• Title/Summary/Keyword: Swelling Ratio

Search Result 432, Processing Time 0.029 seconds

Effects of neutron irradiation on densities and elastic properties of aggregate-forming minerals in concrete

  • Weiping Zhang;Hui Liu;Yong Zhou;Kaixing Liao;Ying Huang
    • Nuclear Engineering and Technology
    • /
    • v.55 no.6
    • /
    • pp.2147-2157
    • /
    • 2023
  • The aggregate-forming minerals in concrete undergo volume swelling and microstructure change under neutron irradiation, leading to degradation of physical and mechanical properties of the aggregates and concrete. A comprehensive investigation of volume change and elastic property variation of major aggregate-forming minerals is still lacking, so molecular dynamics simulations have been employed in this paper to improve the understanding of the degradation mechanisms. The results demonstrated that the densities of the selected aggregate-forming minerals of similar atomic structure and chemical composition vary in a similar trend with deposited energy due to the similar amorphization mechanism. The elastic tensors of all silicate minerals are almost isotropic after saturated irradiation, while those of irradiated carbonate minerals remain anisotropic. Moreover, the elastic modulus ratio versus density ratio of irradiated minerals is roughly following the density-modulus scaling relationship. These findings could further provide basis for predicting the volume and elastic properties of irradiated concrete aggregates in nuclear facilities.

Characterization of Hyaluronic Acid Membrane Cross-linked with Lactide (락타이드로 가교시킨 히아루론산 막의 특성)

  • Kwon, Ji-Young;Cheong, Seong-Ihl
    • Polymer(Korea)
    • /
    • v.29 no.6
    • /
    • pp.599-604
    • /
    • 2005
  • The hyaluronic acid (HA) with excellent biocompatibility has been combined with lactide, the ester dimer of polylactide, with good biodegradability to produce biocompatible materials which can control the period of degradation in a human body. By freeze frying method, HA and lactide were crosslinked with crosslinking agent, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide (EDC). Degree of lactide and EDC reaction was determined by the analysis of nuclear magnetic resonance spectroscopy. Both lactyl group and EDC conversion increased as the mole ratio of lactide to HA increased from 5 to 13. The membrane swelled less and became more brittle with the more addition of lactyl group resulting from the higher mole ratio of lactide to HA. Swelling ratio decreased and tensile modulus increased due to the more addition of lactyl group as the EDC concentration increased or reaction temperature decreased. Drug release experiment from various membranes with different degree of crosslinking showed that permeability decreased with increasing degree of crosslinking. The degradation became slower with the more addition of lactyl group. Mechanical property and degradation rate of the synthesized membrane were shown to be controlled through adjusting operation parameters such as mole ratio, temperature, and crosslinking agent concentration.

Rheological Evaluation of Cooked Rice with Milk (우유첨가 취반미의 물성에 관한 연구)

  • 김경자;강선희;곽연주
    • Korean journal of food and cookery science
    • /
    • v.7 no.4
    • /
    • pp.71-86
    • /
    • 1991
  • This study was attempted to enhance nutritional value of cooked rice by adding milk in cooking water. Cooked and soaked rice with five different levels of milk in cooking water (0%, A: 30%, B: 50%, C: 70%, D: 100%, E) was tested for rheological parameters, fine structural changes, sensory evaluation. 1. Water absorbance of raw rice in cooking water with varying amountes of milk, was tested at $5^{\circ}C$ and $15^{\circ}C$ for 2 hours. Water absorption ratio was decreased as milk content was increased and soaking temperature was low. Time for maximum water absorption of sample A was 40 min at 1$15^{\circ}C$ but for sample B to D, it was not reached until 120 min. 2. Electronmicroscopic observation revealed that starch granules of rice lost their regular forms by soaking for 90 minutes, but recovered most of initial regularity after 24 hours. Increase in milk content of soaking water decreased marginal sharpness of the starch granule, presumably due to reduced swelling of the granule. 3. Degree of gelatinization of cooked rice was highest in sample A and progressively decreased as milk content was increased. It was, however, increased in all samples when the cooking water to rice ratio was raised from 160% to 180%. During 4 hour storage, rates of retrogradation were not different between A and B samples, but those of C, D and E were about 2.5 times higher than A and B under the optimal condition of 170% cooking water to rice ratio. This was in the order reverse to hardness order of AC>A, D>E at cooking water to rice ratios of 160% and 170%, above which A sample surpassed the rest of samples. 4. Sensory evaluation conducted by fifteen university students as panelists showed that there were more significant differences among five samples in flavour, texture than appearance and a notable preference for b and C over A, D and E.

