• Journal of the Korean Geotechnical Society
• /
• v.36 no.4
• /
• pp.5-15
• /
• 2020

This paper proposes a revised Modified Cam Clay type failure surface based on the critical state theory. In the plane of the mean effective and von Mises stresses, the original Modified Cam Clay model has an elliptic failure surface which leads the critical-state mean effective stress to be always half of the pre-consolidation mean effective stress without hardening and evolution rules. This feature does not agree with the real mechanical response of clay. In this study, the preconsolidation mean effective stress only reflects the consolidation history of the clay whereas the critical state mean effective stress only relies on the currenct void ratio of clay. Therefore, the proposed failure surface has a distorted elliptic shape without any fixed ratio between the preconsolidation and critical state mean effective stresses. Numerical simulations for various clays using failure surfaces as yield surface provide mechanical responses similar to the experimental data.

• Journal of Environmental Science International
• /
• v.17 no.5
• /
• pp.565-571
• /
• 2008

The surface properties of activated carbon modified by acids and base were studied. The influence of the surface chemistry on the adsorption of benzene and acetone vapor on modified activated carbons has been investigated The modified activated carbons were obtained by treatment with acetic acid ($CH_3COOH$), nitric acid ($HNO_3$) and sodium hydroxide (NaOH). The modified activated carbons had similar porosity but different surface chemistry and adsorption characteristics. The total surface acidity (sum of functional groups) of activated carbon (AC-AN) treated by nitric acid was 2.6 times larger than that of activated carbon (AC) before the acid treatment. Especially, carboxyl group was much developed by nitric acid treatment. The benzene equilibrium adsorption capacity of AC-AN decreased 20% more than that of AC. However, the acetone equilibrium adsorption capacity of AC-AN increased 20% more than that of AC because of the large increase of carboxyl group and acidity.

• Journal of Pharmaceutical Investigation
• /
• v.41 no.3
• /
• pp.185-190
• /
• 2011

The purpose of this study was to evaluate the phagocytic uptake of surface modified PLGA microspheres containing ovalbumin (OVA) into dendritic cell. In order to find the most suitable formulation for targeted delivery to antigen presenting cells (APC), OVA was encapsulated by a double emulsion solvent evaporation method with three PLGA microspheres (PLGA 50:50, PLGA 75:25 and PLGA 85:15) and two surface modified microspheres by chitosan and sodium dodecyl sulfate (SDS). Physicochemical properties were evaluated in terms of size, zeta potential, encapsulation efficiency, different scanning calorimeter (DSC), x-ray diffraction, morphology, and OVA release test from microspheres. Phagocytic activity was estimated using dendritic cells and analyzed by fluorescence activated cell sorter (FACS). The result showed that zeta potential of PLGA particles was changed to positive by the chitosan modification. The release profile of chitosan modified PLGA microspheres exhibited sustained release after initial burst. The chitosan modified microspheres had higher phagocytic uptake than the other microspheres. Such physicochemical properties and phagocytic uptake studies lead us to conclude that chitosan modified microspheres is more suitable formulation for the targeted delivery of antigens to APC compared with the other microspheres.

• Membrane Journal
• /
• v.10 no.3
• /
• pp.121-129
• /
• 2000

The membrane requires both high in selectivity and flux. However, the permselective membrane has low flux. In this study, the porous alumina membrane was coated with silane coupling agent in order to enhance the flux with proper selectivity. The contact angle of water to the surface-modified alumina membrane was greater than 90$^{\circ}$, which indicated the high hydrophobicity. The modified membrane was tested in vapor permeation for the concentration of aqueous ethanol, isopropanol, and n-butanol. With the increase of ethanol, isopropanol, butanol concentration in the feed, permeation flux increased due to the greater affinity of ethanol, isopropanol, butanol with surface-modified alumina membrane than that of water. The experimental results showed that the permeation tate of surface-modified alumina membrane was 20~1000 times greater than that of a polymer membranes.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.12
• /
• pp.3805-3810
• /
• 2013

The surface modification of silica particles (SPs) was systemically conducted by the treatment of 0.1-10 wt % phenylsilanetriol (PST) on the basis of SPs used through two step processes: 1) the PST coating of SPs via evaporation under reduced pressure and 2) their thermal condensation leading to Si-O-Si bond formation via heating at $130^{\circ}C$. The evaluation of the modified SPs was conducted by the simple floating test on water and the measurement of the contact angle (CA) of water droplet on the 2-dimensional layer of modified SPs on slide glass. When PST was used about 2 wt % or above on the basis of SPs (about average size: 50 nm) used, the modified SPs were fully floated on the water and all dispersed into upper organic solvent layer after a shaking with the mixture of the water and benzene, indicating that the modified SPs have hydrophobic properties. The modified SPs were characterized by $^{29}Si$ MAS NMR and physicochemical properties including SEM, TEM, BET, adsorption/desorption isotherms, etc. were measured and compared each other in details. This research demonstrates that the organosilanetriol is a good modifier applicable for the surface modification of inorganic oxide particles using a low amount of modifier on the basis of oxide particles used.

