• Applied Science and Convergence Technology
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• 제23권6호
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• pp.317-327
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• 2014

In order to develop nano-devices with much lower power consumption for beyond-CMOS applications, the fundamental understanding and precise control of the electronic properties of ultrathin transition metal oxide (TMO) films are strongly required. The metal-insulator transition (MIT) is not only an important issue in solid state physics, but also a useful phenomenon for device applications like switching or memory devices. For potential use in such application, the electronic structures of MIT, observed for TMO nano-structures, have been investigated using a synchrotron radiation angle-resolved photoelectron spectroscopy system combined with a laser molecular beam epitaxy chamber and a scanning photoelectron microscopy system with 70 nm spatial resolution. In this review article, electronic structures revealed by soft X-ray nano-spectroscopy are presented for i) polarity-dependent MIT and thickness-dependent MIT of TMO ultrathin films of $LaAlO_3/SrTiO_3$ and $SrVO_3/SrTiO_3$, respectively, and ii) electric field-induced MIT of TMO nano-structures showing resistance switching behaviors due to interfacial redox reactions and/or filamentary path formation. These electronic structures have been successfully correlated with the electrical properties of nano-structured films and nano-devices.

• Journal of the Korean Wood Science and Technology
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• 제50권5호
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• pp.353-364
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• 2022

The crystalline domain of thermosetting urea-formaldehyde (UF) resins at low formaldehyde-to-urea (F/U) molar ratios (≤ 1.0) is known to be responsible for their poor performance as wood adhesives. Crystallization has been observed in 1.0 F/U UF resins during the addition reaction stage and at the end of the synthesis process (neat UF resins). The crystallinity and X-ray diffraction (XRD) spectra of the uncured neat UF resins, on the other hand, differed significantly from those of the cured neat UF resins, raising the possibility that their crystal structures were also different. This study demonstrates for the first time that the crystalline domains in 1.0 F/U UF resins generated from uncured and cured samples are identical. Despite having a lower crystallinity value, the synchrotron XRD patterns of purified neat UF resins were equivalent to the XRD patterns of cured neat UF resins. Transmission electron microscope images of the cured UF resins showed that the crystals were lamellar structures. This finding suggests that the crystal at low molar ratio UF resins are isotropic polycrystals with random orientation.

• 천문학회보
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• 제43권2호
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• pp.43.1-43.1
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• 2018

Young pulsar wind nebulae, powered by energetic central pulsars, are often observed as bright extended sources in the X-ray band. They are believed to accelerate electrons and positrons to very high energy and can possibly explain the positron excess observed by Fermi and AMS. The electron distribution in these PWNe can be best studied by X-ray satellites because emission in the X-ray band is produced by direct synchrotron radiation of the electrons and positrons. We present NuSTAR studies of PWNe and discuss the implication. Future studies to help further our understanding of particle acceleration will be briefly discussed.

• Macromolecular Research
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• 제14권1호
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• pp.45-51
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• 2006

We conducted simultaneous, small-angle, X-ray scattering/differential scanning calorimetry (SAXS/DSC) and simultaneous, wide-angle, X-ray scattering (WAXS)/DSC measurements for a polymer blend of poly($\varepsilon$-caprolactone)/poly(ethylene glycol)(PCL/PEG). The time-dependent SAXS/DSC and WAXS/DSC results, measured while the system was quenched below the melting temperature of PCL from a melting state, revealed the competitive behavior between liquid-liquid phase separation and crystallization in the polymer blend. The time-dependent structural evolution extracted from the SAXS/WAXS/DSC results can be characterized by the following four stages in the PCL crystallization process: the induction (I), nucleation (II), growth (III), and late (IV) stages. The influence of the liquid-liquid phase separation on the crystallization of PCL was also observed by phase-contrast microscope and polarized microscope with 1/4$\lambda$ compensator.

• 보존과학회지
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• 제36권1호
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• pp.1-14
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• 2020

This study investigates the crystallinity distribution of ancient silk. Owing to the inherent multi-hierarchical structure of silk protein and the complicated structural changes that occur due to various burial environments, it is challenging but worthwhile to study ancient silk ageing behavior, which is based on the fact that ageing begins with a single fiber and then spreads to a whole fabric. Crystallinity was one of the most effective indicators found to reveal the ageing status of silk. Therefore, a synchrotron radiation-based X-ray diffraction(SR-XRD) method was employed to study the crystallinity distribution of single fibers of ancient silk unearthed from seven archaeological sites in China from historical periods including the warring states, Han dynasty, Song dynasty, and Ming dynasty. In comparison, the conventional X-ray diffraction method, which uses large amounts of samples, was also performed to determine the integral crystallinity of ancient silk. Thermal stability experiments by thermogravimetry(TG) as well as morphology observations by scanning electron microscopy(SEM) and optical microscopy(OM) all confirmed the deterioration of ancient silk. Moreover, the ageing mechanism of ancient silk was proposed with the assistance of an artificial ageing study. The results confirmed the effectiveness of SR-XRD as an ageing indicator, revealing the crystallinity distribution. This research could provide motivation to determine the deterioration status of ancient silk, and would also aid in explaining the fragility of ancient silk due to ageing.