  • PDF

Effect of flour and frying temperature on quality of Gaeseong-Juak(doughnut of waxy rice) (밀가루와 튀김온도가 개성주악의 품질에 미치는 영향)

  • 김명애
    • Korean journal of food and cookery science
    • /
    • v.16 no.4
    • /
    • pp.316-320
    • /
    • 2000
  • This study was carried out to standardize the recipe of Gaeseong-Juak. The formation and quality of the Juak were investigated under different treatment conditions. 1. The high ratio of medium flour(20%) in the flour mixture resulted in poor swelling. 2. The flour mixture with 10% strong flour showed higher volume of Gaeseong-Juak compared with the 10% mixture of medium flour, but the score of sensory evaluation was low. 3. The addition of Makkoli in the dough did not give significant difference in the formation of Juak, but the sensory score was low. 4. The deep-frying temperature in the range of 150$\^{C}$ to 170$\^{C}$ allowed the greatest swelling of Gaeseong-Juak, but the highest quality score was obtained at 160$\^{C}$ treatment. Overall, the best preparation condition of Gaeseong-Juak was that the mixture of waxy rice flour with 10% medium flour was kneaded with Makkoli and fried at 160$\^{C}$.

  • PDF

Effect of Water State in Electroactive Chitosan/Poly (Diallyldimethylammonium Chloride) Hydrogels on Bending Behavior at Various pH Conditions (키토산/폴리디아릴디메틸암모늄클로라이드 전기감응성 고분바 하이드로겔의 굽힘 거동에서 물 상태에 따른 영향 분석)

  • Yoon, Seong-Gil;Kim, Seon-Jeong;Kim, In-Young;Kim, Sun-I.
    • Journal of Biomedical Engineering Research
    • /
    • v.28 no.3
    • /
    • pp.344-347
    • /
    • 2007
  • A interpenetrating polymer network (IPN) hydrogel, composed of chitosan (CS) and poly(diallydimethylammonium chloride) (PDADMAC) was prepared, which exhibited electrical sensitive behavior. The swelling behavior of the CS/PDADMAC SIPN hydrogel was studied by immersion of the gel into various pH buffer solutions, and their stimuli response in electric fields also investigated. In order to clarify the relationship between the equilibrium swelling ratio and bending behavior of the SIPN hydrogels, the state of water in the SIPN hydrogel was also investigated using differential scanning calorimetry (DSC).

PVT Measurement and Phase Transition Behavior of Dimer Liquid Crystals (이량체액정의 PVT측정과 상전이 거동)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.14 no.1
    • /
    • pp.17-29
    • /
    • 1996
  • N-substituted acrylamide hydrogel is reported to have the feature of bing transparent and sensitive enough to response to a temperature stimulus below the temperature of phase transition. Especially at the near of 35 C it becomes shrunk and opaque very quickly. It has also the characteristic of reversing swelling and shrinking. The experiment showed that it is possible to produce a functional gel of super water absorption with the process of free radical polymerizing PVA(polyvinylalcohol) and PAA(polyacrylamide), and crosslinking. The ratio of shrinking and swelling caused by copolymerization rises 10% to 80% at the each temperature of 20 C, 30 C, 40 C, respectively. Phase transition temperature of this gel by copolymerization is50 C while that of ordinary N-substituted acrylamides is between 32~35 C. This temperature reaches the rearing limit of animals and plants so that volumetric transition polymer gel can be ulilized in varying fields such as agriculture/gardening which are water-using field, on-off switch sensing temperature and volumetric variation, processing of liquid wastes and civil engineering works, architecture and electronics. We have no doubt that this material will be the high-functional resin in the hi-tech age of the near future.

