• 제목/요약/키워드: Surface-active property

검색결과 92건 처리시간 0.026초

Plastic Displays - Latest Developments In Polyester Film For Plastic Electronics

  • Hashimoto, K.;MacDonald, W.A.;Rollins, K.;MacKerron, D.;Eveson, R.;Rustin, R.A.;Rakos, K.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
    • /
    • pp.620-622
    • /
    • 2005
  • DuPont Teijin Films (DTF) have developed a family of films engineered specifically for the flexible electronics market. $Teonex^{(R)}Q65A$ is a biaxially oriented crystalline polyester with an engineered surface and it is emerging as a competitive material for the base substrate in OLED displays and active matrix backplanes. This contribution will describe the properties of this film, its uniquely different property set compared to amorphous high performance films and discuss examples of the film in use in flexible electronic applications.

  • PDF

Polyphenylenediamine-Dimercaptan 복합 필름의 제막특성 (The Preparation Characteristic of Polyphenylenediamine -Dimercaptan Composite film)

  • 박수길;나재진;이홍기;임기조;김상욱;이주성
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.105-108
    • /
    • 1996
  • The positive active material for polymer film battery was prepared by using Polyphenylenediamine(PPD) synthesized in our lab. and 2.5-dimercapto-1, 3, 4-thiadiazole(DMcT) in various mixture ratio. The transference measurement of surface morphology and thermal stability of prepared composite film was carried out by using SEM and TGA, respectively. Electrocyhemical property and electrical conductivity of composite film were also measured by using cyclic voltammetry and four-probe method in dry box, respectively. The thermal stability of prepared composite film is more than 20$0^{\circ}C$. The electrical conductivity of composite film increased and showed the highest value(about 3 S/cm)when doped at 0.4% LiClO$_4$solution. And we could confirm that DMcT effect on reactiviation of PPD through cyclic voltammogram.

  • PDF

Methyl- $\beta$ -D-Fructofuranoside 합성을 위한 고정화 전화당 효소의 미소환경 최적화 (Microenvironmental Optimizaton of Immobilized Invertase for Methyl- $\beta$ -D-Fructofuranoside Synthesis)

  • 허주형;안형환
    • 대한안전경영과학회지
    • /
    • 제1권1호
    • /
    • pp.259-272
    • /
    • 1999
  • In order to enhance the selectivity, productivity and yield of methyl fructoside, which was synthesized by enzymatic glycosylation of sucrose and methanol solution, controlling of surface property of solid support using different immobilization procedures optimized microenvironment of immobilized invertase. Silanization and polyethylene imine coating methods were adopted to give a hydrophobic and hydrophilic environment of immobilized invertase. As a result, polyethyleneimine coating method gave higher loading of enzyme, effective activity, and relative activity than silanization method, because it brought on increasing the functional density of amino group and enhancing the conservation of activity by regulating of hydrophilicity. And then, hydrophilic environment was possible to restraint the assessing of methyl fructoside molecule, which was more hydrophobic than sucrose, fructose, and glucose molecule in the reaction mixture, into .the active site of immobilizedinvertase. Consequently, hydrophilic microenvironment of immobilized invertase by polyethyleneimine coating obtained higher yield and productivity with increasing conversion than silanized and native invertase. Thus, this procedure optimized the microenvironment of immobilized invertase suitable for the enzymatic synthesis of methyl fructoside.

  • PDF

솔젤법으로 제조된 고활성 $TiO_2$ 광촉매에서 미세구조-물성-공정조건의 상관성 (Microstrictire-property-processing relationship in highly active $TiO_2$ photocatalysts prepared by the sol-gel method)

  • 신현기;김헌
    • 한국결정성장학회지
    • /
    • 제9권5호
    • /
    • pp.493-497
    • /
    • 1999
  • 솔젤법을 사용하여 광촉매 $TiO_2$ 분말체를 제조하였으며 제조조건으로서 R값(물/알콕사이드 몰비), 열처리 온도, 미세구조로서 결정상, 물성으로서 비표면적과 입자크기의 상관관계를 조사하였으며 기능성으로 수용액상 염료의 광표백반응에 적용하여 광분해능을 극대화하기 위한 최적조건을 결정하였다.