• Proceedings of the KSRS Conference
• /
• v.2
• /
• pp.794-796
• /
• 2006

This study investigated the Brightness Temperature Difference threshold as criterion between aerosols and clouds in conjunction with radiative transfer model. Surface temperature is caused by a significant error over 50% in the BTD threshold. In addition, The BTD threshold contains the uncertainties about 20% due to the surface emissivity and 8% due to the satellite zenith angle. Therefore, we have composed the Look-up table for BTD between 11㎛and 12㎛ according to satellite zenith angle, surface temperature, and surface emissivity. The modified BTD show the enhanced signal, especially over bright surface such as desert in China. However, a weak aerosol signal over Ocean remains in the modified BTD.

• Proceedings of the IEEK Conference
• /
• 2001.10a
• /
• pp.307-312
• /
• 2001

Adsorption capacities of toxic heavy metal ions using as-received carbon(AC), single and double surface-modified activated carbon(OAC and DSMC) in wide pH ranges are extensively evaluated. Physical and chemical properties of surface-modified activated carbons are evaluated through BET analysis, surface acidity and oxides measurements. Based oil tile adsorption isotherms of Pb, Cd and Cr ions by AC, OAC and DSMC, the adsorption amount on DSMC was obviously higher than that on the other carbons. Breakthrough behaviors of ternary metal ions in a column packed with three kinds of carbon were also characterized with respect to the variations of the influent pH and concentration. The adsorption capacity of DSMC in a fixed bed stood a favorable comparison with that of as-received carbon.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.201-201
• /
• 2011

Recently, mussel-inspired surface modification, called polydopamine coating has been extensively implemented to many areas, due to its material versatility and ease to use. In particular, incubation of substrates in an alkaline dopamine solution resulted in self-polymerization of dopamine and modified variety of material surfaces, including noble metals, metal oxides, ceramics, and synthetic polymers. However, the polydopamine coating has a drawback to practical use; it takes more than 12 hrs to introduce sufficient polydopamine layers to solid substrates. Here, we investigated the rate-enhanced polydopamine coating by varying reaction conditions: pH, concentration, and the addition of the oxidizing agent. As a result, the optimum condition for fast polydopamine coating was found, and solid substrates were efficiently coated with polydopamine layers in just few minutes using the condition. The polydopamine-modified surface was characterized by XPS and contact angle goniometry, and the biocompatibility of the modified surface was also proved by cell attachment test.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.11a
• /
• pp.445-448
• /
• 2004

Recently, bridge deck overlay with latex modified concrete is widely applied in domestic. the capacity of bridge deck overlay depends on bond state on the surface. factors that have an effect on bond state are clean condition on the surface, absence of surface microcracking, absence of laitance, overlay curing. In this study, it is researched that characteristic of bond strength according to moisture condition on the surface and the removal method of concrete. As a result, it shows high bond strength in dry condition when w/c is $31\%$ and in moisture condition when w/c is $38\%$ respectively. characteristic of bond strength according to the removal method of concrete shows high bond strength when using water-jets rather than jackhammers.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.309-314
• /
• 2010

The surface modified $LiMn_2O_4$ materials with Li-Fe composites were prepared by a sol-gel method to improve the electrochemical performance of $LiMn_2O_4$ and were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), and transmission electron microscopy (TEM)-EDS. XRD results indicate that all the samples (modified and pristine samples) have cubic spinel structures, and XRD, XPS, and TEM-EDS data reveal the formation of $Li(Li_xFe_xMn_{2-2x})O_4$ solid solution on the surface of particles. For the electrochemical properties, the modified material demonstrated dramatically enhanced reversibility and stability even at elevated temperature. These improvements are attributed to the formation of the solid solution, and thus-formed solid solution phase on the surface of $LiMn_2O_4$ particle reduces the dissolution of Mn ion and suppresses the Jahn-Teller effect.