• Title/Summary/Keyword: Swelling properties

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Application of NMR Microscopy for the Study of the Swelling Effect in Biopolymers (생체고분자의 팽윤현상연구를 위한 핵자기공명 현미영상법의 응용)

  • 이동훈;김승수
    • Journal of Biomedical Engineering Research
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    • v.18 no.2
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    • pp.167-172
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    • 1997
  • Novel measurement method has been performed for the noninvasive study of the swelling effect detected in hydrophilic polymers using Magnetic Resonance Microscopy. iN NMR images were acquired to measure geometric changes due to the swelling effect occurred in the polymer specimens. In addition to the geometric changes, the water ingress process was visualized noninvgsively. The measurement method performed .in the present study utilized some of NMR's valuable properties, both noninvasiveness and parameter selectivity. It is believed that the method used in the present study may be applicable to the study of biopolymers in which noninvasiveness is particularly important.

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Quality Characteristics and Changes in GABA Content and Antioxidant Activity of Noodle Prepared with Germinated Brown Rice (발아현미 첨가에 따른 국수의 제조 특성과 GABA 함량 및 항산화 활성 변화)

  • Kong, Su-Hyun;Lee, Jun-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.2
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    • pp.274-280
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    • 2010
  • This study was to investigate the quality characteristics of noodles prepared with germinated brown rice and rice bran, and to determine the changes in GABA content and antioxidant activity of the noodles. These noodles were evaluated for cooking properties (cooking loss, swelling index, water holding capacity), total polyphenols, antioxidant activities (radical scavenging of ABTS and DPPH), and GABA contents. The addition of germinated rice bran in the range of 5, 10, and 15% showed a significant influence on cooking loss, although no effect on swelling index was observed. The raw and cooked noodles containing germinated brown rice and rice bran contained more GABA contents (2751.6~4176.7 and 5522.0~9617.8 nmol/20 g of fresh noodle, respectively) than those of non-germinated brown rice and rice bran. Noodles made with germinated brown rice and rice bran had similar total polyphenolics contents and antioxidant activities compared to noodles made with non-germinated brown rice and rice bran. Overall, the germinated brown rice could be used as a good ingredient to increase the nutritional value and antioxidant properties of wheat flour noodle without affecting the cooking properties.

Assessment of Hydraulic Properties of Bentonite Swelling Agents by Blending with Additives (첨가제 혼합에 의한 벤토나이트 팽윤재의 수리학적 특성평가)

  • Jeon, Han-Yong;Park, Yeoung-Mog;Mok, Mun-Sung
    • Journal of the Korean Geosynthetics Society
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    • v.1 no.1
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    • pp.43-51
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    • 2002
  • In this study, free swell index of betonite was examined in several regeants; distilled water, leachate, seawater and 3% NaCl solution. Free swell index values of bontonite to be added Poly(acrlylic acid), PYA(Polyvinyl Alcohol) or SCMC (Sodium Carboxymethyl Cellulose) were evaluated and compared. From this, it was confirmed that hydraulic conductivities of GCL in seawater were examined and the hydraulic conductivities of GCL in seawater were compared to those in distilled water. The average values of free swell indices of bentonite were decreased in order of distilled water>leachate>seawater. It was shown that no significant differences were occurred for free swell index between seawater and 3% NaCl solution. For bentonite to be added PVA, the other reagents except distilled water didn't affect increase of swelling. Swelling properties of bentonite to be added SCMC were improved except 3% NaCl solution.

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Evaluation of Physical Properties as Magnesium Stearate Blendedin Hydrophilic Matrix Tablets

  • Choi, Du-Hyung;Jung, Youn-Jung;Wang, Hun-Sik;Yoon, Jeong-Hyun;Jeong, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.41 no.2
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    • pp.83-90
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    • 2011
  • Main objectives of this study were to investigate the effects of a lubricant, magnesium stearate, as blended in a hydrophilic matrix tablet and to identify significant factors using a tablet ejection force and a swelling property. The characteristics of tablet ejection were evaluated with three different compression forces (30, 40, and 60 MPa) and two controlled factors, amount of magnesium stearate and its mixing time. A hydrophilic model drug (terazosin HCl dihydrate) was regarded as a default factor. Tablet swelling was also evaluated. The optimal amount of PEG compared to PEO was set to be 88.50% w/w. As the amount of magnesium stearate was varied from 0.79% to 2.20% w/w, the amount of PEO and PEG was adjusted to meet the tablet's total weight while maintaining the ratio between the two excipients constant. As the mixing time of magnesium stearate was increased, the tablet ejection force and the swelling property were decreased. As the amount of magnesium stearate was increased, the tablet ejection force and the swelling property were decreased since the increased mixing time and the amount of magnesium stearate induced hydrophobic properties of the matrix tablet more effectively. The ejection force of the tablet increased as a result of increase in the compression force, which means that the breaking of tablet/die-wall adhesion energy was also increased when the compression energy was increased. The results gavea valuable guide how to choose suitable amount of the lubricant with processing conditions for the development of hydrophilic matrix formulations.