  • PDF

The Effects of Chelidonii Herba Extract on the Cell Mediate and Humoral Immune Responses in Mice (백굴채가 마우스의 세포성 및 체액성 면역반응에 미치는 영향)

  • Park, Ji-Young;Kim, Nam-Joong
    • Journal of Environmental Health Sciences
    • /
    • v.31 no.1
    • /
    • pp.66-72
    • /
    • 2005
  • The effects of Chelidonii Herba on the cell mediate and humoral immune responses were investigated in ICR mice. ICR mice received intraperitoneal injection of methanol extracts (ether fraction, buthanol fraction, water fraction) for 5 days before sensitization. The change of body weight (%), the organ weight ratio (%), the numbers of RBC and WBC, the ear swelling by dinitrofluorobenzene, the titers of hemagglutination (HA) and hemolysin (HY) to SRBC were determined. The results were as follows; 1. The change of body weight (%) showed a tendency of increasing generally. 2. The weight of spleen (%) revealed decreasing but that of thymus revealed increasing. 3. Ear swelling was maxium at 48 hours after challenge and was significantly decreased in the groups treated with Ether, Buthanol and Water. 4. The numbers of RBC and WBC were decreased generally. 5. HA and HY titers were decreased significantly.

Preparation and Characterization of Composite Membrane for Low Temperature Direct Methanol Fuel Cells

  • Huang Sheng-Jian;Lee Hoi-Kwan;Kang Won-Ho;Wu Qing
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.11 no.4 s.33
    • /
    • pp.69-73
    • /
    • 2004
  • A series of $H_3PO_4$-doped composite membranes based on poly(vinyl alcohol)(PVA) and silica have been prepared by sol-gel process. The proton conductivity, as well as properties of swelling, methanol permeation, was measured in this study. The proton conductivity increased with the molar ratio of $H_3PO_4$ to silica. With the silica content increasing, swelling degree decreased and methanol permeability showed a slight increase. It suggested that the former was mainly determined by hydrophilicity of the membrane, while the latter was dominated by the interconnectivity of matrix. According to the value of on, the optimal conformations of these composite membranes were 60, 70, 80 wt.$\%$ of PS-x in membranes, where x were 1.5, 1.0, and 0.5, respectively. These composite membranes were thermal stability up to $200^{\circ}C$.

  • PDF

Pervaporation Separation of Trace VOCs from Water Through PDMS Membranes

  • Rhim, Ji-Won;Kwon, Young-Mann
    • Korean Membrane Journal
    • /
    • v.1 no.1
    • /
    • pp.73-80
    • /
    • 1999
  • The removal of trace chlorinated and aromatic hydrocarbons from water by a pervaporation technique has been carried out through poly (dimethylsiloxane) membrane which had been fabricated by the addition crosslinking reaction. This study dealt with the swelling and permeation behaviors of the PDMS membranes with dichloroethane trichloroethane and toluene aqueous solutions. The swelling ratio in the toluene aqueous solution was much higher than those in the chloroethane solutions at all of the operating temperatures and concentrations. The solubility parameter theory was introduced to interpret the affinity between permeates and a membrane material and in all cases this approach seemed to be proper. It was suggested that the existence of water clusters in the membrane due to the hydrophobic characteristics of the membrane made the size of the permeating water larger resulting in suppressing water permeation and increasing enrichment of the organic components. The permeation behaviors at different membrane thicknesses were indirectly interpreted in terms of the effect of concentration polarization.

  • PDF

The Effects of Asiasarum Root Methanol Extract Fractions on the Cell Mediated and Humoral Immune Responses in Mice (족도리풀 뿌리의 메탄올엑스 분획이 마우스의 세포성 및 체액성 면역반응에 미치는 영향)

  • Park, Ji-Young
    • Journal of Environmental Health Sciences
    • /
    • v.34 no.3
    • /
    • pp.213-218
    • /
    • 2008
  • The effects of Asiasarum Root on the cell mediated and humoral immune responses were investigated in ICR mice. ICR mice received intraperitoneal injection of methanol extracts (ether fraction, butanol fraction, water fraction) for 5 days before sensitization. The change of body weight (%), the organ weight ratio (%), the numbers of RBC and WBC, the ear swelling by dinitrofluorobenzene, the titers of hemagglutination (HA) and hemolysin (HY) to SRBC were determined. The results were as follows; 1. The change of body weight (%) showed a tendency of increasing. 2. The weight of spleen (%) decreased. 3. Ear swelling was maximum at 48 hours after challenge and was significantly decreased in the groups. 4. The numbers of RBC and WBC were decreased. 5. HA and HY titers were decreased.