• Current Applied Physics
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• 제18권11호
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• pp.1218-1224
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• 2018

Pressure-dependent structural and morphological changes of two amphibole minerals, tremolite and actinolite, were investigated up to 7.0 GPa using synchrotron X-ray powder diffraction underthree different pressure transmission media (PTM): water (W), $CO_2$ and silicone oil (SI). The elastic response of tremolite and actinolite are found to be dependent on the PTM used. When using water (W) as PTM, tremolite and actinolite show normal volume contractions with bulk moduli of 74(1) and 78(1) GPa, respectively. When using $CO_2$ as PTM, we observe the formation of calcite from tremolite above 3.8(1) GPa, whereas actinolite did not show any carbonation reaction. Under silicone oil PTM, we observe modulated volume contraction behaviors in both samples, compared to water and $CO_2$ PTM, with bulk moduli in the order of 90(1) and 94(4) GPa for tremolite and actinolite, respectively.

• 한국주조공학회지
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• 제30권1호
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• pp.5-13
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• 2010

This article aims to introduce the synchrotron radiation for its utilization in the casting and solidification fields as an unique tool for observation of real time phenomena of molten metal during solidification. General features of the synchrotron radiation were briefly introduced for readers in the casting and solidification fields, with no background regarding to synchrotron radiation. And basic principles of imaging technologies using synchrotron light for in-situ observation of molten metal were explained together with exemplary research works, which were reported on the casting and solidification fields in recent years. As a practical guide, real time observation of Al-Si casting alloy was introduced with experimental facilities, image acquisition, and processing together with representative results.

• International Journal of Concrete Structures and Materials
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• 제7권2호
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• pp.95-110
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• 2013

We report various synchrotron radiation laboratory based techniques used to characterize cement based materials in nanometer scale. High resolution X-ray transmission imaging combined with a rotational axis allows for rendering of samples in three dimensions revealing volumetric details. Scanning transmission X-ray microscope combines high spatial resolution imaging with high spectral resolution of the incident beam to reveal X-ray absorption near edge structure variations in the material nanostructure. Microdiffraction scans the surface of a sample to map its high order reflection or crystallographic variations with a micron-sized incident beam. High pressure X-ray diffraction measures compressibility of pure phase materials. Unique results of studies using the above tools are discussed-a study of pores, connectivity, and morphology of a 2,000 year old concrete using nanotomography; detection of localized and varying silicate chain depolymerization in Al-substituted tobermorite, and quantification of monosulfate distribution in tricalcium aluminate hydration using scanning transmission X-ray microscopy; detection and mapping of hydration products in high volume fly ash paste using microdiffraction; and determination of mechanical properties of various AFm phases using high pressure X-ray diffraction.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2002년도 추계학술대회 논문집
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• pp.31-34
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• 2002

Imaging techniques using x-ray beam at high energies (>6KeV) such as contact radiography, projection microscopy, and tomography have been used to nondestructively discern internal structure of objects in material science, biology, and medicine. This paper introduces the x-ray micro-imaging method using 1B2 micro-probe line of PAL (Pohang Accelerator Laboratory). Cross-sectional information on low electron density materials can be obtained by probing a sample with coherent synchrotron x-ray beam in an in-line holography setup. Living organism such as plants, insects are practically transparent to high energy x-rays and create phase shift images of x-ray wave front. X-ray micro-images of micro-bubbles of $20\~120\;{\mu}m$ diameter in an opaque tube were recorded. Clear phase contrast images were obtained at Interfaces between bubbles and surrounding liquid due to different decrements of refractive index.

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.145-150
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• 2022

움직이는 접촉선에서의 계면 거동을 이해하기 위해 많은 연구자들은 동적접촉각에 대한 연구를 지속적으로 연구해 왔다. 하지만 가시화 기술의 한계로 선행연구에서의 동적접촉각에 대한 실험은 일반적으로 친수성 미세관에서 가시광선 기반으로 실험이 수행되었다. 하지만, 최근 다양한 연구 및 산업 분야에서 소수성 미세관에서의 동적접촉각에 대한 연구의 필요성이 대두되고 있다. 따라서, 본 연구에서는 높은 공간 및 시간 분해능을 갖는 방사광 X-선 영상법을 이용하여 소수성 마이크로 튜브 내 물-글리세롤 혼합물 슬러그의 동적접촉각을 측정하였으며, 이를 바탕으로 기존의 동적 접촉각 실험 상관식을 검증하였다.