• Title/Summary/Keyword: Synthesis

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Effect of Light, Temperature, and Shaking Speed on Production of Capsaicin in Suspension-Cultured Jalapeno Pepper (Capsicum annuum L.)

  • Lee, Kwon-Bok;Engler, Cady;Yang, Jae E.;Lee, Shin-Woo;Park, Yong-Ha
    • Journal of Applied Biological Chemistry
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    • v.44 no.2
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    • pp.84-86
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    • 2001
  • Capsaicin synthesis by suspension cultured cells of Jalapeno pepper (Capcicum annuum L.) was assessed in vitro under various conditions including temperature (23 and $30^{\circ}C$), light intensity (with light and without light), and shaking speed (110 and 200 rpm). Capsaicin production increased, while the cell biomass growth decreased possibly due to the production of a secondary metabolite. Capsaicin synthesis was primarily affected by light condition. Cells cultivated at 110 rpm and $23^{\circ}C$ under light condition yielded the highest fresh weight, while those cultivated under the same condition, but without light resulted in the lowest cell mass. Capsaicin content in cells of 18-day-old pepper grown at 110 rpm and $23^{\circ}C$ under light was 0.125% of the cell mass. However, without light treatment, the capsaicin content in cells at the same shaking speed and temperature increased up to 169%, indicating no light is favored in the capsaicin synthesis by Jalapeno pepper. Increasing the shaking speed from 110 to 200 rpm without light enhanced the capsaicin synthesis. Results of this study demonstrate that light condition is the limiting factor in the synthesis of capsaicin in tissue-cultured Jalapeno pepper cells.

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Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 1. Effect of Synthesis Conditions

  • Seo, Hee Sung;Lee, Hyun Kyung;Yoo, Eui Sang
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.229-244
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    • 2015
  • The effects of synthesis conditions on characteristics of the calcium-azo complex pigment, C.I. Pigment Red 57:1, were studied. It was mainly considered that the industrially required synthesis conditions for lowering electrical conductivity of the pigment solution keeping pigment quality such as particle size and color characteristics. Three parameters were chosen as control factors during the synthesis. The first was the amount of hydrochloric acid added to transform sodium nitrite into nitrous acid. The second was the amount of calcium chloride added to insolubilize the synthesized azo dye. The final factor was pH control during the coupling reaction. The electrical conductivity and pigment aggregate particle size were dependent on the amount of hydrochloric acid and calcium chloride. Higher HCl concentration gave brighter yellowish-red color because of smaller particle aggregate size and narrower size distribution. Amount of charged ions in the synthesis process might affect the "lake" formation resulting different particle aggregate size and color shade.

A Study on TSIUVC Approximate-Synthesis Method using Least Mean Square (최소 자승법을 이용한 TSIUVC 근사합성법에 관한 연구)

  • Lee, See-Woo
    • The KIPS Transactions:PartB
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    • v.9B no.2
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    • pp.223-230
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    • 2002
  • In a speech coding system using excitation source of voiced and unvoiced, it would be involves a distortion of speech waveform in case coexist with a voiced and an unvoiced consonants in a frame. This paper present a new method of TSIUVC (Transition Segment Including Unvoiced Consonant) approximate-synthesis by using Least Mean Square. The TSIUVC extraction is based on a zero crossing rate and IPP (Individual Pitch Pulses) extraction algorithm using residual signal of FIR-STREAK Digital Filter. As a result, This method obtain a high Quality approximation-synthesis waveform by using Least Mean Square. The important thing is that the frequency signals in a maximum error signal can be made with low distortion approximation-synthesis waveform. This method has the capability of being applied to a new speech coding of Voiced/Silence/TSIUVC, speech analysis and speech synthesis.

