and acetonitrile-benzene(1:1'V/V) for 7 hours. Using ultra pure water as subphase for L-B film deposition, the Y-type L-B film of (N-docosyl pyridinium)-TCNQ(1:1) complex was farbricated. The electrical conductivities on a perpendicular direction of the L-B film were measured to be $5{\times}10^{-5}{\sim}5{\times}10^{-14}$S/cm according to the number of layer.

전도성 Langmuir-Blodgett 막 제작을 위한 성막물질의 합성과 막의 누적 (Synthesis of Membrane Forming Material for the Fabrication of Conducting Langmuir-Blodgett Film and Layering the Film.)

  • 신동명;손병청;유덕선;최강훈;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1991년도 하계학술대회 논문집
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    • pp.238-240
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    • 1991
  • Langmuir-Blodgett(L.B) method is one of the most possible candidate for the fabrication of the micro scale memory or electrical devices. As for a fundamental study on the conduction mechanism in the organic thin membrane, N-alkyl quinolium-TCNQ complexes were synthesized and their physical properties were examined spectroscopically. LB film was produced by using Moving Wall Type LB Apparatus. The average area per molecule (N-docosylquinolium-TCNQ) was $67.97{\AA}^2$ which is ${\AA}^2$ larger than N-docosyl quinolium-TCNQ.

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Preparation and Characterization of Sol-Gel Derived $SiO_2-TiO_2$ -PDMS Composite Films

  • 황진명;여창선;김유항
    • Bulletin of the Korean Chemical Society
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    • 제22권12호
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    • pp.1366-1370
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    • 2001
  • Thin films of the SiO2-TiO2-PDMS composite material have been prepared by the sol-gel dip coating method. Acid catalyzed solutions of tetraethoxy silane (TEOS) and polydimethyl siloxane (PDMS) mixed with titanium isopropoxide Ti(OiPr) were used as precursors. The optical and structural properties of the organically modified 70SiO2-30TiO2 composite films have been investigated with Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible Spectroscopy (UV-Vis), Differential Thermal Analysis (DTA) and prism coupling technique. The films coated on the soda-lime-silicate glass exhibit 450-750 nm thickness, 1.56-1.68 refractive index and 88-94% transmittance depending on the experimental parameters such as amount of PDMS, thermal treatment and heating rate. The optical loss of prepared composite film was measured to be about 0.34 dB/cm.

진공조의 잔류산소가 입방정질화붕소 박막 합성에 미치는 영향 (Effect of Residual Oxygen in a Vacuum Chamber on the Deposition of Cubic Boron Nitride Thin Film)

  • 오승근;김영만
    • 한국표면공학회지
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    • 제46권4호
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    • pp.139-144
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    • 2013
  • c-BN(cubic boron nitride) is known to have extremely high hardness next to diamond, as well as very high thermal and chemical stability. The c-BN in the form of film is useful for wear resistant coatings where the application of diamond film is restricted. However, there is less practical application because of difficult control of processing variables for synthesis of c-BN film as well as unclear mechanism on formation of c-BN. Therefore, in the present study, the structural characterization of c-BN thin film were investigated using $B_4C$ target in r.f. magnetron sputtering system as a function of processing variables. c-BN films were coated on Si(100) substrate using $B_4C$ (99.5% purity). The mixture of nitrogen and argon was used for carrier gas. The deposition processing conditions were changed with substrate bias voltage, substrate temperature and base pressure. Fourier transform infrared microscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) were used to analyze crystal structures and chemical binding energy of the films. In the case of the BN film deposited at room temperature, c-BN was formed in the substrate bias voltage range of -400 V~ -600 V. Less c-BN fraction was observed as deposition temperature increased and more c-BN fraction was observed as base pressure increased.

Single Crystals for Functional Devices

  • Kim, You-Song
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF KACG FALL MEETING, SEOUL, 4 DECEMBER, 1999
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    • pp.93-99
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    • 1999
  • It is definite trend that the functional devices are to be integrated by miniaturizing of individual components. Bulk crystals turn into wafer form, while thin film of the functional materials is being fabricated for single and multi-layer devices. In addition, single crystals with multi-function performance would be desirable for further miniaturization. crystal growers have the responsibility for synthesis single crystals work to meet ever increasing requirement of future devices.