  • PDF

자동차용 마찰재에 사용되는 흑연과 마그네시아에 따른 전이막과 마찰특성에 관한 연구 (The Effects of Graphite and Magnesium Oxide in Automotive Friction Materials on Friction and Formation of Transfer Film)

  • 배은갑;윤장혁;장호
    • 한국윤활학회:학술대회논문집
    • /
    • 한국윤활학회 2002년도 제35회 춘계학술대회
    • /
    • pp.226-234
    • /
    • 2002
  • A systematic study of the role of transfer films on friction properties was performed with various temperatures in the brake system. An NAO friction material specimens containing 9 ingredients were tested using a pad-on-disk type friction tester A new method of measuring the transfer film thickness was developed by considering the electrical resistance of the transfer film using a 4-point probe technique. The properties of transfer film such as surface morphology and film distribution vaied according to the relative amount of graphite and magnesium oxide. By using SEM, it was possible to obtain information about the chemical composition of the transfer film. Results showed that there detected a threshold value of the relative amount of a two active materials to maintain a certiain thickness of a transfer film. Results also showed that formation of friction layer generated on the friction surface was strongly affected by chemical action of two ingredients during sliding due to chemical reaction of solid lubricants at different interface temperature. The results suggested that no apparent relationship between transfer film thickness and the average friction coefficient was founded and friction characteristics were affected more by the property of the solid lubricant and abrasive in the material.

  • PDF

Advances in High Emission Sc2O3-W Matrix Cathode Materials

  • Wang, Jinshu;Yang, Yunfei;Liu, Wei;Wang, Yiman
    • Applied Microscopy
    • /
    • 제46권1호
    • /
    • pp.20-26
    • /
    • 2016
  • Our work on $Sc_2O_3-W$ matrix dispenser cathodes had been reviewed in this paper. The cathode with uniform distribution of $Sc_2O_3$ had been obtained using liquid-liquid doping method. The cathode had excellent emission property, i.e., the emission current density in pulse condition could reach over $35A/cm^2$. It was found that the cathode surface was covered by a Ba-Sc-O active substance multilayer with a thickness of about 100 nm, which was different from the monolayer and semiconducting layer in thickness. Furthermore, the observation results displayed that nanoparticles appeared at the growth steps and the surface of tungsten grains of the fully activated cathode. The calculation result indicated that the nanoparticles could cause the increase of local electric field strengths. We proposed the emission model that both the Ba-Sc-O multilayer and the nanoparticles distributing mainly on the growth steps of the W grains contributed to the emission. The future work on this cathode has been discussed.

Fabrication of Endothelial Cell-Specific Polyurethane Surfaces co-Immobilized with GRGDS and YIGSR Peptides

  • Choi, Won-Sup;Bae, Jin-Woo;Joung, Yoon-Ki;Park, Ki-Dong;Lee, Mi-Hee;Park, Jong-Chul;Kwon, Il-Keun
    • Macromolecular Research
    • /
    • 제17권7호
    • /
    • pp.458-463
    • /
    • 2009
  • Polyurethane (PU) is widely used as a cardiovascular biomaterial due to its good mechanical properties and hemocompatibility, but it is not adhesive to endothelial cells (ECs). Cell adhesive peptides, GRGDS and YIGSR, were found to promote adhesion and spreading of ECs and showed a synergistic effect when both of them were used. In this study, a surface modification was designed to fabricate an EC-active PU surface capable of promoting endothelialization using the peptides and poly(ethylene glycol) (PEG) spacer, The modified PU surfaces were characterized in vitro. The density of the grafted PEG on the PU surface was measured by acid-base back titration to the terminal-free isocyanate groups. The successful immobilization of pep tides was confirmed by amino acid analysis, following hydrolysis, and contact angle measurement. The uniform distribution of peptides on the surface was observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). To evaluate the EC adhesive property, cell viability test using human umbilical vein EC (HUVEC) was investigated in vitro and enhanced endothelialization was characterized by the introduction of cell adhesive peptides, GRGDS and YIGSR, and PEG spacer. Therefore, GRGDS and YIGSR co-immobilized PU surfaces can be applied to an EC-specific vascular graft with long-term patency by endothelialization.

코코넛 오일로부터 유래된 당계 비이온 계면활성제 합성 및 계면 특성 연구 (Synthesis of Saccharide Nonionic Biosurfactants from Coconut Oil and Characterization of Their Interfacial Properties)

  • 조선희;이예진;박기호;임종주
    • 공업화학
    • /
    • 제30권4호
    • /
    • pp.435-444
    • /
    • 2019
  • 본 연구에서는 코코넛 오일을 원료로 사용하여 2종의 비이온 당계 생체계면활성제 GP-6 및 GP-7을 합성하였으며, FT-IR, $^1H-NMR$$^{13}C-NMR$ 분광광도계를 이용하여 구조를 규명하였다. 합성한 계면활성제에 대하여 임계 마이셀 농도, 정적 및 동적 표면장력, 계면장력, 유화 작용, 습윤성 및 거품 안정성 등과 같은 계면 물성을 측정한 결과, GP-6 및 GP-7 모두 우수한 계면 특성을 가진 것으로 평가되었다. 또한 Terg-o-tometer를 사용하여 평가한 세척력 측정 결과에 의하면 GP-6 및 GP-7 모두 세제 제품에서 사용되는 기존 계면활성제들과 비교하여 양호한 세척력을 나타내었다. 생분해성, 급성 경구 독성, 급성 피부 자극 및 급성 안자극 검사 결과, GP-6 및 GP-7 모두 저 독성, 저자극성 및 우수한 환경친화성을 가지고 있어서 세제 제품에 적용 가능함을 나타냈으며, 특히 GP-6가 GP-7보다 계면활성이 우수하고 저자극성이고 쉽게 생분해 될 수 있기 때문에 세제 제조에 더 적합할 것으로 판단되었다.