Synthesis and surface characterization of mesoporous carbon for the adsorption of methane gas (메탄가스 흡착을 위한 메조포러스 카본 합성과 표면 특성 연구)

  • Park, Sang-Won;Lee, Kamp-Du;Noh, Min-Soo
    • Journal of Environmental Science International
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    • v.22 no.7
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    • pp.837-845
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    • 2013
  • This study was designed to synthesize mesoporous carbon, porous carbonic material and to characterize its surface in an attempt to adsorption methane gas($CH_4$). Synthesis of mesoporous carbon was carried out under two steps ; 1. forming a RF-silica complex with a mold using CTMABr, a surfactant, and TEOS, raw material of silica, and 2. eliminating silica through carbonization and HF treatment. The mesoporous carbon was synthesized under various conditions of synthesis time and calcination. Eight different types of mesoporous carbon, which were designated as MC1, MC2, MC3, MC4, MCT1, MCT2, MCT3, and MCT4, were prepared depending upon preparation conditions. The analysis of mesoporous carbon characteristics showed that the calcination of silica stabilized the mixed structure of silica and carbonic complex, and made the particle uniform. The results also showed that hydrothermal synthesis time did not have a strong influence on the size of pore. The bigger specific surface area was obtained as the hydrothermal synthesis time was extended. However, the specific surface area was getting smaller again after a certain period of time. In adsorption experiments, $CH_4$ was used as adsorbate. For the case of $CH_4$, MCT3 showed the highest adsorption efficiency.

Technology Mapping of Sequential Logic for TLU-Type FPGAs (TLU형 FPGA를 위한 순차회로 기술 매핑 알고리즘)

  • Park, Jang-Hyeon;Kim, Bo-Gwan
    • The Transactions of the Korea Information Processing Society
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    • v.3 no.3
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    • pp.564-571
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    • 1996
  • The logic synthesis systems for table look up(TLU) type field programmable e gate arrays(FPGAs) have so farstudied mostly the combinational logic problem m. This paper presents for mapping a sequential circuit onto a popular table look up architecture, theXilinx 3090 architecture. In thefirst for solving this problem, combinational and sequential elements which have 6 or7 input combinational and sequential elements which haveless thanor equal to 5 inputs. We heavily use the combinational synthesis techniques tosolve the sequential synthesis problem. Our syntheisis approach is very simple, but its results are reasonable. We compare seveal benchmark Examples with sis-pga(map_together and map_separate) synthesis system and the experimental results show that our synthesis system is 17% betterthan sis-pga sequential synthesis system for TLU PGAs.

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Synthesis of Au Nanowires Using S-L-S Mechanism (S-L-S 성장기구를 이용한 양질의 골드 나노선 합성)

  • No, Im-Jun;Kim, Sung-Hyun;Shin, Paik-Kyun;Cho, Jin-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.922-925
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    • 2012
  • Single crystalline Au nanowires were successfully synthesized in a tube-type furnace. The Au nanowires were grown by vapor phase synthesis technique using solid-liquid-solid (SLS) mechanism on substrates of corning glass and Si wafer. Prior to Au nanowire synthesis, Au thin film served as both catalyst and source for Au nanowire was prepared by sputtering process. Average length of the grown Au nanowires was approximately 1 ${\mu}m$ on both the corning glass and Si wafer substrates, while the diameter and the density of which were dependent on the thickness of the Au thin film. To induce a super-saturated states for the Au particle catalyst and Au molecules during the Au nanowire synthesis, thickness of the Au catalyst thin film was fixed to 10 nm or 20 nm. Additionally, synthesis of the Au nanowires was carried out without introducing carrier gas in the tube furnace, and synthesis temperature was varied to investigate the temperature effect on the resulting Au nanowire characteristics.

DNA Repair Synthesis Induced by Bleomycin in HeLa $S_3$ Cells Pretreated with Base Analogs (鹽基相似體를 前處理한 HeLa $S_3$ 細胞에 있어 Bleomycin에 의한 DNA 回復合成)

  • Um, Kyung-Il;Park, Sang-Dai
    • The Korean Journal of Zoology
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    • v.20 no.1
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    • pp.41-48
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    • 1977
  • Dose response of DNA repair synthesis induced by bleomycin was dose-dependent in lower doses, and maximum rate of it at 5 $\\mu$g/ml represents about 15% of total cells analyzed. At higher doses DNA-repair synthesis was reduced and the rate of it remained unchanged even prolonged treatment. Pretreatment with BUdR or IUdR was found to enhance DNA repair synthesis and also to interfere with semiconservative DNA synthesis at higher doses. Time dependence study showed that DNA repair synthesis occurred as long as for 24 hours after removal of bleomycin. These results seem to suggest that bleomycin is not to be an effective chemical in inducing excision repair and that damages induced in DNA by this drug might include not only strand breaks but other types of DNA damage.