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퀴녹살린을 포함한 신규 전기 발광성 고분자의 합성 (Design and Synthesis New Electroluminescent poly(p-phenylenevinylene) polymers containing Quinoxaline)

  • Jang, Mi-Hae;Lee, Bum-Hoon;Jaung, Jae-Yun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.53-56
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    • 2002
  • Today, interest in electroluminescent(EL) diodes has been increasing since vacuum-sublimed thin-film dioes exhibited high performance. And since the discovery of electroluminescence from aluminaqinone, which has uniform $\pi$-conjugated segment by Eastmann kodack,$^1$ lots of attentions have been concentrated on organic EL devices. However, they have disadvantage such as low mechanical intensity, thermic crystallization. (omitted)

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박막형 형광체 합성 및 발광 특성 (Synthesis and Luminous Properties of Thin Film Phosphors)

  • 김영진;정승묵;정영호;송국현;박광자
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 1999년도 추계학술발표회 초록집
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    • pp.51-52
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    • 1999
  • 각기 녹색, 적색의 발광특성플 갖는 $ZnGa_20_4:Mn,{\;}CaTi0_3:Pr$을 rf 마그네트론 스퍼터링법으로 박막을 제조하였다. 박막증착변수가 성장특성 및 발광특성에 미치는 영향을 분석한 결과, 산소분압 및 기판온도조건에 따라서 결정화 및 발광특성이 크게 달라짐을 확인할수 있었다. 열처리후에는 진공분위기보다는 $N_2$가스분위기에서 열처리를 한 시편이 발광특성이 우수하 게 나타났으며, 기판의 종류에 따라서 박막의 성장기구와 발광특성이 다르며, 특히 결정질의 기판이 형광체 박막 합성에 적합함을 알 수 있었다.

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Pulsed DC 마그네트론 스퍼터링을 이용한 $SiN_x$ 합성 (Synthesis of silicon nitride thin film using pulsed DC magnetron sputtering on polymer substrates)

  • 전아람;금민종;신경식;이교웅;한전건
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2007년도 추계학술대회 논문집
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    • pp.109-111
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    • 2007
  • Pulsed DC 마그네트론 스퍼터링 장치를 이용하여 Polymer 및 Glass 기판 위에 $SiN_{\chi}$ (Silicon Nitride) 박막을 합성 시키고 이들의 구조적, 광학적 특성을 조사하였다. 막두께는 100 nm로 고정하였으며, power mode 및 질소 가스 유량비를 변수로 합성하였다.

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2차 버퍼층 ZnMgO 박막의 Mg/(Mg+Zn) 비율 조절을 통한 SnS 박막 태양전지 효율 향상 (Improving the Efficiency of SnS Thin Film Solar Cells by Adjusting the Mg/(Mg+Zn) Ratio of Secondary Buffer Layer ZnMgO Thin Film)

  • 이효석;조재유;윤성민;정채환;허재영
    • 한국재료학회지
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    • 제30권10호
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    • pp.566-572
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    • 2020
  • In the recent years, thin film solar cells (TFSCs) have emerged as a viable replacement for crystalline silicon solar cells and offer a variety of choices, particularly in terms of synthesis processes and substrates (rigid or flexible, metal or insulator). Among the thin-film absorber materials, SnS has great potential for the manufacturing of low-cost TFSCs due to its suitable optical and electrical properties, non-toxic nature, and earth abundancy. However, the efficiency of SnS-based solar cells is found to be in the range of 1 ~ 4 % and remains far below those of CdTe-, CIGS-, and CZTSSe-based TFSCs. Aside from the improvement in the physical properties of absorber layer, enormous efforts have been focused on the development of suitable buffer layer for SnS-based solar cells. Herein, we investigate the device performance of SnS-based TFSCs by introducing double buffer layers, in which CdS is applied as first buffer layer and ZnMgO films is employed as second buffer layer. The effect of the composition ratio (Mg/(Mg+Zn)) of RF sputtered ZnMgO films on the device performance is studied. The structural and optical properties of ZnMgO films with various Mg/(Mg+Zn) ratios are also analyzed systemically. The fabricated SnS-based TFSCs with device structure of SLG/Mo/SnS/CdS/ZnMgO/AZO/Al exhibit a highest cell efficiency of 1.84 % along with open-circuit voltage of 0.302 V, short-circuit current density of 13.55 mA cm-2, and fill factor of 0.45 with an optimum Mg/(Mg + Zn) ratio of 0.02.