• Title/Summary/Keyword: Surface tension effect

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Kinetics of Denaturation of Human and Chicken Hemoglobins in the Presence of Co-solvents

  • Ajloo, Davood;Moosavi-Movahedi, Ali A.
    • BMB Reports
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    • v.36 no.4
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    • pp.367-372
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    • 2003
  • The stability of four hemoglobins (Hb) in dimer forms (low concentration) were investigated by the kinetics of denaturation. The rate constants of denaturation were obtained by variation of 280 nm absorption versus time in 10 mM Tris-HCl, 10 mM EDTA, pH 8.0 at $45^{\circ}C$ in the absence and presence of 0.5 M ethanol, dimethyl sulfoxide (DMSO), formamide, and glycerol. The results show the trend of rate constants in different co-solvents in the following order: chicken hemolysate < human hemolysate and chicken Hb D < chicken Hb A. The buried surface area was calculated for Hb samples in the absence of cosolvents. Accordingly, the trend points out that: chicken Hb D > chicken Hb A > human Hb A. These results suggest that both chicken hemolysate and chicken Hb D are relatively more stable than human and chicken Hb A, respectively. However, the denaturation rate constants of Hb in different co-solvents have designated the following order: ethanol > DMSO > formamide > glycerol. As a matter of fact, this phenomenon is an indication of an increase in the denaturation capacity (DC) and hydrophobicity, and a decrease in the surface tension of the solution in the preceding co-solvents.

Critical Micelle Concentration of Sucrose Monostearate (모노스테아르산설탕의 Critical Micelle Concentration)

  • Noh Jang Sook;Lee Kwang Soon;Chang Sae Hee;Ahn Woon-Sun
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.354-357
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    • 1974
  • The critical micelle concentration(CMC) of sucrose monostearate is determined between 20 and $40^{\circ}C$, and the effect caused by the addition of sucrose distearate on the CMC is also studied. It is found that, when both of monoester and diester are dissolved, the curve of surface tension of the solution versus the concentration shows a discontinuity at about 40 dyne $cm^{-1}$ of the surface tension. The discontinuity is interpreted as the associate formed between monoester and diester changes its surface orientation at this region.

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Surface effects on vibration and buckling behavior of embedded nanoarches

  • Ebrahimi, Farzad;Daman, Mohsen;Fardshad, Ramin Ebrahimi
    • Structural Engineering and Mechanics
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    • v.64 no.1
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    • pp.1-10
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    • 2017
  • The present paper deals with the free vibration and buckling problem with consideration of surface properties of circular nanobeams and nanoarches. The Gurtin-Murdach theory is used for investigating the surface effects parameters including surface tension, surface density and surface elasticity. Both linear and nonlinear elastic foundation effect are considered on the circular curved nanobeam. The analytically Navier solution is employed to solve the governing equations. It is obviously detected that the natural frequencies of a curved nanobeams is substantially influenced by the elastic foundations. Besides, it is revealed that by increasing the thickness of curved nanobeam, the influence of surface properties and elastic foundations reduce to vanished, and the natural frequency and critical buckling load turns into to the corresponding classical values.

Stress Intensity Factor Analysis for Surface Crack in Inhomogeneous Materials (비균질재료의 표면균열에 대한 응력확대계수 해석)

  • 김준수;이준성
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.816-819
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    • 2002
  • Accurate stress intensity factor analyses and crack growth rate of surface-cracked components in inhomogeneous materials are needed for reliable prediction of their fatigue lift and fracture strengths. This paper describes an automated system for analyzing the stress intensity factors of three-dimensional (3D) cracks in inhomogeneous materials. 3D finite element method (FEM) was used to obtain the stress intensity factor for subsurface cracks and surface cracks existing in inhomogeneous materials. To examine accuracy and efficiency of the present system, the stress intensity factor for a semi-elliptical surface crack in a plate subjected to uniform tension is calculated, and compared with Raju-Newman's solutions. Then the system is applied to analyze cladding effect of subsurface cracks in inhomogeneous materials. The results were compared with those surface cracks in homogeneous materials. It is clearly demonstrated from these analyses that the stress intensity factors for subsurface cracks are less than those of surface cracks.

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Vibration analysis of inhomogeneous nonlocal beams via a modified couple stress theory incorporating surface effects

  • Ebrahimi, Farzad;Safarpour, Hamed
    • Wind and Structures
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    • v.27 no.6
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    • pp.431-438
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    • 2018
  • This paper presents a free vibration analysis of size-dependent functionally graded (FG) nanobeams with all surface effects considerations on the basis of modified couple stress theory. The material properties of FG nanobeam are assumed to vary according to power law distribution. Based on the Euler-Bernoulli beam theory, the modeled nanobeam and its equations of motion are derived using Hamilton's principle. An analytical method is used to discretize the model and the equation of motion. The model is validated by comparing the benchmark results with the obtained results. Results show that the vibration behavior of a nanobeam is significantly influenced by surface density, surface tension and surface elasticity. Also, it is shown that by increasing the beam size, influence of surface effect reduces to zero, and the natural frequency tends to its classical value.

