• Title/Summary/Keyword: Surfactant recycle

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Preparation f emulsion by Microfluidizer (고압유화장치를 이용한 emulsion의 제조)

  • 백승석;한창규
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.127-138
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    • 1993
  • This study was investigated optimal conditions which were necessary to prepare emulsion of four component systems by the Microfluidizer. Squalane, isopropyl myristate, PPG-15 stearyl benzoate ester were used as an oil and POE(20) sorbitan monolaurate, POE(20) sorbitan monopalmitate, POE(20) sorbitan monostearate, glycerine were selected as a cosurfactant and surfactant. The emulsion was affected by the operating pressure, the recycle frequency and oil, surfactant, cosurfactant phase. The operating pressure and recycle frequency increased, the droplet diameter of emulsion decreased and was constant later. In this study, the optimal pressure and recycle frequency were 1400 bar, 4 cycles. The droplet size was the smallest when the concentration of glycerine was 30 wt.%. As the oil phase is increased, the size is increased.

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Phenanthrene Uptake by Surfactant Sorbed on Activated Carbon (활성탄에 흡착된 계면활성제에 의한 Phenanthrene 흡착)

  • Ahn, Chi-Kyu;Woo, Seung-Han;Park, Jong-Moon
    • Journal of Soil and Groundwater Environment
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    • v.13 no.2
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    • pp.1-11
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    • 2008
  • Phenanthrene uptake by surfactant sorbed on activated carbon was investigated to recycle of surfactant in washed solution for contaminated soil. The partitioning of phenanthrene to the activated carbon coating with Triton X-100 as a surfactant was also evaluated by a mathematical model. Phenanthrene-contaminated soil (200 mg/kg) was washed in 10 g/L of surfactant solution. Washed phenanthrene in solution was separated by various particle loadings of granular activated carbon through a mode of selective adsorption. Removal of phenanthrene was 99.3%, and surfactant recovery was 88.9% by 2.5 g/L of granular activated carbon, respectively. Phenanthrene uptake by activated carbon was greater than that of phenanthrene calculated by a standard model for a system with one partitioning component. This is accounted for enhanced surface solubilization by hemi-micelles adsorbed onto granular activated carbon. The effectiveness factor is greater than 1 and molar ratio of solubilization to sorbed surfactant is higher than that of liquid surfactant. Results suggest that separation of contaminants and surfactants by activated carbon through washing process in soil is much effective than that of calculated in a theoretical model.

Effect of Fatty Acid and Non-ionic Surfactant on the Deinkability of Mixed Recovered Paper (혼합폐지의 탈묵효율에 미치는 지방산과 비이온성 계면활성제의 영향)

  • Seo, Jin Ho;Choi, Do Chim;Ryu, Jeong Yong;Chung, Sung Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.2
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    • pp.34-41
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    • 2015
  • Recovered paper has been widely used as a main raw material of papermaking in Korea. Recycling of recovered paper helps to reduce production cost and preserve an environment. To recycle recovered paper efficiently, de-inking is a key process in recycling mills. De-inking process would be affected by various influencing factors such as the type of de-inking agent, mixed ratio of recovered paper, season, and process conditions. In this study, fatty acid and nonionic surfactant were used as the de-inking agent in froth-flotation process of mixed recovered paper. De-inking properties of mixed recovered paper were investigated according to the addition level of each chemical. Nonionic surfactant had a small effect on de-inking efficiency of mixed recovered paper due to decreased reject. As the additional level of fatty acid increases, fragmented ink particles increased and then optical properties of recycled paper decreased because fragmented ink particles adsorbed onto the fiber surface.

In vitro Glutathione Production using Mixed Cells in an Aerated Slurry Bioreactor (혼합세포를 이용한 Aerated Slurry Bioreactor에서의 in vitro Glutathione 생산)

  • Go, Seong-Yeong;Gu, Yun-Mo
    • KSBB Journal
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    • v.14 no.4
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    • pp.445-451
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    • 1999
  • Glutathione production was carried out using mixed cells of E. coli TG1/pDG7 $\alpha$ and bakers yeast in an Aerated Slurry Bioreactor. Glutathione-producing enzymes were stable for 34 hours, yielding 4.6 mM glutathione in suspension reaction. Glutahione production with high density mixed cells was studied as a function of flow rate in an Aereated Slurry Bioreactor. Glutathione concentration was higher than that in suspension reaction for 32 hours at the substrate feeding rate of 5.2 mL/hr with cell recycle in continuous Aerated Slurry Bioreactor. It was for 42 hours at 2.6 mL/hr and 22 hours at 5.2 mL/hr without cell recycle. Glutahione productivity was 25.7 mg/g wet $cell{\cdot}hr$ at the substrate feeding rate of 10.4 mL/hr with cell recycle, but 5.28 mg/g wet $cell{\cdot}hr$ at 5.2 mL/hr and 1.65 mg/g wet $cell{\cdot}hr$ at 2.6 mL/hr without cell recycle. Effective production time increased from 25 to 45 hours, by using a surfactant, tween 80. As a purfing gas, nitrogen was tested instead of air to avoid a possible oxidizing effect on glutathione-producing enzymes, resulting in the increase of effective production time to 40 hours.

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Sorption and Leaching Characteristics of Diesel-Contaminated Soils Treated by Cold Mix Asphalt (Cold Mix Asphalt로 처리한 디젤 오염 토양의 흡착 및 용출특성)

  • Seo Jin-Kwon;Hwang Inseong;Park Joo-Yang
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.24-31
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    • 2004
  • A cold mix asphalt (CMA) treatment process was proposed as a tool to recycle soils contaminated with petroleum hydrocarbons. Experimental studies were conducted to characterize performances of the CMA process in treating soils contaminated with diesel or diesel compounds. From the screening experiments, it was found that performances of five types of asphalt emulsions that contained a cationic or an anionic or a nonionic surfactant were not substantially different. In consideration of higher affinity for soils and higher sorption coefficients obtained, an emulsion containing Lauryl Dimethyl Benzyl Ammonium Chloride (LDBAC) was selected as a promising asphalt emulsion for treating diesel-contaminated soils. When the asphalt emulsion LDBAC was applied to treat three compounds that originated from diesel, the removal efficiencies obtained in the order of decreasing efficiencies were as follows: docosane > pentadecane > undecane. Leaching experiments on the specimen formulated by the emulsion LDBAC found that the selected treatment method could treat soils with diesel concentrations as high as 10,000 mg/kg. Leaching of the diesel from the specimen was controlled by diffusion for the first four days and then leaching rate diminished substantially. The latter behavior was characterized as depletion, which represents that the contaminant released amounts to more than $50\%$ of the total amount of the contaminant that can be leached. The amounts of three diesel compounds leached from the specimen in the order of decreasing amount were undecane, pentadecane, and docosane. The curing of the soil contaminated with pentadecane was relatively slow.