Synergy effect for performance of anionic SDS/ADS mixtures with amphoteric and nonionic surfactants

  • Noh, Hongche;Kang, Taeho;Ryu, Ji Soo;Kim, Si Yeon;Oh, Seong-Geun
    • 한국응용과학기술학회지
    • /
    • 제33권3호
    • /
    • pp.449-458
    • /
    • 2016
  • Detergency and surface active properties of mixed anionic surfactants with amphoteric and nonionic were investigated. Sodium dodecyl sulfate (SDS) and ammonium dodecyl sulfate (ADS) as anionic surfactants and cocamidopropyl betaine (CAPB) as an amphoteric surfactant were used. Nonionic surfactants, which are butyl glucoside (BG), octyl glucoside (OG), decyl glucoside (DG), lauryl dimethylamine oxide (AO) and saponin were also used. To study the synergy effects of mixed SDS/ADS anionic surfactant systems, amphoteric and nonionic surfactants were added into the mixed anionic surfactants. Investigated properties of surfactant mixtures were critical micelle concentration (CMC), surface tension (${\gamma}$), wettability. In addition, based on these properties, detergency of each sample was examined. Surfactant mixtures are anionics (SDS/ADS), anionic/amphoteric/nonionic (SDS/ADS/CAPB/saponin), and anionic/nonionic (SDS/ADS/BG/saponin, SDS/ADS/OG/saponin, SDS/ADS/DG/saponin, and SDS/ADS/AO/saponin). With the addition of amphoteric and nonionic to mixed anionic surfactants, CMC and ${\gamma}$ were decreased. Addition of CAPB, which is amphoteric, showed the best property at CMC and ${\gamma}$. Furthermore, as the chain length of hydrocarbon in alkyl glucosides was increased, the CMC and ${\gamma}$ were enhanced. However, the wettability did not exactly match up with CMC and ${\gamma}$. The surfactant mixture, which contained DG, showed the best performance at wetting time. Detergency was measured at various temperatures ($15^{\circ}C$, $30^{\circ}C$, $50^{\circ}C$). The cleaning performance was enhanced by increasing washing temperature. Moreover, detergency was influenced by not only CMC and ${\gamma}$ but also wettability. Although CMC and ${\gamma}$ were not minimum at surfactant mixture that included DG, the best cleaning performance showed in that sample.

Staggered and Inverted Staggered Type Organic-Inorganic Hybrid TFTs with ZnO Channel Layer Deposited by Atomic Layer Deposition

  • Gong, Su-Cheol;Ryu, Sang-Ouk;Bang, Seok-Hwan;Jung, Woo-Ho;Jeon, Hyeong-Tag;Kim, Hyun-Chul;Choi, Young-Jun;Park, Hyung-Ho;Chang, Ho-Jung
    • 마이크로전자및패키징학회지
    • /
    • 제16권4호
    • /
    • pp.17-22
    • /
    • 2009
  • Two different organic-inorganic hybrid thin film transistors (OITFTs) with the structures of glass/ITO/ZnO/PMMA/Al (staggered structure) and glass/ITO/PMMA/ZnO/Al (inverted staggered structure), were fabricated and their electrical and structural properties were compared. The ZnO thin films used as active channel layers were deposited by the atomic layer deposition (ALD) method at a temperature of $100^{\circ}C$. To investigate the effect of the substrates on their properties, the ZnO films were deposited on bare glass, PMMA/glass and ITO/glass substrates and their crystal properties and surface morphologies were analyzed. The structural properties of the ZnO films varied with the substrate conditions. The ZnO film deposited on the ITO/glass substrate showed better crystallinity and morphologies, such as a higher preferred c-axis orientation, lower FWHM value and larger particle size compared with the one deposited on the PMMA/glass substrate. The field effect mobility ($\mu$), threshold voltage ($V_T$) and $I_{on/off}$ switching ratio for the OITFT with the staggered structure were about $0.61\;cm^2/V{\cdot}s$, 5.5 V and $10^2$, whereas those of the OITFT with the inverted staggered structure were found to be $0.31\;cm^2/V{\cdot}s$, 6.8 V and 10, respectively. The improved electrical properties for the staggered OITFTs may originate from the improved crystal properties and larger particle size of the ZnO active layer.

  • PDF