Beating Properties with Swelling agent and Concentration for Preparation of MicroFibrillated Cellulose (MFC) (MicroFibrillated Cellulose (MFC) 제조를 위한 전처리 팽윤제의 종류와 농도에 따른 펄프의 고해 특성)

  • Ahn, Eun-Byeol;Jung, Jin-Dong;Jung, Soo-Eune;Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.3
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    • pp.3-10
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    • 2015
  • In this study, we evaluated properties of pulp treated with swelling agent and swelling concentration. We used swelling agent, such as NaOH, DMSO, urea. One of them, pulps treated with NaOH from 0 to 5% measured WRV, beating efficiency, crystallinity and aspect ratio. We identified that NaOH when freeness reaches 100mL CSF was the shortest, on the other hand, WRV didn't change. Because NaOH is good beating efficiency, when pulp treated with various concentration of NaOH from 0 to 5%, pulp treated 1% NaOH was best beating efficiency. However, WRV, crystalline structure and crystallinity didn't change. The more NaOH concentration increased, the more aspect ratio increased, but when NaOH concentration exceeds 3%, aspect ratio decreased. As a result, pulp treated with 1% NaOH was the greatest beating efficiency and WRV, chemical structure didn't change.

Partially Hydrolyzed Crosslinked Alginate-graft-Polymethacrylamide as a Novel Biopolymer-Based Superabsorbent Hydrogel Having pH - Responsive Properties

  • Pourjavadi A.;Amini-Fazi M. S.;Hosseinzadeh H.
    • Macromolecular Research
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    • v.13 no.1
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    • pp.45-53
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    • 2005
  • In this study, a series of highly swelling hydrogels based on sodium alginate (NaAlg) and polymethacryl­amide (PMAM) was prepared through free radical polymerization. The graft copolymerization reaction was performed in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator and N,N'-methylenebis­acrylamide (MBA) as a crosslinker. The crosslinked graft copolymer, alginate-graft-polymethacrylamide (Alg-g­PMAM), was then partially hydrolyzed by NaOH solution to yield a hydrogel, hydrolyzed alginate-graft-poly­methacrylamide (H-Alg-g-PMAM). During alkaline hydrolysis, the carboxamide groups of Alg-g-PMAM were converted into hydrophilic carboxylate anions. Either the Alg-g-PMAM or the H-Alg-g-PMAM was characterized by FTIR spectroscopy. The effects of the grafting variables (i.e., concentration of MBA, MAM, and APS) and the alkaline hydrolysis conditions (i.e., NaOH concentration, hydrolysis time, and temperature) were optimized systematically to achieve a hydrogel having the maximum swelling capacity. Measurements of the absorbency in various aqueous salt solutions indicated that the swelling capacity decreased upon increasing the ionic strength of the swelling medium. This behavior could be attributed to a charge screening effect for monovalent cations, as well as ionic cross-linking for multivalent cations. Because of the high swelling capacity in salt solutions, however, the hydrogels might be considered as anti-salt superabsorbents. The swelling behavior of the superabsorbing hydrogels was also measured in solutions having values of pH ranging from 1 to 13. Furthermore, the pH reversibility and on/off switching behavior, measured at pH 2.0 and 8.0, suggested that the synthesized hydrogels were excellent candidates for the controlled delivery of bioactive agents. Finally, we performed preliminary investigations of the swelling kinetics of the synthesized hydrogels at various particle sizes.

Comparison of Physicochemical Properties of Hard and Floury Type Rice Flour by Dry Heat Treatment (건열처리에 따른 경질미와 분질미 쌀가루의 이화학적 특성 비교)

  • Jung, Hee Nam
    • Journal of the Korean Society of Food Culture
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    • v.36 no.5
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    • pp.484-491
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    • 2021
  • This study investigated the effect of dry heat treatment (DHT) on the physicochemical properties of hard type (HR) and floury type (FR) rice to improve the processing aptitude of rice flour. The rice flour was heated at 130℃ for 0, 2 and 4 hours, and the color value, water absorption index (WAI), water soluble index (WSI), swelling power, solubility, pasting properties, particle shape and the X-ray diffraction were measured. After DHT, the L value of rice flour decreased, and the b value increased. The WAI, WSI, swelling power and solubility of HR and FR increased with the increase of treatment time. The cold viscosity and setback increased, while breakdown decreased. Cracks and lumps formed with fine particles were observed. The X-ray diffraction pattern was A-type, while the diffraction intensity decreased. According to the results of the two-way analysis of variance (ANOVA) test, the hydration and pasting properties were significantly different between HR and FR and were affected by DHT time. The results suggest that the properties of modified rice flour by DHT can be used in the food industry.

