• Journal of the Korean Chemical Society
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• v.66 no.6
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• pp.442-450
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• 2022

Diverse pyrrolo[3,2-d]pyrimidines that are expected to exhibit bioactivity were synthesized through O-arylation and Suzuki coupling reactions. Microwave-assisted O-arylation was successfully performed using a Cu metal catalyst, so that 4 position of pyrrolo[3,2-d]pyrimidine could be substituted with phenol group. In addition, 4-aryl substituted pyrrolo[3,2-d]pyrimidines were synthesized with good to excellent yields by microwave-assisted Suzuki coupling reaction using a Pd metal catalyst. By using microwaves as reaction conditions for diversification of derivatives, it was possible to dramatically overcome the disadvantages of traditional heat reactions of long reaction times and heat transfer efficiency problems. The result of this study can be used to be diversify pyrrolo[3,2-d]pyrimidine derivatives, which are expected to play an important role in the drug discovery research.

• Korean Journal of Plant Taxonomy
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• v.45 no.3
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• pp.239-242
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• 2015

Rhododendron keiskei Miq. var. hypoglaucum Suto & Suzuki (Ericaceae) was found in Yeosu-si, Jeollanam-do, Korea. This species is distinguished from related taxa in Korea by lepidote hairs entire, flower-bud terminal, inflorescences umbel-like racemes, corolla lepidot outside, white tinged with yellow. This taxon was named 'Seom-Jin-Dal-Lae' in Korean based on its habitat. We provide its description, illustrations, photographs and a key of related taxa in Korea.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2584-2592
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• 2011

Nickel nanoparticle-poly(N-vinyl-2-pyrrolidone)/$TiO_2-ZrO_2$ composite (Ni-PVP/$TiO_2-ZrO_2$) was prepared by in situ polymerization method. The physical and chemical properties of Ni-PVP/$TiO_2-ZrO_2$ were investigated by XRD, FT-IR, BET, TGA, SEM and TEM techniques. The catalytic performance of this novel heterogeneous catalyst was determined for the Suzuki-Miyaura cross-coupling reaction between aryl halides and phenylboronic acid in the presence of methanol-water mixture as solvent. The effects of reaction temperature, the amount of catalyst, amount of support, solvent, and amount of metal for the synthesis of Ni-PVP/$TiO_2-ZrO_2$, were investigated as well as recyclability of the heterogeneous composite. The catalyst used for this synthetically useful transformation showed considerable level of reusability besides very good activity.

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.180.1-180.1
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• 2007

• The Journal of the Korean Society for Microbiology
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• v.35 no.5_6
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• pp.333-335
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• 2000

• Journal of Radiation Protection and Research
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• v.25 no.3
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• pp.121-128
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• 2000

• Proceedings of the Korean Society for Language and Information Conference
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• 1994.02a
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• pp.103-112
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• 1994

• Journal of Food Hygiene and Safety
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• v.5 no.3
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• pp.123-129
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• 1990

• Proceedings of the Korean Society for Applied Microbiology Conference
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• 2004.06a
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• pp.310-310
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• 2004

• 월간 기계설비
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• s.106
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• pp.28-33
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• 1999