Instabilities of Natural Convection in a Shallow Fluid Layers (얇은 유체층(流體層)에 있어서 자연대류(自然對流)의 불안정성(不安定性))

  • Yang, Soong-Hyo;Park, Chan-Kuk
    • Solar Energy
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    • v.8 no.1
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    • pp.33-40
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    • 1988
  • The characteristics of thermal instabilities of natural convection in a horizontal fluid layer bounded below by a rigid plate and above by an interface with a passive gas is presented. The critical Grashof number decreases as the surface tension gradient effect (Marangoni effect) at the interface increases and the flow remains unstable for a critical Marangoni number depending on Prandtl numbers. These results are in substantial agreement with those of Smith and Davis.

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Vibration analysis of boron nitride nanotubes by considering electric field and surface effect

  • Zeighampour, Hamid;Beni, YaghoubTadi
    • Advances in nano research
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    • v.11 no.6
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    • pp.607-620
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    • 2021
  • In this paper, the vibrations of boron nitride nanotubes (BNNTs) are investigated by considering the electric field. To consider the size effect at nanoscale dimensions, the surface elasticity theory is exploited. The equations of motion of the BNNTs are obtained by applying Hamilton's principle, and the clamped-guided boundary conditions are also considered. The governing equations and boundary conditions are discretized using the differential quadrature method (DQM), and the natural frequency is obtained by using the eigenvalue problem solution. The results are compared with the molecular dynamic simulation in order to validate the accurate values of the surface effects. In the molecular dynamics (MD) simulation, the potential between boron and nitride atoms is considered as the Tersoff type. The Timoshenko beam model is adopted to model BNNT. The vibrations of two types of zigzag and armchair BNNTs are considered. In the result section, the effects of chirality, surface elasticity modulus, surface residual tension, surface density, electric field, length, and thickness of BNNT on natural frequency are investigated. According to the results, it should be noted that, as an efficient non-classical continuum mechanic approach, the surface elasticity theory can be used in scrutinizing the dynamic behavior of BNNTs.

The Effect of Surface Tension on the Transient Free-Surface Flow near the Intersection Point (교차점 부근의 과도자유표면유동에 미치는 표면장력의 영향)

  • Lee, G.J.;Rhee, K.P.
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.104-117
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    • 1991
  • When a body starts to move, the flow near the intersection point between a body and a free surface changes violently and rapidly in a very short initial time interval. This flow phenomena must be investigated whenever one treats the interaction between a body and a fluid, such as the motion of a floating body, sloshing in a tank, wave maker problem, entry of a body into a fluid etc.. Until Roberts(1987), it was widely accepted that a singularity exists at the intersection point. However, he showed that the singularity does not exist if a body moves non-impulsively. In this paper, an analytical solution cosistent for the case of impulsive motion of a body is obtained by including the effect of surface tension. From the characteristics of the newly obtained solution, a critical value associated with an oscillating phenomenon is found, and further more, it is shown that the oscillating phenomenon does not appear in the region where the distance form the intersection point is less than this critical value.

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R-113 condensation on vertically finned plate (핀이 가공된 수직평판의 R-113 응축)

  • Kim, Nae-Hyeon;Jo, Jin-Pyo;Kim, Jeong-O
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.6
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    • pp.750-756
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    • 1998
  • In this study, condensation tests were conducted on a vertically finned plate (fin height 1 mm, fin thickness 1 mm, fin spacing 1 mm) using R-113. Results showed that fins enhanced the condensation on a vertical plain surface as much as four times. Comparison with theoretical models revealed that the effect off surface tension should be included in the model. The effect of interruption plates was also investigated. The plates were not effective in enhancing the finned plate condensation. The reason may be attributed to the already thinned condensate film on the finned surface.

A treatise on irregular shaped concrete test specimens

  • Gorkem, Selcuk Emre
    • Computers and Concrete
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    • v.16 no.1
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    • pp.179-190
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    • 2015
  • An experimental program has been carried out to investigate the effect of edge-slope on compressive strength of concrete specimens. In this study, effect of such slope was investigated by testing 100 standard cylinder specimens and 40 standard cubes. When molds are put on a slanted place, wet concrete starts to flow through the open end of mold. It keeps flowing until it reaches to a parallel surface with the place over which it was placed. That creates a sloped surface over the loading area. Experimental results revealed significant relationships between failure loads and slope of loading surface for cylinders. Angled cracks occurred in sloped cylinder specimens. Tension cracks occurred in cube specimens. Fracture mechanisms were also evaluated by using finite element analyses approach. Experiments yielded an exponential curve with bandwidth for cylinders. Average value of curve is $y={\frac{\pi}{2}}e^{-cf}$ between slope and compressive strength. Inclination is much effective parameter for cylinders than cubes.