Preparation and Characterization of Biodegradable Hydrogels for Tissue Expander Application (조직 확장기용 생분해성 하이드로젤의 제조 및 특성분석)

  • Yuk, Kun-Young;Kim, Ye-Tae;Im, Su-Jin;Garner, John;Fu, Yourong;Park, Ki-Nam;Park, Jeong-Sook;Huh, Kang-Moo
    • Polymer(Korea)
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    • v.34 no.3
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    • pp.253-260
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    • 2010
  • In this study, we prepared and evaluated a series of biocompatible and biodegradable block copolymer hydrogels with a delayed swelling property for tissue expander application. The hydrogels were synthesized via a radical crosslinking reaction of poly(ethylene glycol) (PEG) diacrylate and poly(D,L-lactide-co-glycolide)-poly(ethylene glycol)-poly(D,L-lactide-co-glycolide)(PLGA-PEG-PLGA) triblock copolymer diacrylate as a swelling/degradation controller (SDC). For the synthesis of various SDCs that can lead to different degradation and swelling properties, various PLGA-PEG-PLGA triblock copolymers with different LA/GA ratios and different PLGA block lengths were synthesized and modified to have terminal acrylate groups. The resultant hydrogels were flexible and elastic even in the dry state. The in vitro degradation tests showed that the delayed swelling properties of the hydrogels could be modulated by varying the chemical composition of the biodegradable crosslinker (SDC) and the block ratio of SDC/PEG. The histopathologic observation after implantation of hydrogels in mice was performed and evaluated by macrography and microscopy. Any significant inflammation or necrosis was not observed in the implanted tissues. Due to their biocompatibility, elasticity, sufficient swelling pressure, delayed swelling and controllable degradability, the hydrogels could be useful for tissue expansion and other biomedical applications.

Development of heat insulating boards by waste-newspaper (폐신문지에 의한 단열보드의 개발)

  • 정승수;이원희;장준복;이종윤
    • Journal of the Korea Furniture Society
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    • v.10 no.1
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    • pp.95-102
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    • 1999
  • The objective of this paper was the development of boards made from waste newspapers. The boards were produced from particle ONP(old newspaper) to reduce energy consumption in the board production process. ONP boards bonded with polyurethan adhesives(PU) were produced on a laboratory scale, and their physical and mechanical properties were examined. The average density of the ONP was $0.48g/cm^3$, and the densities of the boards were $0.50-0.90g/cm^3$. Therefore, th compaction ratios of the boards were in the range of 1.04-1.88. The results obtained were as follows: 1) An increase in board density results in a corresponding improvement in bending properties. 2) An increase in board density results in increased thermal conductivity. 3) In this research, ONP board can be used only for interior applications. To gain exrerior applications, the dimensional stability properties(thickness swelling and water absorption) need to be improved.

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Swelling and Thermal Properties of Crosslinked Poly(2-Hydroxyethyl Methacrylate) Hydrogels (가교된 폴리(2-히드록시에틸 메타크릴레이트)수화겔의 팽윤성 및 열적 성질)

  • Seong, Yong-Gil;Nam, Gi-Ho;Kim, Gye-Yong
    • Journal of Biomedical Engineering Research
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    • v.8 no.1
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    • pp.13-28
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    • 1987
  • Crosslinked poly(2-hydroxyethylmethacrylate) has been prepared by polymerizing 2-hydroxyethyl methacrylate(HEMA) with crosslinkers such as ehyleng glycol dime- thacrylate(EGDMA), tetraethylene glycol dimethacrylate(TEGDMA), tetraethylene glycol diacrylate(TEGDA), divinyl benzene(DVB), and N, N-methylenebisacry- lamide(MAB) in the presence of initiator $\alpha$ , $\alpha$ -azobisisobutyronitrile at 60。C, The synthesized copolymers were identified by FT-lR spectrophotomether. The swelling properties of the crosslinked copolymers in various solvents such as water, methanol, ethanol, n-propanol, and n-butanol were investigated at different temperatures. The thermal properties of the crosslinked coplymers were also measured by differential scanning calorimetry(DSC) and thermogravimetry(TG)

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