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Sensitization Effects of Thymidine Analogs on Methyl Methanesulfonate Induced DNA Repair synthesis (Methyl Methanesulfonate 에 의한 DNA 回復合成에 미치는 Thymidine 相似체體의 感受性 효과)

  • Park, Sang-Dai;Um, Kyung-Il
    • The Korean Journal of Zoology
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    • v.18 no.3
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    • pp.131-140
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    • 1975
  • Dose response for the nuscheduled DNA synthesis induced by various concentration of MMS was dose dependent and directly proportional to dose increased. Time dependence of unscheduled DNA synthesis was continued up to 4 hours, with the peak appearing 2$\\sim$3 hours after treatment with MMS and $^3 H$-thymidine labeling. Single treatment with BUdR or IUdR does not induce unscheduled DNA synthesis. BUdR and IUdR greatly enhanced MMS-induced unscheduled DNA synthesis, but the dose responses were different from that of single treatment with MMS. IUdR was found to be more effective sensitizer on MMS-induced unscheduled DNA synthesis.

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Organotemplate-free synthesis of ZSM-5 membrane for pervaporation dehydration of isopropanol

  • Li, Jiajia;Li, Liangqing;Yang, Jianhua;Lu, Jinming;Wang, Jinqu
    • Membrane and Water Treatment
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    • v.10 no.5
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    • pp.353-360
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    • 2019
  • ZSM-5 membrane was prepared on tubular macroporous ${\alpha}$-alumina support using a different synthesis route. The effects of organic template agent and Si/Al ratio of the synthesis gel on morphology, structure, and separation performance of the ZSM-5 membrane used for dehydration of isopropanol were investigated. High water perm-selectivity ZSM-5 membrane with a thickness of about $3.0{\mu}m$ and a low Si/Al ratio of 10.1 was successfully prepared from organotemplate-free synthesis gel with a molar composition of $SiO_2$ : $0.050Al_2O_3$ : $0.21Na_2O$ : NaF : $51.6H_2O$ at $175^{\circ}C$ for 24 h. The ZSM-5 membrane exhibited high pervaporation performance with a flux of $3.92kg/(m^2{\cdot}h)$ and corresponding separation factor of higher than 10,000 for dehydration of 90 wt.% isopropanol/water mixture at $75^{\circ}C$.

Effects of Pre-Annealing Treatment on the Combustion Synthesis of Ni3Al Intermetallics Coating (Ni-25at.%Al 금속간화합물의 연소합성반응에 미치는 사전 Annealing 처리의 영향)

  • Lee, Han-Young;Mo, Nam-Kyu
    • Tribology and Lubricants
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    • v.37 no.2
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    • pp.62-70
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    • 2021
  • The problem with intermetallics coating using the heat of molten casting is that the heat generated during combustion synthesis dissolves the coating and the substrate metal. This study investigates whether pre-annealing before synthesis can control the reaction heat, with the aim of Ni3Al coating on the casting surface. Therefore, the effects of the annealing temperature and time on the combustion synthesis behavior of the powder compact of Ni-25at%Al after annealing were investigated. As results, the reaction heat when synthesized decreased as the annealing temperature was high and the annealing time was longer. This was attributed to the fact that Al was diffused to Ni particles during low temperature annealing and intermediate Ni-Al compounds were formed during high temperature annealing. After combustion synthesis, however, it was found that their microstructures were almost identical except for the amount of intermediate intermetallics. Furthermore, an annealing temperature above 450℃, at which intermediate compounds begin to form, is needed to prevent the dissolving problem during synthesizing. The intermetallics synthesized after annealing at higher temperature and prolonger annealing time showed a good wear resistance. This might be because much intermediate intermetallics of high hardness were remained in the microstructure.